近紫外光激发的白光LED用单基质硅酸盐荧光粉的研究进展

材料导报, 2009, 23(9): 25-34.

近紫外光激发的白光LED用单基质硅酸盐荧光粉的研究进展

章少华 ^1, , 周明斌 ^2, , 胡江峰 ^3, , 谢冰 ^4,

1.南昌大学材料科学与工程学院,南昌,330031

2.南昌大学材料科学与工程学院,南昌,330031

3.南昌大学材料科学与工程学院,南昌,330031

4.南昌大学分析测试中心,南昌,330047

关键词：近紫外激发 , 白光LED , 单基质 , 硅酸盐荧光粉

Research Progress in Preparation of Single Phase Silicate Phosphor for NUV-white Light Emitting Diodes

白光LED被称作第4代照明光源,有着庞大的应用市场.荧光粉光转换白光LED是当今固态照明的主流方案.研制近紫外光激发的白光LED用单基质硅酸盐荧光粉具有十分重要的意义.综述了目前国内外这一领域的研究进展,并指出了当前存在的问题及未来的发展方向.

参考文献

[1]	梁春广.半导体照明灯[J].半导体技术,2000(01):1.
[2]	余德芳 .新型的半导体光源--白光LED[J].世界电子元器件,2000,15(03):46.
[3]	刘行仁.白光LED固态照明光转换荧光体[J].发光学报,2007(03):291-301.
[4]	Kuo C H;SheuJ K;Chang S J et al.N-UV+blue/green/red white light emitting diode lamps[J].Japanese Journal of Applied Physics,2003,42(4B):2284.
[5]	Jong Su KIM;Ji Young KANG;Pyung Eun JEON;Jin Chul CHOI;Hong Lee PARK;Tae Whan KIM .GaN-Based White-Light-Emitting Diodes Fabricated with a Mixture of Ba_3MgSi_2O_8:Eu~(2+) and Sr_2SiO_4:Eu~(2+) Phosphors[J].Japanese journal of applied physics,2004(3):989-992.
[6]	Kim JS;Jeon PE;Park YH;Choi JC;Park HL;Kim GC;Kim TW .White-light generation through ultraviolet-emitting diode and white-emitting phosphor[J].Applied physics letters,2004(17):3696-3698.
[7]	孙晓园,张家骅,张霞,刘慎薪,蒋大鹏,王笑军.新一代白光LED照明用一种适于近紫外光激发的单一白光荧光粉[J].发光学报,2005(03):404-406.
[8]	夏威,王细凤.白光LED用宽谱激发智能型硅酸盐发光材料[J].材料导报,2007(08):插1.
[9]	Thomas L Barry .Fluorescence of Eu2+-activated phase in binary alkaline earth orthosilicae systems[J].J Eiectrochem Soc,1968,115(11):1181.
[10]	Copeland TS.;Lee BI.;Qi J.;Elrod AK. .Synthesis and luminescent properties of Mn2+-doped zinc silicate phosphors by sol-gel methods[J].Journal of Luminescence: An Interdisciplinary Journal of Research on Excited State Processes in Condensed Matter,2002(3-4):168-173.
[11]	张迈生,祁家雄,杨燕生.Sol-Gel法和微波辐射法合成亚纳米级Zn2SiO4：Mn2+，Er3+高效绿色荧光体[J].发光学报,1999(03):258-261.
[12]	乔彬,张中太,唐子龙,张俊英,王晓欣.Eu2+, Mn2+共激活碱土镁硅酸盐基红色荧光粉的发光性能[J].中国稀土学报,2003(02):192-195.
[13]	徐叙珞;苏勉曾.发光学与发光材料[M].北京:化学工业出版社,2004
[14]	Menkara;Hisham;Summers et al.Light emitting device having silicate fluorescent phosphor[P].US,6982045,2006-01-03.
[15]	Zhang XL;He H;Li ZS;Yu T;Zou ZG .Photoluminescence studies on EU2+ and Ce3+-doped Li2SrSiO4[J].Journal of Luminescence: An Interdisciplinary Journal of Research on Excited State Processes in Condensed Matter,2008(12):1876-1879.
[16]	Srivastava;Alok Mani;Duggal et al.Phosphors for light generation from light emitting semiconductors[P].US,6255670,2001-07-03.
[17]	J. S. Kim;P. E. Jeon;J. C. Choi;H. L. Park;S. I. Mho;G. C. Kim .Warm-white-light emitting diode utilizing a single-phase full-color Ba_(3)MgSi_(2)O_(8):Eu~(2+), Mn~(2+) phosphor[J].Applied physics letters,2004(15):2931-2933.
[18]	王继磊,王达健,李岚,蒙延双,张纳,李光旻.硅酸盐单基质白光LED荧光体的制备和光谱性质[J].发光学报,2006(04):463-468.
[19]	WANG Da-Jian,WANG Ji-Lei,LI Lan.Colour Tuning of Single Host Phosphors for White Light by Al Addition[J].中国物理快报（英文版）,2006(08):2247-2250.
[20]	Sung Hun Lee et al.White-light-emitting phosphor:CaMgSi2O5 Eu2+,Mn2+ and its related properties with blending[J].Applied Physics Letters,2006,89(22):221916.
[21]	Dent GLS;GlasserFP .SilicatesM3SiO5.I.Sr3SiO5[J].Acta Crystallographica,1965,18(03):453.
[22]	Dent G L S .Silicates M3SiO5.Ⅱ.Relationships between Sr3 SiO5,Cd3 SiO5 and Ca3 SiO5[J].Acta Crystallographica,1965,18(03):455.
[23]	杨志平,刘玉峰,熊志军,徐小岭,李盼来.Sr2MgSiO5：（Eu2+,Mn2+）单一基质白光荧光粉的发光性质[J].硅酸盐学报,2006(10):1195-1198.
[24]	杨志平,刘玉峰,王利伟,余泉茂,熊志军,徐小岭.用于白光LED的单一基质白光荧光粉Ca2SiO3Cl2：Eu2+,Mn2+的发光性质[J].物理学报,2007(01):546-550.
[25]	Shen Changyu;Yang Yi;Jin Shangzhong .Synthesis and luminous characteristics of Ba2SiO3Cl2:Eu2+,Mn2+ phosphor for white LED[J].Light-emitting Diode Materials and Devices,2007,Ⅱ(6828):82815.
[26]	Ananias A D;Carlos B L D;Rocha J .Unusual fuU-colour phosphors:Naa LnSi3O9[J].Optical Materials,2006,28(06):582.
[27]	Ci Zhipeng;Wang Yuhua et al.Ca1-x,Mo1-ySiyO4:Eu3+:A novel red phosphor for white light emitting diodes[J].Physical Review B:Condensed Matter,2008,403(04):670.
[28]	山田健一,姜伟.Ca（Eu1-xLax）4Si3O13红色荧光粉的研究及其在三基色白光LED上的应用[J].中国照明电器,2005(08):24-29.
[29]	Raju GSR;Buddhudu S .Emission analysis of Eu3+ : MgLaLiSi2O7 powder phosphor[J].Physica, B. Condensed Matter,2008(4):619-623.
[30]	乔彬,张中太,唐子龙,张俊英,王晓欣.Eu2+, Mn2+共激活碱土镁硅酸盐基红色荧光粉的发光性能[J].中国稀土学报,2003(02):192-195.
[31]	杨志平,王少丽,杨广伟,田晶,李盼来,李旭.Sr2SiO4：Sm3+红色荧光粉的发光特性[J].硅酸盐学报,2007(12):1587-1589.
[32]	Raju GSR;Buddhudu S .Emission analysis of Sm3+ and Dy3+: MgLaLiSi2O7 powder phosphors[J].Spectrochimica acta, Part A. Molecular and biomolecular spectroscopy,2008(3):601-605.
[33]	张中太;张俊英.无机光致发光材料及应用[M].北京:化学工业出版社,2005
[34]	庄卫东,胡运生,张书生,何华强,黄小卫.高效低光衰LED用红色荧光粉的研制[C].海峡两岸第十届照明科技与营销研讨会论文集,2003:44-51.
[35]	张凯,刘河洲,胡文彬.白光LED用荧光粉的研究进展[J].材料导报,2005(09):50-53.
[36]	巨荣玲,胡晓珊,吕振刚,方英,崔屾,姚琲,王慧,庄卫东.若干物理处理方法对稀土荧光粉Y2O3：Eu3+发光性能的影响[J].中国稀土学报,2007(04):412-416.
[37]	蒋建清;董岩;于金等.一种荧光粉的后处理方法[P].中国,1664050A,2005-09-07.
[38]	崔洪涛,张耀文,洪广言.荧光粉的表面包覆[J].功能材料,2001(06):564-567,579.
[39]	杨庆华,李李泉,王海波.BaSi2 O5：Pb荧光粉表面性能的改善[J].发光学报,2007(01):83-87.

上一张下一张

计量

下载量()
访问量()

作者相关

文章评分

您的评分：
1

0%
2

0%
3

0%
4

0%
5

0%

材料期刊网

近紫外光激发的白光LED用单基质硅酸盐荧光粉的研究进展

Research Progress in Preparation of Single Phase Silicate Phosphor for NUV-white Light Emitting Diodes

参考文献