采用聚酰胺-胺(PAMAM)树状分子化学修饰方法制备碳纳米管接枝炭纤维(CF-PAMAM-CNTs)新型增强体.利用X射线光电子能谱(XPS)、扫描电子显微镜(SEM)和原子力显微镜(AFM)对接枝前后CF表面官能团和表面形貌进行表征;利用接触角测量、单丝拉伸方法研究了接枝前后纤维单丝的润湿性能及拉伸强度,并通过微脱黏法分析了其复合材料的界面剪切强度,同时探索了CNTs的最佳接枝量.结果表明,当CNTs接枝量为15%时,CF表面粗糙度提高了180%,表面能提高了300%,拉伸强度提高了22%,复合材料的界面剪切强度提高了178%,这表明CNTs接枝有利于改善CF复合材料的界面性能.
参考文献
[1] | 夏春霞,闫亚明,邓蜀平,白光君,蒋云峰,宋惠森,王钰.PAN基炭纤维经济规模分析[J].新型炭材料,2001(04):58-62. |
[2] | Han Gi Chae;Young Ho Choi;Marilyn L. Minus;Satish Kumar .Carbon Nanotube Reinforced Small Diameter Polyacrylonitrile Based Carbon Fiber[J].Composites science and technology,2009(3/4):406-413. |
[3] | M.F.De Riccardis;D.Carbone;Th.Dikonimos Makris .Anchorage of carbon nanotubes grown on carbon fibres[J].Carbon: An International Journal Sponsored by the American Carbon Society,2006(4):671-674. |
[4] | B. O. Boskovic;V. B. Golovko;M. Cantoro .Low temperature synthesis of carbon nanofibres on carbon fibre matrices[J].Carbon,2005(13):2643-2648. |
[5] | 赵建国,刘朗,郭全贵,史景利,翟更太,宋进仁.炭纤维表面生长碳纳米管[J].新型炭材料,2008(01):12-16. |
[6] | Laachaehi A .A chemieal method to graft carbon nanotobes onto a carbon fiber Materialsl[J].Materials Letters,2008,62:394-397. |
[7] | Yi-Tao Liu;Wei Zhao;Zhen-Yu Huang .Noncovalent surface modification of carbon nanotubes for solubility in organic solvents[J].Carbon: An International Journal Sponsored by the American Carbon Society,2006(8):1613-1616. |
[8] | Sager R J;Klein P J;Lagoudas D C et al.Effect of carbon nanotubes on the inteffacial shear strength of T650 carbon fiber in an epoxy matrix[J].Composites Science and Technology,2009,69:898-904. |
[9] | Sharma, S.P.;Lakkad, S.C. .Compressive strength of carbon nanotubes grown on carbon fiber reinforced epoxy matrix multi-scale hybrid composites[J].Surface & Coatings Technology,2010(2):350-355. |
[10] | Xiaodong He;Fuhua Zhang;Rongguo Wang .Preparation of a carbon nanotube/carbon fiber multi-scale reinforcement by grafting multi-walled carbon nanotubes onto the fibers[J].Carbon: An International Journal Sponsored by the American Carbon Society,2007(13):2559-2563. |
[11] | Mei L;He X D;Li Y B et al.Grafting carbon nanotubes onto carbon fiber by use of dendrimers[J].Materials Letters,2010,64:2505-2508. |
[12] | 杨应奎,邱胜强,王贤保,解孝林.碳纳米管的聚合物功能化与结构控制:聚合物接枝碳纳米管[J].化学进展,2010(04):684-695. |
[13] | WANG Xiaodong,TIAN Yong,PENG Xiaofeng.Self-aggregation of vapor-liquid phase transition[J].自然科学进展(英文版),2003(06):451-456. |
[14] | Wu E;Yen C S .The contact behavior between laminated composite plates and rigid spheres[J].Journal of pplied Mechanics,1994,61:60-66. |
上一张
下一张
上一张
下一张
计量
- 下载量()
- 访问量()
文章评分
- 您的评分:
-
10%
-
20%
-
30%
-
40%
-
50%