采用臭氧处理聚丙烯微孔膜,在其表面引入过氧化物,然后通过过氧化物的分解引发丙烯酸单体在微孔膜表面接枝.研究了臭氧处理条件、接枝反应条件对聚丙烯微孔膜的接枝率、亲水性及溶胀性的影响.研究结果表明,丙烯酸接枝微孔膜与水的接触角随接枝率的增加而逐渐下降,吸水率随接枝率的增加而呈线性增加趋势,表现出良好的亲水性与溶胀性.
参考文献
[1] | Gineste J L;Pourcelly G .[J].Journal of Membrane Science,1995,107:155-164. |
[2] | Hirotsu Toshihiro .[J].Industrial and Engineering Chemistry Research,1987,26:1287-1290. |
[3] | Shim J K;Na H S;Lee Y M et al.[J].Journal of Membrane Science,2001,90:215-226. |
[4] | Ma H M;Davis R H;Bowman C N .[J].Macromolecules,2000,33:331-335. |
[5] | Kou RQ.;Xu ZK.;Deng HT.;Liu ZM.;Seta P.;Xu YY. .Surface modification of microporous polypropylene membranes by plasma-induced graft polymerization of alpha-allyl glucoside[J].Langmuir: The ACS Journal of Surfaces and Colloids,2003(17):6869-6875. |
[6] | Shan B;Yan H;Shen J;Lin SC .Ozone-induced grafting of a sulfoammonium zwitterionic polymer onto low-density polyethylene film for improving hemocompatibility[J].Journal of Applied Polymer Science,2006(6):3697-3703. |
[7] | Kokatnur V R;Jelling M .[J].Journal of the American Chemical Society,1941,63:1432. |
[8] | Jun Y;Akiyoshi Y;Kunji L et al.[J].Journal of Applied Polymer Science,1991,43:1197-1203. |
[9] | O'Neill T .[J].Journal of Polymer Science Part A:Polymer Chemistry,1972,10:569. |
上一张
下一张
上一张
下一张
计量
- 下载量()
- 访问量()
文章评分
- 您的评分:
-
10%
-
20%
-
30%
-
40%
-
50%