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采用溶胶-凝胶工艺制备了Ce掺杂六方相WO3光催化剂,Ce掺杂的摩尔分数分别为0、1%、2%、3%和5%.采用XRD和SEM表征了催化剂的结构,研究了Ce掺杂、热处理温度对WO3催化剂结构和光解水制氢性能的影响.结果表明:Ce掺杂提高了WO3催化剂的光催化活性.Ce掺杂摩尔分数为2%、热处理温度为400℃、催化剂用量为0.2g时,Ce掺杂WO3催化剂的光催化活性最好,光解水制氢速率为6.5,μmol/h.

参考文献

[1] 吴玉琪;吕功煊;李树本.纳米WO3粉体的制备与光催化活性研究[J].化学学报,2004(12):1134-1138.
[2] Sun DL.;Heusing S.;Puetz J.;Aegerter MA..Influence of water on the electrochemical properties of (CeO2)(x)(TiO2)(1-x) and WO3 sol-gel coatings and electrochromic devices[J].Solid state ionics,20031/4(1/4):181-189.
[3] 沈毅;颜莎宁;赵丽;曹元媛.热处理温度对WO3薄膜微观结构和光致变色性能的影响[J].稀有金属材料与工程,2010(z1):504-507.
[4] Anukorn Phuruangrat;Dong Jin Ham;Suk Joon Hong.Synthesis of hexagonal WO3 nanowires by microwave-assisted hydrothermal method and their electrocatalytic activities for hydrogen evolution reaction[J].Journal of Materials Chemistry: An Interdisciplinary Journal dealing with Synthesis, Structures, Properties and Applications of Materials, Particulary Those Associated with Advanced Technology,20109(9):1683-1690.
[5] 徐宇兴;唐子龙;张中太.六方相氧化钨纳米线的制备及氨敏特性[J].稀有金属材料与工程,2009(z2):932-934.
[6] 杜俊平;陈启元;赵娟;李洁.铈掺杂WO3的表征及其光解水催化性能的研究[J].无机化学学报,2007(6):1005-1010.
[7] 傅小明;杨在志;徐艳.水热条件对合成WO3纳米棒形貌和光吸收特性的影响[J].人工晶体学报,2011(1):242-246.
[8] 余长林;杨凯;余济美;彭鹏;操芳芳;李鑫;周晓春.稀土Ce掺杂对ZnO结构和光催化性能的影响[J].物理化学学报,2011(2):505-512.
[9] Bamwenda GR.;Arakawa H..The photoinduced evolution of O-2 and H-2 from a WO3 aqueous suspension in the presence of Ce4+/Ce3+[J].Solar Energy Materials and Solar Cells: An International Journal Devoted to Photovoltaic, Photothermal, and Photochemical Solar Energy Conversion,20011(1):1-14.
[10] 王添辉;李越湘;彭绍琴;吕功煊;李树本.铂修饰的稀土掺杂TiO2的光催化制氢活性[J].化学学报,2005(9):797-801.
[11] F.B.Li;X.Z.Li;M.F.Hou.Photocatalytic degradation of 2-mercaptobenzothiazole in aqueous La~(3+)-TiO_2 suspension for odor control[J].Applied Catalysis, B. Environmental: An International Journal Devoted to Catalytic Science and Its Applications,20043(3):185-194.
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