合成了一种新型的曼尼希碱季铵盐(BMQA)酸化缓蚀剂,通过静态失重法测试了缓蚀剂在不同浓度盐酸中的缓蚀性能。结果表明,90℃下,缓蚀剂 BMQA 在15%盐酸中加入0.1%,18%盐酸中加入0.2%,28%盐酸中加入0.5%,N80钢的腐蚀速率都能小于4 g·m-2·h-1。极化曲线测试表明该缓蚀剂是抑制阳极为主的混合型缓蚀剂,遵循 Langmuir 吸附等温式,能自发在金属表面进行化学吸附。
A new type of Mannich base quaternary ammonium salt was synthesized as an acidification corrosion inhibitor.The inhibition performance of this corrosion inhibitor was evaluated in hydrochloric acid with different concentrations by static weight loss method.The results showed that with 0.1% inhibitor in 15% hydrochloric acid, 0.2% inhibitor in 18% hydrochloric acid and 0.5% inhibitor in 28% hydrochloric acid,the corrosion rates of steel N80 were all lower than 4 g·m-2 ·h-1 at 90℃.Polarization curves indicate that the corrosion inhibitor is a mixed inhibitor but mainly prohibits the anodic corrosion process,obeys the Langmuir adsorption isothermal equation and can spontaneously absorb on the steel surface by chemisorption.
参考文献
[1] | 刘志辉,王霞,吴艺琛.曼尼希碱型酸化缓蚀剂研究进展[J].应用化工,2014(01):148-150,155. |
[2] | 张勇,陆原,张颖,胡廷,赵璐.曼尼希酸化缓蚀剂H-402的合成及其缓蚀性能研究[J].油田化学,2013(01):111-114. |
[3] | 袁志平,陈林,陈俊斌.一种酸化缓蚀剂的合成及缓蚀效果评价实验研究[J].钻采工艺,2012(02):87-89. |
[4] | 王霞,刘志辉,陈玉祥,罗全民.不同合成原料对曼尼希碱缓蚀性能的影响[J].应用化工,2013(12):2163-2166. |
[5] | 陆原,张勇,李羽,王犇,曾少云,郭海军.一种曼尼希缓蚀剂的合成及其缓蚀性能[J].腐蚀与防护,2013(06):515-517,522. |
[6] | 刘传宗.含3-二甲基氨基苯丙酮Mannich碱缓蚀剂合成与评价[J].石油化工腐蚀与防护,2013(04):4-7. |
[7] | 王红艳,卢永斌,白方林,李俊莉.一种新型Mannich碱酸化缓蚀剂的合成及性能评价[J].腐蚀科学与防护技术,2013(02):133-137. |
[8] | 赵修太,杨永飞,邱广敏.芳香酮曼尼希碱系列酸化缓蚀剂研究[J].材料保护,2007(12):60-62. |
[9] | 彭雪飞,冯浦涌,王贵,陈振宇.一种曼尼希碱季铵盐缓蚀剂的合成与性能研究[J].腐蚀与防护,2010(05):345-348. |
[10] | 宋伟伟,张静,杜敏.新型不对称双季铵盐缓蚀剂在HCl中对Q235钢的缓蚀行为[J].化学学报,2011(16):1851-1857. |
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