本文提出了一种直接利用废玻璃制备硅灰石玻璃陶瓷的新工艺:反应析晶烧结法.将高岭土和碳酸钙为主要原料合成的析晶促进剂加入到废玻璃粉末中烧结,通过两者间的反应析出硅灰石.研究了析晶促进剂含量和烧结温度对硅灰石玻璃陶瓷的组织、烧结和性能的影响,结果表明:随着析晶促进剂含量的增加,玻璃陶瓷的体密度和开孔隙率增加,强度先增后降.提高烧结温度促进反应析晶,并导致玻璃陶瓷的体密度、开孔隙率和强度降低.析晶促进剂含量为15％,烧结温度为850℃时,制得的硅灰石玻璃陶瓷的力学性能最佳.
参考文献
| [1] | 毛必明 .新型建材-微晶玻璃板材的制造及展望[J].陶瓷研究,1996,11(04):199-200. |
| [2] | 邓再德,曾惠丹,英廷照.硅灰石型烧结微晶玻璃及其应用前景[J].玻璃与搪瓷,2001(01):42-45. |
| [3] | 刘军;邢军;童粤明 等.尾矿建筑微晶玻璃成分的研究[J].新型建筑材料,1998,25(10):15-16. |
| [4] | 何峰,许超,袁坚.CaO-Al2O3-SiO2系统微晶玻璃的成分、结构与性能[J].武汉工业大学学报,1998(02):20-23. |
| [5] | Barbieri L.;Ferrari A.M. .Crystallization of (Na_2O_MgO)-CaO-Al_2O_3-SiO_2 Glassy Systems Formulated from Waste Products[J].Journal of the American Ceramic Society,2000(10):2515-2520. |
| [6] | E. Bernardo;R. Castellan;S. Hreglich .Sintered glass-ceramics from mixtures of wastes[J].CERAMICS INTERNATIONAL,2007(1):27-33. |
| [7] | Yeong-Hum Yun;Chung-Han Yoon;Yun-Ho Kim;Chi-Kyoon Kim;Sang-Bok Kim;Jeong-Tae Kwon;Bo-An Kang;Kyu-Seog Hwang .Glass-ceramics prepared by waste fluorescent glass[J].Ceramics International,2002(5):503-505. |
| [8] | 梁晓娟,周永强,刘海涛.废玻璃在建筑微晶玻璃中的应用研究[J].中国陶瓷,2006(05):49-51. |
| [9] | 曾华瑞,阮玉忠,于岩,刘慧颍.氟化钙晶核剂对废啤酒瓶微晶玻璃的影响[J].硅酸盐通报,2008(02):345-348,354. |
| [10] | 林剑英,阮玉忠,曾华瑞.Cr2O3对废建筑玻璃研制的微晶玻璃结构及性能影响[J].中国陶瓷,2009(02):27-29,22. |
| [11] | Yoon SD;Yun YH .Waste glass and fly ash derived glass-ceramic[J].Journal of Materials Science,2006(13):4315-4319. |
| [12] | Wei-yi Zhang;Hong Gao;Buo-yu Li .A novel route for fabrication of machinable fluoramphibole glass-ceramics[J].Scripta materialia,2006(3):275-278. |
| [13] | 章为夷,高宏.可加工氟闪石玻璃陶瓷的制备[J].人工晶体学报,2006(06):1392-1396. |
| [14] | 章为夷,高宏.氟云母加入量对可加工氟闪石玻璃陶瓷反应析晶的影响[J].硅酸盐学报,2007(10):1396-1400. |
| [15] | 章为夷,高宏,张力明.反应析晶烧结法制备可加工氟闪石玻璃陶瓷致密化研究[J].硅酸盐通报,2009(05):1088-1092,1096. |
| [16] | Wei Yi Zhang;Hong Gao;Yu Xu .Sintering and reactive crystal growth of diopside-albite glass-ceramics from waste glass[J].Journal of the European Ceramic Society,2011(9):1669-1675. |
| [17] | Yun Y H;Yun S D;Park H R et al.Preparation of β-wollastonite glass-ceramics[J].J Mater Syn Proce,2002,10(04):205-209. |
| [18] | Yun YH.;Yoon CH.;Oh JS.;Kim SB.;Kang BA.;Hwang KS. .Waste fluorescent glass and shell derived glass-ceramics[J].Journal of Materials Science,2002(15):3211-3215. |
| [19] | Enrico Bernardo;Giovanni Scarinci .Fast-Sintered Gehlenite Glass-Ceramics from-Plasma-Vitrified Municipal Solid Waste Incinerator Fly Ashes[J].Journal of the American Ceramic Society,2009(2):528-530. |
| [20] | Stefan Kemethmuller;Marcel Hagymasi;Alfons Stiegelschmitt .Viscous Flow as the Driving Force for the Densmcation of Low-Temperature Co-Fired Ceramics[J].Journal of the American Ceramic Society,2007(1):64-70. |
| [21] | Aldo R. Boccaccini;Reinhard Conradt .Isotropic shrinkage of platelet containing glass powder compacts during isothermal sintering[J].International journal of inorganic materials,2001(2):101-106. |
| [22] | 章为夷.混合烧结法在玻璃陶瓷制备中的应用[J].硅酸盐通报,2011(05):1110-1113. |
| [23] | Barbieri L;Corradi A;Lancellotti I et al.Sintering and crystallisation behaviour of glass frits made from silicate wastes[J].Glass Technology,2003,44(05):184-190. |
| [24] | E. Bernardo;R. Castellan;S. Hreglich .Sintered glass-ceramics from mixtures of wastes[J].CERAMICS INTERNATIONAL,2007(1):27-33. |
上一张
下一张
上一张
下一张
计量
- 下载量()
- 访问量()
文章评分
- 您的评分：
-
10%
-
20%
-
30%
-
40%
-
50%