综述了钨晶须/纳米线几种典型的制备方法及其最新研究进展,如气相沉积法、金属催化诱导法、电化学蚀刻法、模板法等,介绍了气-固、气-液-固和气-固-固生长机制及模型,分析了钨晶须/纳米线在研究和应用中存在的主要问题,指出钨晶须/纳米线生长过程中的影响因素、生长模型建立及钨晶须/纳米线的形貌、组成和产率综合调控是未来重要的研究方向.
In this paper,synthetic strategies of tungsten whiskers/nanowires and their recent research progress are summarized. Typical methods for preparing tungsten whiskers/nanowires,such as vapor deposition,metal-catalyzed,electrochemical etching and template are introduced in detail. Furthermore,several typical growth mechanisms and models such as vapor-solid,vapor-liquid-solid and vapor-solid-solid are introduced. Finally,based on the existing problems in the present research and application,the future important trends in this field are discussed,which are critical to study the growth model and the influencing factors during the growth process of tungsten whiskers/nanowires and to adjust the morphology,composition and yield comprehensively.
参考文献
| [1] | 张存信,秦丽柏,米文宇,白志国.我国穿甲弹用钨合金研究的最新进展与展望[J].粉末冶金材料科学与工程,2006(03):127-132. |
| [2] | Yun-Hi Lee;Chang-Hoon Choi;Yoon-Taek Jang;Eun-Kyu Kim;Byeong-Kwon Ju;Nam-Ki Min;Jin-Ho Ahn .Tungsten nanowires and their field electron emission properties[J].Applied physics letters,2002(4):745-747. |
| [3] | A.G.Umnov;Y.Shiratori;H.Hiraoka .Giant field amplification in tungsten nanowires[J].Applied physics, A. Materials science & processing,2003(1):159-161. |
| [4] | J. P. Singh;T. Karabacak;T.-M. Lu;G.-C. Wang;N. Koratkar .Field ionization of argon using β-phase W nanorods[J].Applied physics letters,2004(15):3226-3228. |
| [5] | Levitt;Albert P .Tungsten penetrators[P].US,5440995,1995-08-15. |
| [6] | Wagner R S.VLS mechanism of crystal growth[A].New York:Wiley-Interscience,1970:47. |
| [7] | Volmer M;Estermann I .Uber der mechanismus der molekǖlabscheidung an kristallen[J].Zeitschrift für Physik,1921,7(01):13. |
| [8] | Sears G W .A mechanism of whisker growth[J].Acta Metallurgica,1955,3(04):367. |
| [9] | Sears G W .A growth mechanism for mercury whiskers[J].Acta Metallurgica,1955,3(04):361. |
| [10] | Sears G W .Mercury whiskers[J].Acta Metallurgica,1953,1(04):457. |
| [11] | Sreeram Vaddiraju;Hari Chandrasekaran;Mahendra K. Sunkara .Vapor Phase Synthesis of Tungsten Nanowires[J].Journal of the American Chemical Society,2003(36):10792-10793. |
| [12] | Karabacak T.;Mallikarjunan A.;Singh JP.;Ye DX.;Wang GC.;Lu TM. .beta-phase tungsten nanorod formation by oblique-angle sputter deposition[J].Applied physics letters,2003(15):3096-3098. |
| [13] | Y. G. Shen;Y. W. Mai;Q. C. Zhang .Residual stress, microstructure, and structure of tungsten thin films deposited by magnetron sputtering[J].Journal of Applied Physics,2000(1):177-187. |
| [14] | A.G.Umnov;Y.Shiratori;H.Hiraoka .Giant field amplification in tungsten nanowires[J].Applied physics, A. Materials science & processing,2003(1):159-161. |
| [15] | 高程,贺跃辉,王世良.金属钨纳米线阵列的制备[J].材料研究学报,2008(06):577-579. |
| [16] | Guha Sumit;Kyriacou;Christos et al.Low cost synthesis technique for tungsten whiskers of (100) orientation[J].Materials and Manufacturing Processes,1994,9(06):1061. |
| [17] | Starliper A G;Kenworthy H .Tungsten whiskers by vapor phase growth[J].Electrodeposition and Surface Treatment,1974,2(04):249. |
| [18] | Nataliya F;Karpovich;Nataliya V .Mechanism of the single-crystal tungsten whiskers growth in the process of the Ni-WO_4 reduction by CO[J].Journal of Physical Chemistry C,2008,112(47):18455. |
| [19] | Givargizov E I.Vapor growth of filamentary and plate-like crystals[M].Moscow:Nauka,1977:304. |
| [20] | 徐剑,贺跃辉,王世良,汤义武.一种制备金属钨纳米针的新方法[J].材料研究学报,2006(06):576-580. |
| [21] | 徐剑,贺跃辉,王世良,朱剑,汤义武.Ni、Fe含量对制备钨纳米晶须的影响[J].中国钨业,2006(02):25-28,32. |
| [22] | Olivier L. Guise;Joachim W. Ahner;Moon-Chul Jung;Peter C. Goughnour;John T. Yates Jr. .Reproducible Electrochemical Etching of Tungsten Probe Tips[J].Nano letters,2002(3):191-193. |
| [23] | 张友生,闫允杰,朱静.两种纳米级针尖的制作和应用[J].电子显微学报,2004(04):483-483. |
| [24] | Yadong Li;Xiaolin Li;Zhao-Xiang Deng;Beichuan Zhou;Shoushan Fan;Junwei Wang;Xiaoming Sun .From Surfactant-Inorganic Mesostructures to Tungsten Nanowires[J].Angewandte Chemie International Edition,2002(2):343-345. |
| [25] | Okuyama F;Fujimoto Y .Fcc needle crystals of molybdenum grown from Mo(Co)_6[J].Journal of Applied Physics,1984,56(02):566. |
| [26] | Thong J T L;Oon C H .Field-emission induced growth of nanowires[J].Applied Physics Letters,2002,81(25):4823. |
| [27] | Electron-beam-induced deposition using a subnanometer-sized probe of high-energy electrons[J].Applied physics letters,2003(10):2064-2066. |
| [28] | Liu Z Q;Mistsuishi K;Furuya K .Effects of focus change on the fabrication of tungsten nanowire by electrorrbeam-induced deposition[J].NANOTECHNOLOGY,2004,15(05):414. |
| [29] | 李武.无机晶须[M].北京:化学工业出版社,2005:7. |
| [30] | Brener S S;SearsG W .Mechanism of whisker growth-Ⅲ Nature of growth site[J].Acta Metallurgica,1956,3(04):268. |
| [31] | P.Yang;C.M.Lieber .Nanostructured high-temperature superconductors: Creation of strong-pinning columnar defects in nanorod/superconductor composites[J].Journal of Materials Research,1997(11):2981-2995. |
| [32] | Xia Younan;Yang Peidong;Sun Yugang .One-dimensional nanostructures:Synthesis,characterization and applications[J].Advanced Materials,2003,15(04):353. |
| [33] | Ann I.Persson;Magnus W.Larsson;Stig Stenstrom;B.Jonas Ohlsson;Lars Samuelson;L.Reine Wallenberg .Solid-phase diffusion mechanism for GaAs nanowire growth[J].Nature materials,2004(10):677-681. |
| [34] | Persson A I;Ohlsson B J et al.Growth mechanisms for GaAs nanowires grown in CBE[J].Journal of Crystal Growth,2004,272(1-4):167. |
| [35] | 徐剑 .钨纳米针的制备及生长机理研究[D].中南大学,2006. |
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