在质子交换膜燃料电池(PEMFC)阴极中,电化学反应速率较低,且反应气体传递缓慢,阴极成为限制PEMFC性能提高的主要因素之一.在阴极中发生着各种物理、化学、电学、电化学过程.从孔隙尺度研究有助于深刻理解这些过程.本文利用格子-Boltzmann方法(LBM)研究了PEMFC阴极中的流动、反应物和生成物的传质、质子传递和电化学反应过程.提出了综合模拟阴极中发生的过程的VCCP-LBM方案.讨论了利用VCCP-LBM模拟得到的结果.
参考文献
[1] | Hui Li;Yanghua Tang;Zhenwei Wang;Zheng Shi;Shaohong Wu;Datong Song;Jianlu Zhang;Khalid Fatih;Jiujun Zhang;Haijiang Wang;Zhongsheng Liu;Rami Abouatallah;Antonio Mazza .A review of water flooding issues in the proton exchange membrane fuel cell[J].Journal of Power Sources,2008(1):103-117. |
[2] | N.P. Siegel;M.W. Ellis;D.J. Nelson;M.R. von Spakovsky .A two-dimensional computational model of a PEMFC with liquid water transport[J].Journal of Power Sources,2004(2):173-184. |
[3] | Z.H.Wang;C.Y.Wang;K.S.Chen .Two-phase flow an transport in the air cathode of proton exchange membrane fuel cells[J].Journal of Power Sources,2001(1):40-50. |
[4] | J.P. Feser;A.K. Prasad;S.G. Advani .Experimental characterization of in-plane permeability of gas diffusion layers[J].Journal of Power Sources,2006(2):1226-1231. |
[5] | Sinha PK;Wang CY .Liquid water transport in a mixed-wet gas diffusion layer of a polymer electrolyte fuel cell[J].Chemical Engineering Science,2008(4):1081-1091. |
[6] | J. Park;M. Matsubara;X. Li .Application of lattice Boltzmann method to a micro-scale flow simulation in the porous electrode of a PEM fuel cell[J].Journal of Power Sources,2007(1):404-414. |
[7] | Sullivan SP;Sani FM;Johns ML;Gladden LF .Simulation of packed bed reactors using lattice Boltzmann methods[J].Chemical Engineering Science,2005(12):3405-3418. |
[8] | M. Secanell;B. Carnes;A. Suleman;N. Djilali .Numerical optimization of proton exchange membrane fuel cell cathodes[J].Electrochimica Acta,2007(7):2668-2682. |
[9] | Sukkee Um;C.-Y. Wang .Computational Fluid Dynamics Modeling of Proton Exchange Membrane Fuel Cells[J].Journal of the Electrochemical Society,2000(12):4485-4493. |
上一张
下一张
上一张
下一张
计量
- 下载量()
- 访问量()
文章评分
- 您的评分:
-
10%
-
20%
-
30%
-
40%
-
50%