采用多元醇法合成了介孔CexZr1-xO2(x=0.5～0.8)复合氧化物,并运用XRD,Raman,BET,FT-IR ,TG和H2-TPR等手段对复合氧化物进行了表征.结果表明,所制样品均为立方萤石结构的介孔铈锆固溶体复合氧化物,并具有较高的比表面积(133～181 m2·g-1)和较集中的孔径分布(3.7～7.7nm).CexZr1-xO2固溶体的晶体结构、比表面积、孔性能和还原性能均与Zr含量有关,随着zr含量的增加,样品的比表面积和孔体积增大,孔径和晶胞参数减小.
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