选用新型稀土β成核剂(WBGⅡ)对无规共聚聚丙烯(PPR)进行政性.借助广角X射线衍射(WAXD)、差示扫描量热仪(DSC)及偏光显微镜(POM)研究了稀土β成核剂诱导无规共聚聚丙烯的结晶行为及晶体形态;并研究了WBGⅡ对PPR力学性能和热变形温度(HDT)的影响.结果表明,加入少量WBGⅡ后,PPR的晶型和结晶形态均发生变化;非等温结晶过程的结晶温度(Tc)从95.8℃提高到102.1℃;PPR的冲击强度提高24%,拉伸和弯曲性能却略有下降;热变形温度提高20℃.
参考文献
[1] | Vincenzo Busico;Roberta Cipullo .Microstructure of polypropylene[J].Progress in Polymer Science,2001(3):443-533. |
[2] | Yamamoto Y;Inoue Y;Onai T;Doshu C;Takahashi H;Uehara H .Deconvolution analyses of differential scanning calorimetry profiles of beta-crystallized polypropylenes with synchronized X-ray measurements[J].Macromolecules,2007(8):2745-2750. |
[3] | E.Lezak;Z.Bartczak;A.Galeski .Plastic Deformation of the γ Phase in Isotactic Polypropylene in Plane-Strain Compression[J].Macromolecules,2006(14):4811-4819. |
[4] | Claudio De Rosa;Finizia Auriemma .Structural-Mechanical Phase Diagram of Isotactic Polypropylene[J].Journal of the American Chemical Society,2006(34):11024-11025. |
[5] | Jin Y;Hiltner A;Baer E;Masirek R;Piorkowska E;Galeski A .Formation and transformation of smectic polypropylene nanodroplets[J].Journal of Polymer Science, Part B. Polymer Physics,2006(13):1795-1803. |
[6] | 王雯霏,上官勇刚,彭懋,郑强.规聚丙烯结晶及生长转变行为[J].高分子材料科学与工程,2005(02):24-27,32. |
[7] | J. X. Li;W. L. Cheung;Demin Jia .A study on the heat of fusion of #beta#-polypropylene[J].Polymer: The International Journal for the Science and Technology of Polymers,1999(5):1219-1222. |
[8] | Li JX.;Cheung WL. .On the deformation mechanisms of beta-polypropylene: 1. Effect of necking on beta-phase PP crystals[J].Polymer: The International Journal for the Science and Technology of Polymers,1998(26):6935-6940. |
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