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  4. 无铅BaTiO3系热敏电阻及其PTC性能的研究进展

材料导报, 2012, 26(1): 24-39.

无铅BaTiO3系热敏电阻及其PTC性能的研究进展

李海龙 1, , 杨德安 2, , 曲远方 3, , 丰红军 4,

1.天津大学先进陶瓷与加工技术教育部重点实验室,天津300072

2.天津大学先进陶瓷与加工技术教育部重点实验室,天津300072

3.天津大学先进陶瓷与加工技术教育部重点实验室,天津300072

4.天津大学先进陶瓷与加工技术教育部重点实验室,天津300072

关键词： PTCR , 居里温度 , BNT , BKT , 无铅

Research Progress of BaTiO3-based Lead-free Thermistor Ceramics and Their PTC Effects

通常在BaTiO3中固溶PbTiO3来提高BaTiO3系PTCR的居里温度,但是铅的毒性和挥发性限制了BaTiO3系PTCR的应用,因此需要研制出高居里点的无铅PTCR陶瓷.随着BNT、BKT含量增加,BaTiO3系PTCR的居里点升高,但同时室温电阻快速增大.若在提高居里点的同时抑制室温电阻率的增大,就能制备出有实用价值的无铅高居里点的PTC材料.综述了BNT、BKT的含量对居里温度的影响及其机理,通过加入还原剂或在还原气氛下烧结并制定合理的烧结制度可以得到低室温电阻率和性能较好的PTC材料.

参考文献

[1] 夏新蕊 .无铅高居里温度PTC材料的研究[D].成都理工大学,2007.
[2] 曲远方.功能陶瓷及应用[M].北京:化学工业出版社,2003:1.
[3] 方志远,沈春英,丘泰.BaTiO3系PTC热敏电阻材料的研究进展[J].电子元件与材料,2010(10):69-71.
[4] S.W. Ding;G. Jia;J. Wang .Electrical properties of Y- and Mn-doped BaTiO_3-based PTC ceramics[J].Ceramics International,2008(8):2007-2010.
[5] Il-Ho Kim et al.PTCR properties of Sb2O3-doped (Ba,Sr)TiO3[J].Materials Letters,2006,60(25-26):3027.
[6] 李燕燕,李国荣,王天宝,郑嘹赢,冷森林,殷庆瑞.Nb2O5掺杂高温无铅（Ba,Bi,Na）TiO3基PTCR陶瓷结构与电性能研究[J].无机材料学报,2009(02):374-378.
[7] Jiang S L et al.Study on BaTiO3 semiconducting ceramic materials with lower resistivity[J]][J].Journal of Electroceramics,2008,21(1-4):694.
[8] He ZM;Ma J;Qu YF;Feng XM .Experimental determination of intrinsic parameters in double-donor-doped (Ba0.92Sr0.08)TiO3-based positive temperature coefficient ceramics[J].Journal of Physics. Condensed Matter,2004(39):6961-6968.
[9] Ping-Hua Xiang;Hiroaki Takeda;Tadashi Shiosaki .Positive Temperature Coefficient of Resistivity Effect of Semiconducting BaTiO_3-(Bi_(1/2)Na_(1/2))TiO_3 Ceramics Prepared by a Wet-Chemistry Route[J].Japanese journal of applied physics,2007(10b):6995-6998.
[10] Huo WR;Qu YF .Effects of Bi1/2Na1/2TiO3 on the Curie temperature and the PTC effects of BaTiO3-based positive temperature coefficient ceramics[J].Sensors and Actuators, A. Physical,2006(2):265-269.
[11] Shimada T et al.Lead free PTCR ceramics and its electrical properties[J].Journal of the European Ceramic Society,2007,27:3877.
[12] Takeda H et al.Fabrication and operation limit of lead-free PTCR ceramics using BaTiO3-(Bi1/2 Na1/2) TiO3 system[J].J Electro Ceram,2009,22:263.
[13] Leng Senlin et al.Synthesis of Y-doped BaTiO3-(Bi1/2 K1/2)-TiO3 lead-free positive temperature coefficient of resistivity ceramics and their PTC effects[J]][J].Journal of the American Ceramic Society,2009,92(11):2772.
[14] Takeda H et al.Fabrication and positive temperature coefficient of resistivity properties of semiconducting ceramics based on the BaTiO3-(Bi1/2K1/2)TiO3 system[J].Journal of the European Ceramic Society,2009,30(02):555.
[15] 冯景星 .1BaTiO3 PTC陶瓷居里温度与添加剂的关系[J].功能材料,1996,27(05):431.
[16] Ming-Long Liu;De-An Yang;Yuan-Fang Qu .Effect of sintering procedure on the resistivity of (1-x)BaTiO_(3-x)(Bi_(0.5)Na_(0.5)) TiO_3 ceramics[J].Journal of Alloys and Compounds: An Interdisciplinary Journal of Materials Science and Solid-state Chemistry and Physics,2010(2):559-564.
[17] Ming-long Liu;Yuan-fang Qu;De-an Yang .Effect of Bi_2O_3 doping methods on the positive temperature coefficient property of Ba_(0.999)(Bi_(0.5)Na_(0.5))_(0.001)TiO_3 ceramics[J].Journal of Alloys and Compounds: An Interdisciplinary Journal of Materials Science and Solid-state Chemistry and Physics,2010(1):237-241.
[18] Senlin Leng;Guorong Li;Liaoying Zheng .Influences of Ba/Ti Ratios on the Positive Temperature Coefficient of Resistivity Effect of Y-Doped BaTiO_3-(Bi_(1/2)Na_(1/2))TiO_3 Ceramics[J].Journal of the American Ceramic Society,2011(5):1340-1342.
[19] Fiorenza P et al.Direct imaging of the core-shell effect in positive temperature coefficient of resistance-BaTiO3 ceramics[J].Applied Physics Letters,2009,95:142904-142901.
[20] Xiang P H et al.High Tc lead-free BaTiO3-(Bi1/2Na1/2)TiO3 positive temperature coefficient of resistivity ceramics with electrically heterogeneous structure[J].Applied Physics Letters,2007,91:162904-162901.
[21] Senlin Leng;Liaoying Zheng;Guorong Li;Jiangtao Zeng;Qingrui Yin;Zhijun Xu;Ruiqing Chu .Impedance spectroscopy analysis for high-T_c BaTiO_3-(Bi_(1/2)Na_(1/2))TiO_3 lead-free PTCR ceramics[J].Physica status solidi, A. Applications and materials science ePSS,2011(5):1099-1104.
[22] Young Hun Jeong;Chul-Min Kim;Chang-D Kim .Enhanced PTCR Characteristics of 0.95BaTiO_3-0.05(Bi_(0.5)Na_(0.5))TiO_3 Ceramics Fabricated by Modified Synthesis Process[J].Journal of the Electrochemical Society,2011(2):J27-J31.
[23] Meng Wei;Yong-ping Pu;Yuqin Mao;Jinfei Wang .Effect of the Reoxidation on Positive Temperature Coefficient Behavior of BaTiO_3-Bi_(0.5)Na_(0.5)TiO_3[J].Journal of the American Ceramic Society,2010(6):1527-1529.
[24] Wei Jifeng et al.Fabrication of high Tc lead free(1-x)BaTiO3-xBi0.5K0.5 TiO3 positive temperature coefficient of resistivity ceramics using reoxidation method[J].Journal of Materials Science:Materials in Electronics,2011,22:551.
[25] Victor Shut et al.PTCR barium titanate ceramics obtained from oxalate-derived powders with varying crystallinity[J].Journal of Materials Science,2008,43:5251.
[26] Wei Li;Zhijun Xu;Ruiqing Chu;Peng Fu;Yanjie Zhang .Synthesis and characterization of (Na_0.85K_0.15)_0.5Bi_0.5TiO_3 ceramics by different methods[J].Materials Research Bulletin: An International Journal Reporting Research on Crystal Growth and Materials Preparation and Characterization,2011(6):871-874.
[27] Xiang P H et al.Annealing effects on the characteristics of high Tc lead-free barium titanate-based positive temperature coefficient of resistivity ceramics[J].Journal of Applied Physics,2008,104:094108-094101.
[28] Wang J F;Pu Y P;Yang G G et al.Microstructure and electrical properties of lead free PTCR cerarnics[J].Materials Research Innovations,2009,13(04):455.
[29] Tadashi Shiosaki.Development of lead-free PTC thermistor materials[A].Sunset Beach,NC,USA,2007:156.
[30] Takeda H et al.Fabrication of lead-free and high Tc BaTiO3-based thermistor ceramics using deoxidizing effect of oxygen-containing a-zirconium[J].Ceramics International,2008,34(08):2073.
[31] Takeda H.Fabrication and PTC properties of lead-free element-modified barium titanate semiconducting ceramics with Tc》130℃[A].Nara,2008:805.
[32] Liu F;Qu YF .Effect of sintering atmosphere on Ni/PTC composites ceramics[J].The journal of physics and chemistry of solids,2007(1):41-44.
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