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利用振动弦黏度/密度计对1,1,1,2,3,3,3七氟丙烷(HFC-227ea)的黏度和密度进行了实验研究,温度范围为243.15-363.15K,压力范围为0.54-11.49MPa,黏度和密度实验测量的不确定度分别为4-2%和4-0.2%。利用获得的实验数据分别拟合了HFC-227ea黏度和密度方程。黏度实验数据与方程的平均绝对偏差为0.71%,最大绝对偏差为2.02%;密度实验数据与方程的平均绝对偏差为0.05%,最大绝对偏差为0.15%。在本文实验范围之内,与文献实验数据进行了比较,本文实验结果与文献数据吻合较好,为HFC-227ea的进一步应用研究提供了可靠的基础数据。

The viscosity and density of l,l,l,2,3,3,3-Heptafluoropropane (HFC-227ea) were reported at temperatures from 243.15 K to 363.15 K and at pressures up to 11.49 MPa. The measurements were performed simultaneously using a vibrating-wire instrument operated in the forced mode of oscillation. The overall uncertainties of these results are ±2.0% in viscosity and ±0.2% in density. Correlations for both the viscosity and the density are presented. The average absolute deviation and the maximum absolute deviation of the viscosity measurements from the correlation are 0.71% and 2.02% respectively, and for density are 0.05% and 0.15%, respectively. Comparisons between measurements of this work and literatures are presented.

参考文献

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[2] Wang ZW;Duan YY .Vapor pressures of 1,1,1,3,3-pentafluoropropane (HFC-245fa) and 1,1,1,2,3,3,3-heptafluoropropane (HFC-227ea)[J].Journal of Chemical and Engineering Data: the ACS Journal for Data,2004(6):1581-1585.
[3] L.Fedele;F.Pernechele;S.Bobbo .Compressed Liquid Density Measurements for 1,1,1,2,3,3,3-Heptafluoropropane(R227ea)[J].Journal of Chemical and Engineering Data: the ACS Journal for Data,2007(5):1955-1959.
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[5] V. A. Gruzdev;R. A. Khairulin;S. G. Komarov;S. V. Stankus .Thermodynamic properties of HFC-227ea[J].International Journal of Thermophysics,2002(3):809-824.
[6] Laesecke A.;Hafer RF. .Viscosity of fluorinated propane isomers. 2. Measurements of three compounds and model comparisons[J].Journal of Chemical and Engineering Data: the ACS Journal for Data,1998(1):84-92.
[7] Liu Xiao-Jun .Liquid Viscosity of 1,1,1,2,3,3,3-Heptafluoropropane (HFC-227ea) along the Saturation Line[J].Journal of Chemical and Engineering Data: the ACS Journal for Data,1999(4):688-692.
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