Mg4Nb2O9具有与α-Al2O3相同的刚玉型晶体结构,可望成为取代氧化铝陶瓷的新一代高Q值基板陶瓷.在900～1400℃温度范围内,合成了Mg4Nb2O9化合物,采用X射线粉末衍射法进行了相结构分析.结果表明,生成物中含有Mg4Nb2O9、Mg4Nb2O6和MgO三种物相,主晶相是Mg4Nb2O9;在900～1300℃温度范围内,随着温度的升高,MgNb2O6和MgO反应生成Mg4Nb2O9相,主晶相含量线性增加,但在1300℃以上,主晶相含量随温度的升高而减小;Mg4Nb2O9相的最佳合成温度为1300℃.这些结果对研究开发Mg4Nb2O9微波基板材料有着重要的意义.
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