铑/双膦配体催化均相内烯烃氢甲酰化反应的研究进展

催化学报 , 2009, 30(6): 577-586.

铑/双膦配体催化均相内烯烃氢甲酰化反应的研究进展

刘雯静 ^1, , 袁茂林 ^2, , 付海燕 ^3, , 李瑞祥 ^4, , 陈华 ^5,

1.四川大学化学学院有机金属络合催化研究所,绿色化学与技术教育部重点实验室,四川成都,610064

2.四川大学化学学院有机金属络合催化研究所,绿色化学与技术教育部重点实验室,四川成都,610064

3.四川大学化学学院有机金属络合催化研究所,绿色化学与技术教育部重点实验室,四川成都,610064

4.四川大学化学学院有机金属络合催化研究所,绿色化学与技术教育部重点实验室,四川成都,610064

5.四川大学化学学院有机金属络合催化研究所,绿色化学与技术教育部重点实验室,四川成都,610064

基金项目: 国家自然科学基金(29792074)

关键词：铑 , 双膦配体 , 内烯烃 , 氢甲酰化

Progress of Rhodium/Diphosphine-Catalyzed Homogeneous Hydroformylation of Internal Olefins

烯烃氢甲酰化反应是工业上合成醛的重要方法.由于双膦配体良好的配位能力,形成的铑配合物有很好的催化活性,在内烯烃氢甲酰化反应中,可以有效地提高直链醛选择性.本文系统地综述了近年来双膦配体铑配合物催化均相内烯烃氢甲酰化反应的研究进展,讨论了双膦配体结构对催化剂活性和生成直链醛选择性的影响.

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材料期刊网

铑/双膦配体催化均相内烯烃氢甲酰化反应的研究进展

Progress of Rhodium/Diphosphine-Catalyzed Homogeneous Hydroformylation of Internal Olefins

参考文献