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能源危机日益加重,寻求替代能源已迫在眉睫.Ni-MH动力电池以其在多方面的优势而成为HEV和EV首选的动力设备.动力电池对电极材料提出了较一般电池不同的要求.主要介绍了近年来动力电池用新型贮氢合金种类、常用替代元素的作用及其发展方向.AB3型贮氢合金以其出众的放电容量和活化性能有望成为AB5型贮氢合金的替代品应用于动力电池.由于Co的毒害效应,且近年来金属Ni、Co的价格不断上涨,低Co、无Co以及低Ni贮氢合金成为新的研究方向.我国稀土资源丰富,为我国发展Ni-MH动力电池提供了有利条件,可推动我国电动车的发展,也有利于环境保护.

参考文献

[1] 陈军;陶占良.镍氢二次电池[M].北京:化学工业出版社,2006:4.
[2] Baddour-Hadjean R;Meyer L;Pereira-Ramos J P et al.An electrochemical study of new La1-x Cex Y2Ni9(0
[3] Willems J J G .From permanent magnets to rechargeable hydride electrodes[J].Journal of the Less-Common Metals,1987,129:13.
[4] Zhang X B;Sun D Z;Yin W Y et al.Effect of La/Ce ratio on the structure and electrochemical characteristics of La0.7-xCexMg0.3Ni2.8Co0.5(x=0.1~0.5) hydrogen storage alloys[J].Electrochimica Acta,2005,50:1957.
[5] Yuan Anbao;Xu Naixin .A study on the effect of nickel,cobalt or graphite addition on the electrochemical properties of an AB5 hydrogen storage alloy and the mechanism of the effects[J].Journal of Alloys and Compounds,2001,322:269.
[6] Huang Yuexiang;Ye Hui;Zhang Hong .Characteristics of a cobalt-free ML(NiCuAl)5.2 alloy obtained by different casing processing methods[J].J Alloys Cornpd,2002,330-332:851.
[7] Kim Dong Myung;Jang KuK Jin;Lee Jai Young .A review on the developmem of AB2-type Zr-based laves phase hydrogen storage alloys for Ni-MH rechargeable batteries in the Korea advanced institute of science and technology[J].Journal of Alloys and Compounds,1999,293-295:583.
[8] Dhar S K;Fetcenko M A;Ovshinsky S R.Advanced materials for next generation high energy and power nickel-metal hydride portable batteries[A].USA:Long Beach,2001:325.
[9] Kadir K;Tanaka H;Sakai T et al.Hydrogen behavior in the La-Mg-Cu system[J].Journal of Alloys and Compounds,1999,298:66.
[10] Liang G.;Huot J. .Hydrogen storage in mechanically milled Mg-LaNi_5 and MgH_2-LaNi_5 composites[J].Journal of Alloys and Compounds: An Interdisciplinary Journal of Materials Science and Solid-state Chemistry and Physics,2000(1/2):261-265.
[11] Ouyang L Z;Dong H W;Peng C H et al.A new type of Mg-based metal hydride with promising hydrogen storage properties[J].International Journal of Hydrogen Energy,2007,32:3929.
[12] Paula V. Jasen;Estela A. Gonzalez;Graciela Brizuela;Oscar A. Nagel;Gustavo A. Gonzalez;Alfredo Juan .A theoretical study of the electronic structure and bonding of the monoclinic phase of Mg_2NiH_4[J].International journal of hydrogen energy,2007(18):4943-4948.
[13] Komiya K;Morisaku N;Shinzato Y et al.Synthesis and dehydrogenation of M(AlH4)2 (M=Mg,Ca)[J].Journal of Alloys and Compounds,2007,446-447:237.
[14] Wua Maosung;Wu Hongrong;Wang Yungyun et al.Electrochemical investigation of hydrogen-storage alloy electrode with duplex surface modification[J].International Journal of Hydrogen Energy,2004,29:1263.
[15] Munehisa Ikom;Katsunori Komori;Satoshi Kaida et al.Effect of alkali-treatment of hydrogen storage alloy on thedegradation of Ni/MH batteries[J].Journal of Alloys and Compounds,1999,284:92.
[16] Feng Yan;Jiao Lifang;Yuan Huatang et al.Effects of NiB doping in MgNi alloy electrode on its electrochemical characteristics[J].International Journal of Hydrogen Energy,2007,32:2325.
[17] Kadir K;Sakai T;Uehara I .Structural investigation and hydrogen capacity of LaMg2Ni9 and (La0.68 Ca0.35) (Mg1.32Ca0.68)Ni9 of the AB2C9 type structure[J].Journal of Alloys and Compounds,2000,302:112.
[18] Kohno T.;Yoshida H. .Hydrogen storage properties of new ternary system alloys: La_2MgNi_9, La_5Mg_2Ni_(23), La_3MgNi_(14)[J].Journal of Alloys and Compounds: An Interdisciplinary Journal of Materials Science and Solid-state Chemistry and Physics,2000(2):L5-L7.
[19] Chu Haitiang;ZhanG Yao;Sun Lixian et al.Structure and electrochemical properties of composite electrodes synthesized by mechanical milling Ni-free TiMn2-based alloy with La-based alloys[J].Journal of Alloys and Compounds,2007,446-447:614.
[20] Genma R;Uchida H H;Okada N et al.Hydrogen reactivity of Li-containing hydrogen storage materiala[J].Journal of Alloys and Compounds,2003,356-357:358.
[21] Wang Yi;Wang Xin;Gao Xueping et al.Electrochemical characteristics of the ball-milled LaMg10-xTixNi2 alloys with Ni powders (x=1 and 2)[J].International Journal of Hydrogen Energy,2007,32:4180.
[22] Zhang Yanghuan;Dong Xiaoping;Wang Guoqing et al.Effect of substituting Mm with La on the electrochemical performances of Co-free LaxMm1-x(NiMnSiAlFe)4.9(x =0~1) electrode alloys prepared by casting and rapid quenching[J].Journal of Power Sources,2005,140:381.
[23] Liao B;Lei Y Q;Chen L X et al.Effect of the La/Mg ratio on the structure and electrochemical properties of LaxMg3-xNi9(x=1.6~2.2) hydrogen storage electrode alloys of nickel-metal hydride batteries[J].Journal of Power Sources,2004,129:358.
[24] Lichtenherg F;Kohler U;Folzer A et al.Development of AB5 type hydrogen storage alloys with low Co content for rechargeable Ni-MH batteries with respect to electric vehicle applications[J].Journal of Alloys and Compounds,1997,253-254:570.
[25] Huang Yuexiang;Hui Ye;Zhang Hong .Characteristics of a cobalt-free ML(NiCuAl) alloy obtained by different casting processing methods[J].Journal of Alloys and Compounds,2002,330-332:851.
[26] Chiaki Iwakura;Kazuhiro Ohkawa;Hiroshi Senoh;Hiroshi Inoue .Electrochemical and crystallographic characterization of Co-free hydrogen storage alloys for use in nickel-metal hydride batteries[J].Electrochimica Acta,2001(28):4383-4388.
[27] Zhang Yanghuan;Li Baowei;Ren Huiping et al.Effects of substituting Ni with Al on the microstructure and electrochemical performances of the as-cast and quenched La-MgNi-based (PuNi3-type) hydrogen storage alloys[J].Materials Chemistry and Physics,2007,105:86.
[28] Wang J;Wu F;Shan Zh Q .Effect of addition of Mn and Co on the hydrogen storage charaeterisitics of microcrystalline Mg[J].Journal of Alloys and Compounds,2003,359:315.
[29] Ye H;Huang Y X;Huang T S et al.Influence of the boron additive on the electrochemical properties of the MinNi3.55Co0.75 Mn0.4 Al0.3 hydrogen storage alloy[J].Journal of Alloys and Compounds,2002,330-332:866.
[30] Zhang Yanghuan;Wang Guoqing;Dong Xiaoping et al.Investigation on the microstructure and electrochemical peformances of La2Mg(Ni0.85Co0.15)9 Bx(x= 0~0.2) hydrogen storage electrode alloys prepared by castion and tepid quenching[J].Journal of Alloys and Compounds,2004,379:298.
[31] Hu Weikang;Kim Dongmyung;Jeon Seokwon et al.Effect of annealing treatment on electrochemical properties of Mmbased hydrogen storage alloys for Ni/MH batteries[J].Journal of Alloys and Compounds,1998,270:255.
[32] Zhang Yanghuan;Wang Guoqing;Dong Xiaoping et al.Effect of rapid quenching on the microstructures and electrochemical performances of Co-free AB5-type hydrogen storage alloys[J].International Journal of Hydrogen Energy,2005,30:1091.
[33] Lin H C;Lin K M;Chou H T et al.Effects of annealing and NaOH pretreatment on an LmNi3.65 Al0.34 Mn0.27 Co0.74 hydrogen storage alloy[J].Journal of Alloys and Compounds,2003,358:281.
[34] Ma Zhihong;Qiu Jufeng;Chen Lixin et al.Effects of annealing on microstructure and electrochemical properties of the low Co-containing alloy Ml(NiCoMnAlFe)5 for Ni/MH battery electrode[J].Journal of Power Sources,2004,125:267.
[35] Marco Di Chio;Alessandro Ziggiotti;Mareello Baricco .Effect of microstructure on hydrogen absorption in LaMg2 Ni[J].J Intermetallics,2008,16:105.
[36] Chu Hailiang;Zhang Yao;Sun Lixian et al.Structure and electrochemical properties of composite electrodes synthesized by mechanical milling Ni-free TiMn2-based alloy with La-hased alloys[J].Journal of Alloys and Compounds,2007,446-447:614.
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