惣悦化铝为载体的某含钯废催化剂为原料,采用恿酸介质中添加悦化助浸剂的方案对钯恒择性浸出,并考察了焙烧,还原,浸出过程的适惚工惤条件。结果表明,钯的回收率可惣达到98%惣上。
Palladium was recovered from spent alumina-supported catalyst by the process of selective leaching using hydrochloric acid with an oxidant. The optimized conditions of roasting, reduction, leaching processes were also investigated. The results showed that the palladium recovery ratio was over 98% in the optimum condition.
参考文献
[1] | 刘时杰.铂族金属冶金学[M].长沙:中南大学出版社,2013:443-448. |
[2] | 贺小塘,郭俊梅,王欢,李勇,吴喜龙,赵雨,韩守礼,李锟,谭文进,刘文.中国的铂族金属二次资源及其回收产业化实践[J].贵金属,2013(02):82-89. |
[3] | Barakat M A;Mahmoud M H H;Mahrous Y S .Recovery and separation of palladium from spent catalyst[J].Applied Catalysis A General,2006),301:182-186. |
[4] | 汪云华,吴晓峰,童伟锋.铂族金属催化剂回收技术及发展动态[J].贵金属,2011(01):76-81. |
[5] | 吴晓峰,汪云华,范兴祥,赵家春,关晓伟,顾华祥.贵金属提取冶金技术现状及发展趋势[J].贵金属,2007(04):63-68. |
[6] | 陈景 .从原子结构探讨贵金属在提取冶金过程中的行为[J].中国工程科学,1999,2(1):34-40. |
[7] | Jin S Yoo .Metal recovery and rejuvenation of metal-loaded spent catalysts[J].Catalysis Today,1998,44:27-46. |
[8] | Roberta Santos Marinho;Julio Carlos Afonso .Recovery of platinum from spent catalyst by liquid-liquid extraction in chloride medium[J].Journal of Hazardous Materials,2010,179:488-494. |
[9] | 刘庆杰,曹秀红,贾玲,王星.从银电解阳极泥中回收铂和钯[J].有色矿冶,2010(04):35-38,41. |
[10] | 蒋志建.从含钯、铜、银等贵金属废料中回收钯和银[J].湿法冶金,2003(03):155-158. |
[11] | 张方宇;李庸华;张邦安 .从废催化剂中回收铂族金属的方法[P].中国,CN1038199,1998-04-29. |
[12] | 吴冠民;周正根 .从废催化剂回收金钯的方法[P].中国,CN91104387,1994-06-01. |
[13] | 储建华 .提取钯的冶金热力学分析[J].贵金属,1984,5(4):9-15. |
[14] | 陈景.铂族金属氧化还原反应的规律[J].贵金属,1991(01):7-16. |
[15] | 谭柯.选择性沉淀法从废催化剂中回收金属钯的研究[J].湖南冶金,2002(03):17-20. |
上一张
下一张
上一张
下一张
计量
- 下载量()
- 访问量()
文章评分
- 您的评分:
-
10%
-
20%
-
30%
-
40%
-
50%