综述了描述聚合物基复合材料导热性能的经典模型和新模型,详细列举了各模型的特点,比较了模型之间的区别,具体分析了影响复合体系导热性能的各种因素.结合对碳纳米管复合材料的研究给出了一些常用模型的应用建议,同时提出了当前研究中存在的模型通用性差的问题,指出今后聚合物基导热复合材料的研究趋势应为开发新的高导热纳米填充物和纳米复合技术以使填充物在基体中能形成有效的导热通路,从而改善复合体系的导热性能.
Many classic and new models predicting the effective thermal conductivity of polymer matrix compo-site are summarized and their different characteristics are analyzed comprehensively by comparing each other.Mean-while,factors influencing the composite's thermal conductivity are discussed in detail.Then the most frequently used models are recommended with proper application conditions according to the study of composites with carbon nano-tubes and the problem that the generality of those models is not very good is also proposed,At last,it is pointed out that the search direction of thermal conducting polymer matrix composite is as follows.New nanofillers with high ther-mal conductivity should be found and new composite technology should be developed to form effective thermal circuits in the matrix,so that the thermal property of the composite can be improved.
参考文献
| [1] | 李冰,张晓伟.环氧树脂基导热复合材料的研究进展[J].中国胶粘剂,2008(01):60-62. |
| [2] | 朱光明,王汝敏,钱德丰.聚合物基纳米复合材料的研究进展[J].材料导报,2001(10):58-61. |
| [3] | Agari Y;Uno T .Estimation on thermal conductivities of filled polymer[J].Journal of Applied Polymer Science,1986,32(07):5705. |
| [4] | 王家俊 .聚酰亚胺/氮化铝复合材料的制备与性能研究[D].浙江大学,2001. |
| [5] | Tekee H S;Kumlutas D;Tavman L H .Effect of partical shape on thermal conductivity of copper reinforced polymer composites[J].Journal of Reinforced Plastics and Composites,2007,26(01):113. |
| [6] | Tavman L H;Akinci H .Transverse thermal cpnductivity of fiber reinforced polymer composites[J].International Journal of Heat and Mass Transfer,2000,27(02):253. |
| [7] | Bigg D M .Thermal conductivity of heterophase polymer compositions[J].Advances in Polymer Science,1995,119:1. |
| [8] | 周文英,寇静利,谷宏智,杜泽强.导热绝缘聚合物复合材料研究[J].上海塑料,2005(02):19-24. |
| [9] | 李亚东,闫福丰,马亿珠,何晶.氮化铝对ABS复合材料导热性能的影响[J].塑料工业,2006(11):63-65. |
| [10] | 闵新民,安继明,饶宝林,吴伯麟.聚合物基纳米复合材料热导率计算[J].武汉理工大学学报,2007(07):26-29. |
| [11] | Agari Y;Ueda A;Nagai S .Thermal conductivities of com-posites in several types of dispersion systems[J].Journal of Applied Polymer Science,1991,42(06):1665. |
| [12] | Agari Y;Ueda A;Nagai S .Thermal conductivity of a poly-mer filled with particles in the wide range from low to super high volume content[J].Journal of Applied Polymer Science,1990,40(05):929. |
| [13] | Agari Y;Ueda A;Nagai S .Thermal conductivity of a poly-ethylene filled with disoriented shortcut carbon fibers[J].Journal of Applied Polymer Science,1991,43(06):1117. |
| [14] | Agari Y;Ueda A;Nagai S .Thermal conductivity of a poly-met composite[J].Journal of Applied Polymer Science,1993,49(09):1625. |
| [15] | 潘能升,李宾,戴干策.石墨填充PP的导热模型检验与改进[J].塑料工业,2006(02):45-47. |
| [16] | 王亮亮.聚合物基复合材料导热模型及热导率方程的研究[J].中国塑料,2005(12):12-14. |
| [17] | 梁基照,李锋华.聚合物/中空微球复合材料理论传热模型的实验验证[J].华南理工大学学报（自然科学版）,2006(01):114-116. |
| [18] | 梁基照,邱玉琳.一个新的颗粒填充聚合物复合材料导热模型[J].现代塑料加工应用,2008(06):9-12. |
| [19] | 梁基照,刘冠生.无机粒子填充聚合物复合材料传热模型及有限元模拟[J].特种橡胶制品,2006(05):35-38. |
| [20] | Liang JZ;Li FH .Simulation of heat transfer in hollow-glass-bead-filled polypropylene composites by finite element method[J].Polymer Testing,2007(3):419-424. |
| [21] | Liang JZ;Li FH .Heat transfer in polymer composites filled with inorganic hollow micro-spheres: A theoretical model[J].Polymer Testing,2007(8):1025-1030. |
| [22] | Rajinder Pal .New Models for Thermal Conductivity of Particulate Composites[J].Journal of Reinforced Plastics and Composites,2007(7):643-651. |
| [23] | Rajinder Pal .On the Lewis-Nielsen model for thermal/electrical conductivity of composites[J].Composites. Part A, Applied science and manufacturing,2008(5):718-726. |
| [24] | 何燕,马连湘,黄素逸.炭黑/橡胶体系的导热模型及应用研究[J].工程热物理学报,2009(04):671-674. |
| [25] | Carson J K .Thermal conductivity bounds for isotropic,po-rous materials[J].International Journal of Heat and Mass Transfer,2005,48:2150. |
| [26] | Wang J;Carson J K;North M F .A new approach to mo-deling the effective thermal conductivity of heterogeneous materials[J].International Journal of Heat and Mass Transfer,2006,49(17):3075. |
| [27] | M. Porfiri;N. Q. Nguyen;N. Gupta .Thermal conductivity of multiphase particulate composite materials[J].Journal of Materials Science,2009(6):1540-1550. |
| [28] | J.-M. Goyheneche;A. Cosculluela .A Multiscale Model for the Effective Thermal Conductivity Tensor of a Stratified Composite Material[J].International Journal of Thermophysics,2005(1):191-202. |
| [29] | 曾群锋,李纪云,彭旭东.聚合物基复合材料导热性能的预测模型[J].润滑与密封,2006(04):70-72,75. |
| [30] | Yang X S .Modelling heat transfer of carbon nanotubes[J].Modelling and Simulation in Materials Science and Engineering,2005,13(06):893. |
| [31] | 刘金世,薛庆忠.碳纳米管复合材料的有效热导率[J].石油大学学报（自然科学版）,2004(05):142-144. |
| [32] | Xue QZ .Model for thermal conductivity of carbon nanotube-based composites[J].Physica, B. Condensed Matter,2005(1/4):302-307. |
| [33] | Xue Q Z.Model for the effective thermal conductivity of carbon nanotube composites[J].Nanotechnology,2006:17-1655. |
| [34] | 祝春华,王端阳.碳纳米管材料导热性能的实验研究[J].广东化工,2007(08):5-9. |
| [35] | Nan C W;Liu G;Lin Y H .Interface effect on therrnal con-ductivity of carbon nanotube composites[J].Applied Physics Letters,2004,85(16):3549. |
| [36] | 吕瑞涛,黄正宏,康飞宇.高导热炭基功能材料研究进展[J].材料导报,2005(11):69-72. |
- 下载量()
- 访问量()
- 您的评分：
-
10%
-
20%
-
30%
-
40%
-
50%