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A new rare earth complex Tb(p-MBA)3phen was synthesized, which is first used as an emitting material in organic electroluminescence. By doping it into the conjugated polymer PVK, single-layer and double-layer devices were fabricated with structures: device 1: ITO/PVK∶ Tb(p-MBA)3phen/Al; device 2∶ ITO/PVK: Tb(p-MBA)3phen/AlQ/LiF/Al. The characteristics of these devices have been investigated. The emission of PVK is completely restrained, and only the pure green emission from Tb3+ can be observed in electroluminescence. The optimized device 2 has better monochromatic characteristics with the maximal brightness of 152 cd · m-2 at the voltage of 20 V.

参考文献

[1] Tang C W;VanSlyke S A .Organic electroluminescent diodes[J].Applied Physics Letters,1987,51:913.
[2] Tang C W;VanSlyke S A;Chen C H .Electroluminescence of doped organic thin films[J].Journal of Applied Physics,1989,65:3610.
[3] Burroughes J H;Bradley D D C;Brown A R et al.Light emitting diodes based on conjugated polymers[J].Nature,1990,347:539.
[4] Kido J;Nagai K;Okamoto Y et al.Electroluminescence from polysilane film doped with europium complex[J].Chemistry Letters,1991,235:1267.
[5] Kido J;Hayase H;Hongawa K et al.Bright red light emitting organic electroluminescent devices having a europium complex as an emitter[J].Applied Physics Letters,1994,65:2124.
[6] Zhao Dongxu;Hong Ziruo;Liang Chunjun et al.Enhanced electroluminescence of europium (Ⅲ) complex by terbium (Ⅲ) substitution in organic light emitting diodes[J].Thin Solid Films,2000,363:208.
[7] Zhong Guolun;Kyungkon Kim et al.Intermolecular energy transfer in photo- and electroluminescence properties of a europium (Ⅲ) complex dispersed in poly(vinylcarbazole)[J].Synthetic Metals,2002,129:193.
[8] Wang Ruifen;Wang Shuping;Shi Shikao et al.Crystal structure and properties of a terbium m-Methylbenzoate complex with 1,10-phenantheroline[J].Coord Chem,2002,55:215.
[9] Jin Linpei;Wang Mingzhao;Wang Ruifen et al.Crystal structure and luminescence of Eu2(p-CH3C6H4COO)6(C12H8N2)2 complex[J].中国科学B辑,1994,24(06):577.
[10] LIANG Chun-jun;Li Wenlian;Hong Ziruo et al.Energy transfer process from polymer to rare earth complexes[J].Synthetic Metals,1997,91:151.
[11] 肖静,邓振波,张志锋,徐登辉,徐颖,王瑞芬.Organic Light Emitting Devices Based on Terbium Complex[J].稀土学报(英文版),2004(05):615-617.
[12] 韩树民,刘宝忠,张忠,朱惜林,王晓铁,荆天辅.Phase Structure and Electrochemical Properties of RE-Mg Based Composite Hydrogen Storage Alloys[J].稀土学报(英文版),2004(06):878-881.
[13] 郭栋,梁春军,林鹏,邓振波,白峰,李勇,徐怡庄,吴瑾光.Eu(BSA)3phen与PVK共混体系的光致和电致发光特性的研究[J].中国稀土学报,2004(06):879-882.
[14] Zhang Renjie;Yang Kongzhang et al.Fluorescence lifetime and energy transfer of rare earth β-diketone complexes in organized molecular films[J].Thin Solid Films,2000,363:275.
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