用共沉淀法合成Gd2Ti2O7纳米粉体,经真空烧结制备不同ZrO2 (3Y)含量的Gd2Ti2O7/ZrO2(3Y)陶瓷.用XRD、SEM和力学性能试验等测试手段研究样品的物相、形貌和力学性能.结果表明:Gd2Ti2O7/ZrO2 (3Y)陶瓷的力学性能随ZrO2 (3Y)含量增加显著提高,ZrO2 (3Y)含量为90vol%时,样品的维氏硬度、抗弯强度和断裂韧性最大值分别达到20.95 GPa、199.21 MPa和8.17 MPa·m1/2.其原因是ZrO2 (3Y)固溶导致晶粒尺寸减小,过饱和析出ZrO2 (3Y)的颗粒弥散增韧,以及ZrO2(3Y)应力诱导相变增韧作用.
参考文献
[1] | Malkin, B.Z.;Lummen, T.T.A.;Loosdrecht, P.H.M.V.;Dhalenne, G.;Zakirov, A.R. .Static magnetic susceptibility, crystal field and exchange interactions in rare earth titanate pyrochlores[J].Journal of Physics. Condensed Matter,2010(27):276003-1-276003-11. |
[2] | Xiao H;Wang LM;Zu XT;Lian J;Ewing RC .Theoretical investigation of structural, energetic and electronic properties of titanate pyrochlores[J].Journal of Physics. Condensed Matter,2007(34):46203-1-46203-10-0. |
[3] | Chen Zhong-Jun,Tian Dong-Bin.First-principles study of disordering tendencies in Gd2B2O7 (B = Ti, Sn, Zr) compounds[J].中国物理B(英文版),2010(12):412-418. |
[4] | ZHANG Ying,DING Linghong,PANG Xinling,ZHANG Weifeng.Influence of annealing temperature on luminescent properties of Eu~(3+)/V~(5+) co-doped nanocrystalline Gd_2Ti_2O_7 powders[J].稀土学报(英文版),2009(06):900-904. |
[5] | Jiaming Zhang;Jie Lian;Fuxiang Zhang .Intrinsic Structural Disorder and Radiation Response of Nanocrystalline Gd2(Ti_(0.65)Zr_(0.35))2O7 Pyrochlore[J].The journal of physical chemistry, C. Nanomaterials and interfaces,2010(27):11810-11815. |
[6] | Todorov IT;Allan NL;Purton JA;Dove MT;Smith W .Use of massively parallel molecular dynamics simulations for radiation damage in pyrochlores[J].Journal of Materials Science,2007(6):1920-1930. |
[7] | Stewart JR;Ehlers G;Wills AS;Bramwell ST;Gardner JS .Phase transitions, partial disorder and multi-k structures in Gd2Ti2O7[J].Journal of Physics. Condensed Matter,2004(28):L321-L326. |
[8] | Dunsiger SR;Kiefl RF;Chakhalian JA;Greedan JE;MacFarlane WA;Miller RI;Morris GD;Price AN;Raju NP;Sonier JE .Magnetic field dependence of muon spin relaxation in geometrically frustrated Gd2Ti2O7[J].Physical review, B. Condensed matter and materials physics,2006(17):2418-1-2418-4-0. |
[9] | Bonville P.;Hodges JA.;Ocio M.;Sanchez JP.;Vulliet P.;Sosin S. Braithwaite D. .Low temperature magnetic properties of geometrically frustrated Gd2Sn2O7 and Gd2Ti2O7[J].Journal of Physics. Condensed Matter,2003(45):7777-7787. |
[10] | Sosin SS;Prozorova LA;Smirnov AI;Bonville P;Bras GJL;Petrenko OA .Spin dynamics of the pyrochlore magnets Gd2Ti2O7 and Gd2Sn2O7 in the paramagnetic state[J].Physical review, B. Condensed matter and materials physics,2008(10):104424-1-104424-8-0. |
[11] | M.L.Pang;J.Lin;J.Fku;Z.Y.Cheng .Luminescent properties of Gd_2Ti_2O_7:Eu~3+ phosphor films prepared by sol-gel process[J].Materials Research Bulletin: An International Journal Reporting Research on Crystal Growth and Materials Preparation and Characterization,2004(11):1607-1614. |
[12] | 郭艳艳,吴杏华,王殿元,常章用,王金亮,王庆凯,张玉霞.980 nm LD激发下稀土掺杂Gd_2Ti_2O_7粉末上转换发光[J].中国稀土学报,2009(06):735-738. |
[13] | 欧阳静,周正,伦惠林,谢亚玲,杨华明.氧化锆(ZrO2)的热、化学性质与应用[J].中国材料进展,2014(6):365-375. |
[14] | 刘纯波,林锋,蒋显亮.热障涂层的研究现状与发展趋势[J].中国有色金属学报,2007(01):1-13. |
[15] | ZrO2含量对Ni-Co-ZrO2复合镀层显微硬度和耐磨性能的影响[J].人工晶体学报,2014(06):1555-1560,1567. |
上一张
下一张
上一张
下一张
计量
- 下载量()
- 访问量()
文章评分
- 您的评分:
-
10%
-
20%
-
30%
-
40%
-
50%