铜基太阳电池是以具有含铜的黄铜矿结构化合物或其衍生物为吸收层的太阳电池,其中以CIGS为吸收层的薄膜太阳电池是目前效率最高的铜基太阳电池.典型的铜基太阳电池通常在窗口层和吸收层间加一层CdS缓冲层作为窗口过渡层,但由于Cd有毒,CdS带隙较小,因此人们对无镉缓冲层材料进行了广泛的探索研究.综述了铜基薄膜太阳电池无镉缓冲层研究进展,指出了作为缓冲层的结构和光电特性要求,比较了各类无镉缓冲层的不同制备方法,讨论了无镉缓冲层研究中存在的问题和今后发展的方向,特别指出锌基化合物是最有潜力的无镉缓冲层材料.
参考文献
| [1] | Hall M .Empa announces 20.4％ efficient thin film CIGSon-polymercell[EB/OL].http://www.pv-magazine.corn/news/details/beitrag/empa-announces204-efficient-thin-film-cigs-on-polymer-cell _ 100009893/#axzz2YMkxEUFP,2013-7-1. |
| [2] | Man2集团携ZSW再创世界纪录薄膜电池转换效率达20.8％[EB/OL].http://solar.ofweek.com/2013-12/ART-260019-8140-28755575.html,2013-12-11. |
| [3] | Williams B .MiaSole achieves 15.7％ efficiency with commercial-scale CIGS thin film solar modules[EB/OL].http://www.businesswire.com /news/home/20101202005382/en,2013-7-3. |
| [4] | Umschlag T .Enabling CIGS mass production[EB/OL].http://www.manz.com/ products-services/manzcigs-fab/overview,2013. |
| [5] | Cu（InAl）Se2薄膜太阳电池的研究进展[J].材料导报,2012(z1):200-202,219. |
| [6] | Olopade M et al.Investigation of some materials as buffer layer in copper zinc tin sulphide (Cu2ZnSnS4) solar cells by SCAPS-1D[J].Adv Appl Sci Res,2012,3(06):3396. |
| [7] | Chelvanathan P;Hossain M et al.Performance analysis of CIGS solar cells with various buffer layers by SCAPS[J].Current Applied Physics,2010,10:387. |
| [8] | Ramli H;Kamal S et al.Optimization of zinc sulfide electron affinity in copper indium sulfide based photovoltaic cell[J].Chalcogenide Lett,2013,10(06):189. |
| [9] | 李长健;张力;熊绍珍.太阳能电池基础与应用[M].北京:科学出版社,2009 |
| [10] | Nakada T;Contreras M A.ZnO/ZnS(O,OH)/Cu(In,Ga) Se2/Mo solar cell with 18.6％ efficiency[A].Osaka,2003:570. |
| [11] | Hariskos D;Spiering S;Powalla M .Buffer layers in Cu(In,Ga)Se-2 solar cells and modules[J].Thin Solid Films: An International Journal on the Science and Technology of Thin and Thick Films,2005(0):99-109. |
| [12] | Platzer-Bjorkman C;Torndahl T;Abou-Ras D;Malmstrom J;Kessler J;Stolt L .Zn(O,S) buffer layers by atomic layer deposition in Cu(In,Ga)Se-2 based thin film solar cells: Band alignment and sulfur gradient[J].Journal of Applied Physics,2006(4):44506-1-44506-9-0. |
| [13] | Kushiya K.Progress in large-area Cu(In,Ga)Se2-based thinfilm modules with the efficiency of over 13％[A].Osaka,2003:319. |
| [14] | Ennaoui A.;Lux-Steiner MC.;Riedl W.;Karg F.;Siebentritt S. .High-efficiency Cd-free CIGSS thin-film solar cells with solution grown zinc compound buffer layers[J].Solar Energy Materials and Solar Cells: An International Journal Devoted to Photovoltaic, Photothermal, and Photochemical Solar Energy Conversion,2001(1/4):31-40. |
| [15] | Siebentritt S.;Kampschulte T.;Bauknecht A.;Blieske U.;Harneit W. Fiedeler U.;Lux-Steiner M. .Cd-free buffer layers for CIGS solar cells prepared by a dry process[J].Solar Energy Materials and Solar Cells: An International Journal Devoted to Photovoltaic, Photothermal, and Photochemical Solar Energy Conversion,2002(4):447-457. |
| [16] | Tokita Y.;Chaisitsak S.;Yamada A.;Konagai M. .High-efficiency Cu(In,Ga)Se-2 thin-film solar cells with a novel In(OH)(3): Zn2+ buffer layer[J].Solar Energy Materials and Solar Cells: An International Journal Devoted to Photovoltaic, Photothermal, and Photochemical Solar Energy Conversion,2003(1/2):9-15. |
| [17] | Huang CH.;Shafarman WN.;Chang CH.;Lambers ES.;Rieth L. Johnson JW.;Kim S.;Stanbery BJ.;Anderson TJ.;Holloway PH.;Li SS. .Study of Cd-free buffer layers using In-x(OH,S)(y) on CIGS solar cells[J].Solar Energy Materials and Solar Cells: An International Journal Devoted to Photovoltaic, Photothermal, and Photochemical Solar Energy Conversion,2001(2):131-137. |
| [18] | Ohtake Y.;Yamada A.;Konagai M.;Chaisitsak S. .Characterization of ZnInxSey thin films as a buffer layer for high efficiency Cu(InGa)Se-2 thin-film solar cells[J].Japanese journal of applied physics,1998(6A):3220-3225. |
| [19] | Negami T;Aoygi T;Satoh T.Cd-free CIGS solar cells fabricated by dry process[A].New Orleans,2002:656. |
| [20] | Spiering S.;Hariskos D.;Powalla M.;Naghavi N.;Lincot D. .CD-free Cu(In,Ga)Se-2 thin-film solar modules with In2S3 buffer layer by ALCVD[J].Thin Solid Films: An International Journal on the Science and Technology of Thin and Thick Films,2003(0):359-363. |
| [21] | Zimmermann Uwe;Marta Ruth;Marika Edoff.Cadmium-free CIGS mini-modules with ALD-grown Zn(O,S)-based buffer layers[A].Dresden,2006 |
| [22] | 孙拓 .CIGS薄膜电池会是下一代领跑者吗[N].中国能源报,2013-1-21(23). |
| [23] | 卞志强 .铜铟镓硒薄膜太阳电池无镉缓冲层ZnS薄膜研究[D].上海:华东师范大学,2009. |
| [24] | 刘军 .铜基化合物薄膜太阳能电池关键材料研究[D].广东工业大学,2013. |
| [25] | 王彩娜 .CBD-ZnS缓冲层的制备及其在CIGS电池中的应用[D].天津:南开大学,2007. |
| [26] | 敖建平 .CIGS薄膜、缓冲层材料太阳电池研究[D].天津:南开大学,2007. |
| [27] | 薛玉明 .CIGS薄膜太阳电池异质结的研究[D].南开大学,2003. |
| [28] | 薛玉明 .CIGS薄膜太阳电池材料及其表界面结构特性的研究[D].南开大学,2006. |
| [29] | 汤会香,严密,张辉,崔天峰,倪利红,杨德仁.不同络合剂对化学水浴法制备ZnS薄膜性能的影响[J].太阳能学报,2006(04):373-376. |
| [30] | 胡居广,李启文,郑彬,汤华斌,王培,罗仲宽,曹慧群,林晓东.衬底温度对PLD法沉积CdS及ZnS薄膜材料的影响[J].太阳能学报,2013(01):34-38. |
| [31] | 黄六一;栾兆菊.化学水浴沉积时间对In2S3薄膜性能的影响[J].功能材料,2010:255. |
| [32] | 江秋怡,王卿璞,王汉斌,王丹丹,武丽伟,李福杰.Zn1-xMgxO用于CIGS太阳电池的研究进展[J].半导体光电,2013(03):355-360. |
| [33] | Kessler J;Velthaus K O;Ruckh M.Chemical bath deposition of CdS on CuInSe2,etching effects and growth kinetics[A].New Del,1992:1005. |
| [34] | Nakada T;Kunioka A .Direct evidence of Cd diffusion into CIGS thin films during chemical-bath deposition process of CdS films[J].Applied Physics Letters,1999,74(17):2444. |
| [35] | Naghavi N;Abou-Ras D;Allsop N .Buffer layers and transparent conducting oxides for chalcopyrite Cu (In,Ga)(S,Se)2 based thin film photovoltacics:Present status and current developments[J].Prog Photovolt:Res Appl,2010,18(06):411. |
| [36] | Hultqvist A;Platzer-Bjorkaman C.Optimization of i-ZnO window layers for Cu(In,Ga)Se2 solar cells with ALD buffers[A].Milan,2007:2381. |
| [37] | Chaisitsak S;Sugiyama T .Cu (In,Ga)Se2 thin film solar cells with high resistivity ZnO buffer layers deposited by atomic layer deposition[J].Japanese Journal of Applied Physics,1999,38:4989. |
| [38] | Abou-Ras D;Kostorz G;Romeo A;Rudmann D;Tiwari A .Structural and chemical investigations of CBD- and PVD-CdS buffer layers and interfaces in Cu(In,Ga)Se-2-based thin film solar cells[J].Thin Solid Films: An International Journal on the Science and Technology of Thin and Thick Films,2005(0):118-123. |
| [39] | 唐茜,黎兵,刘才,李愿杰,冯良桓,李卫.磁控溅射法制备纳米级ZnS薄膜及其性能研究[J].四川大学学报（自然科学版）,2008(03):619-622. |
| [40] | 谢婧,黎兵,李愿杰,颜璞,冯良桓,蔡亚平,郑家贵,张静全,李卫,武莉莉,雷智,曾广根.射频磁控溅射法制备ZnS多晶薄膜及其性质[J].物理学报,2010(08):5749-5754. |
| [41] | Igalson M;Platzer-Bjorkman C .The influence of buffer layer on the transient behavior of thin film chalcopyrite devices[J].Solar Energy Materials and Solar Cells: An International Journal Devoted to Photovoltaic, Photothermal, and Photochemical Solar Energy Conversion,2004(1/4):93-103. |
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