采用射频溅射法在SnO2衬底上生长了NiOx薄膜,制备的薄膜是非理想化学计量的微晶薄膜.研究了氧分压对NiOx薄膜的溅射速率、表面形貌和光学电学特性的影响.研究结果显示,O2分压在1∶10时,可得到最快的沉积速率;低的氧分压沉积的薄膜表面比较疏松;随着氧含量的增加,方块电阻呈上升趋势,当氧分压达到一定值时,膜电阻又开始下降;随着氧分压的升高,颜色会逐渐加深,透射率降低.
参考文献
[1] | Sato H;Minami T;Takata S et al.[J].Thin Solid Films,1993,23:27. |
[2] | Ushio Y.;Niwa T.;Ishikawa A. .DEGRADATION OF THE ELECTROCHROMIC NICKEL OXIDE FILM UPON REDOX CYCLING[J].Thin Solid Films: An International Journal on the Science and Technology of Thin and Thick Films,1996(1/2):233-237. |
[3] | Granqvist C G.Handbook of Inorganic Electrochromic Materials[M].Amsterdam:Elsevier Science,1995 |
[4] | Ahn KS.;Nah YC.;Sung YE. .Surface morphological, microstructural, and electrochromic properties of short-range ordered and crystalline nickel oxide thin films[J].Applied Surface Science: A Journal Devoted to the Properties of Interfaces in Relation to the Synthesis and Behaviour of Materials,2002(1/4):259-269. |
[5] | Kumagai N;Matsumoto M;Toyoda K et al.[J].Journal of Materials Science Letters,1996,15:1081. |
[6] | Estrada W;Andersson A M;Granqvist C G .[J].Journal of Applied Physics,1988,64:3678. |
[7] | Lampert C M .[J].Solar Energy Materials,1982,11:1. |
[8] | Bogner M.;Scharnagl K.;Winter R.;Doll T.;Eisele I.;Fuchs A. .Thin (NiO)(1-x)(Al2O3)(x), Al doped and Al coated NiO layers for gas detection with HSGFET[J].Sensors and Actuators, B. Chemical,1998(1/3):145-152. |
[9] | Passerini S;Scrosati B;Gorenstein A et al.[J].Journal of the Electrochemical Society,1989,136:3394. |
[10] | Passerini S;Scrosati B;Gorenstein A .[J].Journal of the Electrochemical Society,1990,137:3297. |
[11] | Mahmoud SA.;Akl AA.;Kamal H.;Abdel-Hady K. .Opto-structural, electrical and electrochromic properties of crystalline nickel oxide thin films prepared by spray pyrolysis[J].Physica, B. Condensed Matter,2002(3/4):366-375. |
[12] | Sato Y.;Murai K.;Ando M. .Electrochromic properties of spin-coated nickel oxide films[J].Solid state ionics,1998(Special Issue SI):443-447. |
[13] | Nakaoka K;Ueyama J;Ogura K .Semiconductor and electrochromic properties of electrochemically deposited nickel oxide films[J].Journal of Electroanalytical Chemistry: An International Journal Devoted to All Aspects of Electrode Kinetics, Interfacial Structure, Properties of Electrolytes, Colloid and Biological Electrochemistry,2004(1):93-99. |
[14] | Wu S Y;Chen W F .[P].US 6652980,2003. |
[15] | Porqueras I;Bertran E .[J].Thin Solid Films,2001,398-399:41. |
[16] | Wu YG.;Ni XY.;Wu X.;Wu GM. .Ion transport in electrochromic nickel oxide thin films[J].Solar Energy Materials and Solar Cells: An International Journal Devoted to Photovoltaic, Photothermal, and Photochemical Solar Energy Conversion,2000(2):217-226. |
[17] | 冯博学,谢亮,王君,蒋生蕊,陈光华.射频溅射微晶NiOxHy膜电致变色性能及其机理研究[J].物理学报,2000(10):2066-2071. |
[18] | Thornton J A .[J].Annual Review of Materials Science,1977,7:239. |
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