石墨烯是单原子厚度的二维碳原子晶体,也是性能优异的新型纳米复合填料.近三年来,石墨烯从概念上的二维材料变成现实材料,在化学和物理学界均引起轰动.通过述评氧化石墨及氧化石墨烯的制备、结构、改性及其与聚合物的复合,展望了石墨烯及其复合材料的研究前景,认为通过机械剥离氧化石墨可规模化制备氧化石墨烯,进一步将其化学改性并制备复合材料已取得较大进展,这一途径被认为足石墨烯规模化应用的战略起点.
参考文献
| [1] | Geim AK;Novoselov KS .The rise of graphene[J].Nature materials,2007(3):183-191. |
| [2] | Meyer J C;Geim A K;Katsnelson M I et al.The structure of suspended graphene sheets[J].Nature,2007,446(7131):60-63. |
| [3] | K. S. Novoselov;D. Jiang;F. Schedin;T. J. Booth;V. V. Khotkevich;S. V. Morozov;A. K. Geim .Two-dimensional atomic crystals[J].Proceedings of the National Academy of Sciences of the United States of America,2005(30):10451-10453. |
| [4] | Novoselov K S;Geim A K;Morozov S V et al.Electric field effect in atomically thin carbon films[J].Science,2004,306(5696):666-669. |
| [5] | Michael J.McAllister;Je-Luen Li;Douglas H.Adamson .Single Sheet Functionalized Graphene by Oxidation and Thermal Expansion of Graphite[J].Chemistry of Materials: A Publication of the American Chemistry Society,2007(18):4396-4404. |
| [6] | Paci J T;Belytschko T;Schatz G C .Computational studies of the structure,behavior upon heating,and mechanical properties of graphite oxide[J].Journal of Physical Chemistry C,2007,111(49):18099-18111. |
| [7] | Stankovich S;Dikin DA;Dommett GHB;Kohlhaas KM;Zimney EJ;Stach EA;Piner RD;Nguyen ST;Ruoff RS .Graphene-based composite materials[J].Nature,2006(7100):282-286. |
| [8] | Dikin, DA;Stankovich, S;Zimney, EJ;Piner, RD;Dommett, GHB;Evmenenko, G;Nguyen, ST;Ruoff, RS .Preparation and characterization of graphene oxide paper[J].Nature,2007(7152):457-460. |
| [9] | HUMMERS W;OFFEMA R .Preparation of graphitic oxide[J].Journal of the American Chemical Society,1958,80:1339. |
| [10] | Nakajima T;Matsuo Y .Formation process and structure of graphite oxide[J].CARBON,1994,32(03):469-475. |
| [11] | Peckett JW.;Gougeon RD.;Poppl A.;Harris RK.;Hudson MJ.;Trens P. .Electrochemically oxidised graphite. Characterisation and some ion exchange properties[J].Carbon: An International Journal Sponsored by the American Carbon Society,2000(3):345-353. |
| [12] | Hudson M J;Hunter-Fujita F R;Peckett J W et al.Electrochemically prepared colloidal,oxidised graphite[J].Journal of Materials Chemistry,1997,7:301-3115. |
| [13] | Halina Kaczmarek;Andrzej Podgorski .Photochemical and thermal behaviours of poly(vinyl alcohol)/graphite oxide composites[J].Polymer Degradation and Stability,2007(6):939-946. |
| [14] | 傅玲,刘洪波,邹艳红,李波.Hummers法制备氧化石墨时影响氧化程度的工艺因素研究[J].炭素,2005(04):10-14. |
| [15] | Matsuo Y.Preparation of intercalation compounds of graphite oxide[J].Tanso,2007(228):2119-2214. |
| [16] | Hannes C.Schniepp;Je-Luen Li;Michael J.McAllister;Hiroaki Sai;Margarita Herrera-Alonso .Functionalized Single Graphene Sheets Derived from Splitting Graphite Oxide[J].The journal of physical chemistry, B. Condensed matter, materials, surfaces, interfaces & biophysical,2006(17):8535-8539. |
| [17] | Boehm H P;Scholz W .124.New results on the chemistry of graphite oxide[J].Carbon,1968,6(02):226. |
| [18] | T. Szabo;E. Tombacz;E. Illes .Enhanced acidity and pH-dependent surface charge characterization of successively oxidized graphite oxides[J].Carbon: An International Journal Sponsored by the American Carbon Society,2006(3):537-545. |
| [19] | Lerf A;Buchsteiner A;Pieper J;Schottl S;Dekany I;Szabo T;Boehm HP .Hydration behavior and dynamics of water molecules in graphite oxide[J].The journal of physics and chemistry of solids,2006(5/6):1106-1110. |
| [20] | Nakajima T;Mabuchi A;Hagiwara R .A new structure model of graphite oxide[J].Carbon,1988,26(03):357-361. |
| [21] | He HY.;Forster M.;Lerf A.;Klinowski J. .A new structural model for graphite oxide[J].Chemical Physics Letters,1998(1/2):53-56. |
| [22] | He H;Riedl T;Left A et al.Solid-state NMR studies of the structure of graphite oxide[J].Journal of Physical Chemistry,1996,100(51):19954-19958. |
| [23] | Anton Lerf;Heyong He;Thomas Riedl;Michael Forster;Jacek Klinowski .~(13)C and ~1H MAS NMR studies of graphite oxide and its chemically modified derivatives[J].Solid state ionics,1997(2):857-862. |
| [24] | Mermoux M;Chabre Y;Rousseau A .FTIR and 13C NMR study of graphite oxide[J].CARBON,1991,29(03):469-474. |
| [25] | Anton Lerf;Heyong He;Michael Forster;Jacek Klinowski .Structure of Graphite Oxide Revisited[J].The journal of physical chemistry, B. Condensed matter, materials, surfaces, interfaces & biophysical,1998(23):4477-4482. |
| [26] | Buchsteiner A;Lerf A;Pieper J .Water dynamics in graphite oxide investigated with neutron scattering[J].The journal of physical chemistry, B. Condensed matter, materials, surfaces, interfaces & biophysical,2006(45):22328-22338. |
| [27] | Teplykh AE;Bogdanov SG;Dorofeev YA;Pirogov AN;Skryabin YN;Makotchenko VG;Nazarov AS;Fedorov VE .Structural state of expanded graphite prepared from intercalation compounds[J].Crystallography reports,2006(Suppl.1):S62-S66. |
| [28] | 昆山舒美超声仪器有限公司 .系列超声波清洗器原理[EB/OL].http://www.ks-csyq.com/gsgj.htm,2007-10-10. |
| [29] | P.Ramesh;S.Bhagyalakshmi;S.Sampath .Preparation and physicochemical and electrochemical characterization of exfoliated graphite oxide[J].Journal of Colloid and Interface Science,2004(1):95-102. |
| [30] | Sasha Stankovich;Dmitriy A. Dikin;Richard D. Piner .Synthesis of graphene-based nanosheets via chemical reduction of exfoliated graphite oxide[J].Carbon: An International Journal Sponsored by the American Carbon Society,2007(7):1558-1565. |
| [31] | Matsuo Y.;Niwa T.;Sugie Y. .Prepartion and characterization of cationic surfactant-intercalated graphite oxide[J].Carbon: An International Journal Sponsored by the American Carbon Society,1999(6):897-901. |
| [32] | 韩志东,王建祺.氧化石墨的制备及其有机化处理[J].无机化学学报,2003(05):459-461. |
| [33] | Wang WP.;Pan CY. .Synthesis and characterizations of poly(ethylene oxide) methyl ether grafted on the expanded graphite with isocyanate groups[J].European Polymer Journal,2004(3):543-548. |
| [34] | Sasha Stankovich;Richard D. Finer;SonBinh T. Nguyen .Synthesis and exfoliation of isocyanate-treated graphene oxide nanoplatelets[J].Carbon: An International Journal Sponsored by the American Carbon Society,2006(15):3342-3347. |
| [35] | Bourlinos AB.;Gournis D.;Petridis D.;Szabo T.;Szeri A.;Dekany I. .Graphite oxide: Chemical reduction to graphite and surface modification with primary aliphatic amines and amino acids[J].Langmuir: The ACS Journal of Surfaces and Colloids,2003(15):6050-6055. |
| [36] | Herrera-Alonso M;Abdala AA;McAllister MJ;Aksay IA;Prud'homme RK .Intercalation and stitching of graphite oxide with diaminoalkanes[J].Langmuir: The ACS Journal of Surfaces and Colloids,2007(21):10644-10649. |
| [37] | Liu ZH.;Wang ZM.;Yang XJ.;Ooi KT. .Intercalation of organic ammonium ions into layered graphite oxide[J].Langmuir: The ACS Journal of Surfaces and Colloids,2002(12):4926-4932. |
| [38] | Yoshiaki Matsuo;Tadaaki Miyabe;Tomokazu Fukutsuka .Preparation and characterization of alkylamine-intercalated graphite oxides[J].Carbon: An International Journal Sponsored by the American Carbon Society,2007(5):1005-1012. |
| [39] | Yoshiaki Matsuo;Kazuya Hatase;Yosohiro Sugie .Monomer emission from pyrene adsorbed in surfactant-intercalated graphite oxide[J].Chemical communications,1999(1):43-44. |
| [40] | Y. Matsuo;Y. Nishino;T. Fukutsuka .Introduction of amino groups into the interlayer space of graphite oxide using 3-aminopropylethoxysilanes[J].Carbon: An International Journal Sponsored by the American Carbon Society,2007(7):1384-1390. |
| [41] | Y. Matsuo;K. Watanabe;T. Fukutsuka .Characterization of n-hexadecylalkylamine-intercalated graphite oxides as sorbents[J].Carbon: An International Journal Sponsored by the American Carbon Society,2003(8):1545-1550. |
| [42] | Y. Matsuo;T. Tabata;T. Fukunaga .Preparation and characterization of silylated graphite oxide[J].Carbon: An International Journal Sponsored by the American Carbon Society,2005(14):2875-2882. |
| [43] | Yoshiaki Matsuo;Tomokazu Fukutsuka;Yosohiro Sugie .Preparation and Fluoroescent Properties of Rhodamine B-hexadecylamine-intercalated Graphite Oxide Thin Film[J].Chemistry Letters,2003(11):1004-1005. |
| [44] | Yoshiaki Matsuo;Tomokazu Fukutsuka;Yosohiro Sugie .Monomeric Dispersion of Covalently Attached Pyrene Chromophores in Silylated Graphite Oxide[J].Chemistry Letters,2006(5):530-531. |
| [45] | Chao Xu;Xiaodong Wu;Junwu Zhu .Synthesis of amphiphilic graphite oxide[J].Carbon: An International Journal Sponsored by the American Carbon Society,2008(2):386-389. |
| [46] | Nicholas A. Kotov;Imre Dekany;Janos H. Fendler .Ultrathin Graphite Oxide-Polyelectrolyte Composites Prepared by Self-Assembly: Transition Between Conductive and Non-Conductive States[J].Advanced Materials,1996(8):637-641. |
| [47] | Sasha Stankovich;Richard D.Piner;Xinqi Chen;Nianqiang Wu;SonBinh T.Nguyen;Rodney S.Ruoff .Stable aqueous dispersions of graphitic nanoplatelets via the reduction of exfoliated graphite oxide in the presence of poly(sodium 4-styrenesulfonate)[J].Journal of Materials Chemistry: An Interdisciplinary Journal dealing with Synthesis, Structures, Properties and Applications of Materials, Particulary Those Associated with Advanced Technology,2006(2):155-158. |
| [48] | 邹艳红,刘洪波,傅玲,陈宗璋.氧化石墨在H2还原过程中的结构与性能变化[J].中国有色金属学报,2005(06):940-945. |
| [49] | Fawn M. Uhl;Charles A. Wilkie .Preparation of nanocomposites from styrene and modified graphite oxides[J].Polymer Degradation and Stability,2004(2):215-226. |
| [50] | Rongfang Ding;Yuan Hu;Zhou Gui;Ruowen Zong;Zuyao Chen;Weicheng Fan .Preparation and characterization of polystyrene/graphite oxide nanocomposite by emulsion polymerization[J].Polymer Degradation and Stability,2003(3):473-476. |
| [51] | Wen-Ping Wang;Cai-Yuan Pan .Preparation and characterization of polystyrene/graphite composite prepared by cationic grafting polymerization[J].Polymer: The International Journal for the Science and Technology of Polymers,2004(12):3987-3995. |
| [52] | 杨建国,牛文新,李建设,吴承佩,丁延伟.聚苯乙烯/氧化石墨纳米复合材料的制备与性能[J].高分子材料科学与工程,2005(05):55-58. |
| [53] | Seredych M;Pietrzak R;Bandosz TJ .Role of graphite oxide (GO) and polyaniline (PANI) in NO2 reduction on GO-PANI composites[J].Industrial & Engineering Chemistry Research,2007(21):6925-6935. |
| [54] | Rabin Bissessur;Peter K.Y.Liu;Wade White;Stephen F.Scully .Encapsulation of Polyanilines into Graphite Oxide[J].Langmuir: The ACS Journal of Surfaces and Colloids,2006(4):1729-1734. |
| [55] | 邹艳红,吴婧,刘洪波,陈宗璋.聚苯胺/氧化石墨的合成及其在DNA识别上的应用[J].新型炭材料,2005(04):360-364. |
| [56] | 胡源,张蕤,徐加艳,宋磊,范维澄.聚丙烯酰胺/氧化石墨纳米复合材料的研究[J].材料科学与工艺,2003(04):337-339. |
| [57] | 徐加艳,胡源,宋磊,王清安,范维澄,陈祖耀.聚丙烯酰胺/氧化石墨纳米复合材料的制备及其表征[J].火灾科学,2001(02):92-94. |
| [58] | Jiayan Xu;Yuan Hu;Lei Song;Qingan Wang;Weicheng Fan .Preparation and characterization of polyacrylamide-intercalated graphite oxide[J].Materials Research Bulletin: An International Journal Reporting Research on Crystal Growth and Materials Preparation and Characterization,2001(10):1833-1836. |
| [59] | Jiayan Xu;Yuan Hu;Lei Song .Thermal analysis of poly(vinyl alcohol)/graphite oxide intercalated composites[J].Polymer Degradation and Stability,2001(1):29-31. |
| [60] | Xu J Y;Hu Y;Song L et al.Preparation and characterization of poly (vinyl alcohol) /graphite oxide nanocomposite[J].Carbon,2002,40(03):450-451. |
| [61] | Hua L;Kai WH;Inoue Y .Crystallization Behavior of poly(epsilon-caprolactone)/graphite oxide composites[J].Journal of Applied Polymer Science,2007(6):4225-4232. |
| [62] | Hua L;Kai W;Inoue Y .Synthesis and characterization of poly(epsilon-caprolactone)-graphite oxide composites[J].Journal of Applied Polymer Science,2007(3):1880-1884. |
| [63] | Kai WH;Hirota Y;Hua L;Inoue Y .Thermal and mechanical properties of a poly(epsilon-caprolactone)/graphite oxide composite[J].Journal of Applied Polymer Science,2008(3):1395-1400. |
| [64] | Rabin Bissessur;Peter K.Y. Liu;Stephen F. Scully .Intercalation of polypyrrole into graphite oxide[J].Synthetic Metals,2006(16/17):1023-1027. |
| [65] | Yongqin Han;Yun Lu .Preparation and characterization of graphite oxide/polypyrrole composites[J].Carbon: An International Journal Sponsored by the American Carbon Society,2007(12):2394-2399. |
| [66] | Kovtyukhova N I;Ollivier P J;Martin B R et al.Layer-bylayer assembly of ultrathin composite films from micron-sized graphite oxide sheets and polycations[J].CHEMISTRY OF MATERIALS,1999,11(03):771-778. |
| [67] | Cassagneau T.;Fendler JH.;Guerin F. .Preparation and characterization of ultrathin films layer-by-layer self-assembled from graphite oxide nanoplatelets and polymers[J].Langmuir: The ACS Journal of Surfaces and Colloids,2000(18):7318-7324. |
| [68] | Tamas Szabo;Anna Szeri;Imre Dekany .Composite graphitic nanolayers prepared by self-assembly between finely dispersed graphite oxide and a cationic polymer[J].Carbon: An International Journal Sponsored by the American Carbon Society,2005(1):87-94. |
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