将TiO2光催化臭氧氧化-生物活性炭(TiO2/UV/O3-BAC)组合工艺用于处理水源水,在优化工艺参数的条件下,该工艺对水源水中溶解性有机碳(DOC)的平均去除率为46.5%, 而UV/O3-BAC工艺对DOC的平均去除率仅为41.6%. TiO2/UV/O3-BAC工艺对有机物去除的协同效应较强. TiO2/UV/O3过程将水中的大分子有机物氧化成小分子,提高了出水的可生物降解性,从而有利于后续的BAC对有机污染物的去除. TiO2/UV/O3-BAC工艺对持久性有机污染物的去除非常有效. 其中,酞酸酯的去除率均大于94%, 但随着烷基链长度的增加而降低; 多溴联苯的去除率均超过89%, 但随着溴原子取代数目的增加而降低.
参考文献
[1] | Pelizzetti E;Maurino V;Minero C;Carlin V Tosato M L Pramauro E Zerbinati O .[J].Environmental Science and Technology,1990,24(10):1559. |
[2] | Pelizzetti E;Carlin V;Minero C;Grtzel M .[J].New Journal of Chemistry,1991,15(05):351. |
[3] | Pelizzetti E;Carlin V;Minero C;Pramauro E Vincenti M .[J].Science of the Total Environment,1992,123-124:161. |
[4] | Bolduc L;Anderson W A .[J].Biodegradation,1997,8(04):237. |
[5] | Arnold S M;Hickey W J;Harris R F;Talaat R E .[J].Environmental Toxicology and Chemistry,1996,15(08):1255. |
[6] | Sarria V;Parra S;Adler N;Peringer P Benitez N Pulgarin C .[J].Catalysis Today,2002,76(2-4):301. |
[7] | Sarria V;Kenfack S;Guillod O;Pulgarin C .[J].Journal of Photochemistry and Photobiology A:Chemistry,2003,159(01):89. |
[8] | Nishijima W.;Shoto E.;Okada M.;Kim WH. .The performance of an ozonation biological activated carbon process under long term operation[J].Water Science and Technology,1998(6):163-169. |
[9] | 李来胜,祝万鹏,张彭义,陈中颖,陈乐.TiO2薄膜光催化臭氧化邻苯二酚[J].催化学报,2003(03):163-168. |
[10] | Li L Sh;Zhu W P;Chen L;Zhang P Y Chen Zh Y .[J].Journal of Photochemistry and Photobiology A:Chemistry,2005,175(2-3):172. |
[11] | Servais P;Billen G;Hascoet M-C .[J].Water Research,1987,21(04):445. |
[12] | Li L Sh;Zhu W P;Zhang P Y;Zhang Z L Wu H H Han W Y .[J].Chemosphere,2006,62(09):1514. |
[13] | Turchi C S;Ollis D F .[J].Journal of Catalysis,1990,122(01):178. |
[14] | Ohtani H.;Ichikawa Y.;Miura I. .Effects of dibutyl phthalate as an environmental endocrine disrupter on gonadal sex differentiation of genetic males of the frog Rana rugosa[J].Environmental Health Perspectives,2000(12):1189-1193. |
[15] | Muneer A;Theurich J;Bahnemann D .[J].Journal of Photochemistry and Photobiology A:Chemistry,2001,143(2-3):213. |
[16] | 杨燕红,傅家谟,盛国英,闵育顺.珠江三角洲一些城市水体中微量有机污染物的初步研究[J].环境科学学报,1998(03):271-277. |
[17] | Kristoffersen A;Voie O A;Fonnum F .[J].Toxicology Letters,2002,129(1-2):161. |
[18] | Bajt O;Mailhot G;Bolte M .[J].Applied Catalysis B:Environmental,2001,33(03):239. |
[19] | Hoque A;Sigurdson A J;Burau K D;Humphrey H E B Hess K R Sweeney A M .[J].Epidemiology,1998,9(04):373. |
上一张
下一张
上一张
下一张
计量
- 下载量()
- 访问量()
文章评分
- 您的评分:
-
10%
-
20%
-
30%
-
40%
-
50%