,用DMM代替甲醇进行重整制氢是一种为燃料电池提供移动氢源的新方案.DMM重整制氢需要兼具酸性和金属的双功能复合催化剂,其中酸性组分应当具有很高的DMM水解活性.硝酸处理的高表面积酸性碳材料H-HSPRC(由酚醛树脂碳化得到)具有很高的DMM水解活性,其与传统的CuZnAI催化剂组成的复合催化剂CuZnAl-H-HSPRC具有很高的DMM重整制氢速率,513K时生成H2的速率可达7410ml/(g·h),高于相同温度下CuZnAI催化剂上甲醇重整的产H2速率.
参考文献
| [1] | Masamoto J;Iwaisako 1;Chohno M;Kawamura M Ohtake J Matsuzaki K .[J].Journal of Applied Polymer Science,1993,50:1299. |
| [2] | Yuan Y Z;Liu H C;Imoto H;Shido T Iwasawa Y .[J].Journal of Catalysis,2000,195:51. |
| [3] | Liu H C;lglesia E .[J].Journal of Catalysis,2004,223:161. |
| [4] | FuYC;Shen JY.[J].Chemical Communications,2007:2172. |
| [5] | Fu Y C;Shen J Y .[J].Journal of Catalysis,2007,248:101. |
| [6] | Venin K D;Ohi J M;Naegeli D W;Childress K H Hagen G P McCarthy C I Cheng A S Dibble R W .SAE Technical Paper Series 1999-01-1508 (reprinted from SAE SP-1458)[R].,1999. |
| [7] | Tsutsumi Y;Nakano Y;Kajitani S;Yamashita S .[J].Electrochemistry,2002,70:984. |
| [8] | Kerangueven G;Berna A;Sibert E;Feliu J M Leger J M .[J].Electrochimica Acta,2008,54:394. |
| [9] | 程极源;俞华根;王华明 .[J].天然气化工,1994,19(02):4. |
| [10] | Satoh S;Tanigawa Y .[P].US 6379507,2002. |
| [11] | Liu H C;Iglesia E .[J].Journal of Physical Chemistry B,2003,107:10840. |
| [12] | Yuan Y Z;lwasawa Y .[J].dPhys Chem B,2002,106:4441. |
| [13] | Liu J W;Fu Y C;Sun Q;Shen J Y .[J].Microporous and Mesoporous Materials,2008,116:614. |
| [14] | Liu J W;Sun Q;Fu Y C;Zhao H Y Auroux A Shen J Y .[J].Catalysis Letters,2008,126:155. |
| [15] | Royer S;Secordel X;Brandhorst M;Dumeignil F;Cristol S;Dujardin C;Capron M;Payena E;Dubois JL .Amorphous oxide as a novel efficient catalyst for direct selective oxidation of methanol to dimethoxymethane[J].Chemical communications,2008(7):865-867. |
| [16] | Liu H C;Bayat N;Iglesia E .[J].Angewandte Chemie International Edition,2003,42:5072. |
| [17] | EImi A S;Tronconi E;Cristiani C;Martin J P G,Forzatti P,Busca G .[J].Industrial and Engineering Chemistry Research,1989,28:387. |
| [18] | Briand L E;Bonetto R D;Sanchez M A;Thomas H J .[J].Catalysis Today,1996,32:205. |
| [19] | Herrmann J M;Disdier J;Deo G;Wachs I E .[J].Journal of the Chemical Society,Faraday Transactions,1997,93:1655. |
| [20] | Tatibouet J M .[J].Applied Catalysis A:General,1997,148:213. |
| [21] | Makedonski L;Nikoiov V;Anastasov A;Stancheva M .[J].Reaction Kinetics and Catalysis Letters,2004,81:21. |
| [22] | Tronconi E;Elmi A S;Ferlazzo N;Forzatti P,Busca G,Tittarelli P .[J].Lnd Eng Chem Res,1987,26:1269. |
| [23] | Forzatti E;Tronconi E;Elmi A S;Busca G .[J].Applied Catalysis A:General,1997,157:387. |
| [24] | Tsai C C;Teng H S .[J].CHEMISTRY OF MATERIALS,2004,16:4352. |
| [25] | Poudel B;Wang W Z;Dames C;Huang J Y,Kunwar S,Wang D Z,Banerjee D,Chert (3,Ren Z E .[J].Nanotechnology,2005,16:1935. |
| [26] | Dubois J L;Brandhorst M;Capron M;Dujardin C .[P].WO 2007034264,2007. |
| [27] | Zhang Q D;Tan Y Sh;Yang C H;Han Y Zh .[J].Catalysis Communications,2008,9:1916. |
| [28] | Cortright RD;Davda RR;Dumesic JA .Hydrogen from catalytic reforming of biomass-derived hydrocarbons in liquid water.[J].Nature,2002(6901):964-967. |
| [29] | Qi A D;Wang S D;Fu G Z;Ni C J Wu D Y .[J].Applied Catalysis A:General,2005,281:233. |
| [30] | Panik E J .[J].Journal of Power Sources,1998,71:36. |
| [31] | Amphlett J C;Mann R F;Peppley B A;Roberge P R,Rodrigues A,Salvador J E .[J].Journal of Power Sources,1998,71:179. |
| [32] | Moon D J;Sreekumar K;Lee S D;Lee B G Kim H S .[J].Applied Catalysis A:General,2001,215:1. |
| [33] | Song C;Reddy K M .[J].Applied Catalysis A:General,1999,176:1. |
| [34] | Shen J E;Song C .[J].Catalysis Today,2002,77:89. |
| [35] | Shen H;Fu Y C;Sun Q;Zuo S L Auroux A Shen J Y .[J].Catalysis Communications,2008,9:801. |
| [36] | Chinchen G C;Spencer M S;Waugh K C;Whan D A .[J].J Chem Soc Faraday Trans,1987,83:2193. |
| [37] | Fisher I A;Bell A T .[J].Journal of Catalysis,1999,184:357. |
| [38] | Takeguchi T;Yanagisawa K I;Inui T;Inoue M .[J].Applied Catalysis A:General,2000,192:201. |
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