综述了近年来用于检测CO2、CH4、CO、NQx和H2等常见气体的金属氧化物气敏材料的最新研究进展.针对气体检测的不同需求,介绍了现阶段主要使用的金属氧化物气敏材料的结构和成分,重点阐述了目前能达到的最佳检测效果,简要分析了部分金属氧化物的制备工艺,并展望其未来发展方向.
参考文献
| [1] | YANGH;FLOWERRJ;THOMPSON JR .Shalegas:pollution fears in China[J].NATURE,2013,499:154-157. |
| [2] | GUBPTA B L .GB-2004N industrial sensor technologies and markets[R].Nowalk,US:Business Communication Company,2004. |
| [3] | Chen Chen;Robert W. Newcomb;Yiding Wang .A trace methane gas sensor using mid-infrared quantum cascaded laser at 7.5 μm[J].Applied physics, B. Lasers and optics,2013(4):491-501. |
| [4] | SEIYAMA T;KATO A;FUJIISHI K et al.A new detector for gaseous components using semiconductive thin films[J].Analytical Chemistry,1962,34:1502-1503. |
| [5] | 李平;余萍;肖定全 .气敏传感器的近期进展[J].功能材料,1999,30(2):127-132. |
| [6] | SEIYAMA T;KATO A;FUJIISHI K et al.A new detector for gaseous components using semiconductive thin films[J].Analytical Chemistry,1962,34:1502-1503. |
| [7] | Tetsuya Kida;Kengo Shimanoe;Masayoshi Yuasa .Preparation of a Stable Sol Suspension of Pd-Loaded SnO2 Nanocrystals by a Photochemical Deposition Method for Highly Sensitive Semiconductor Gas Sensors[J].ACS applied materials & interfaces,2012(8):4231-4236. |
| [8] | WANG Z J;LI Z Y;JIANG T et al.Ultrasensitive hydrogen sensor based on Pd-loaded SnO2 electrospun nanofibers at room temperature[J].Applied Materials Interfaces,2013,5:2013-2021. |
| [9] | Dario Buso;Michael Post;Carlo Cantalini;Paul Mulvaney;Alessandro Martucci .Gold Nanoparticle-doped Tio_2 Semiconductor Thin Films: Gas Sensing Properties[J].Advanced functional materials,2008(23):3843-3849. |
| [10] | 赵义芬,赵鹤云,吴心惠.金属氧化物半导体气敏材料的研究进展[J].传感器世界,2009(01):6-11,20. |
| [11] | 刘海峰,彭同江,孙红娟,马国华,段涛.气敏材料敏感机理研究进展[J].中国粉体技术,2007(04):42-45. |
| [12] | BARSAN N;WEIMAR U .Conduction model of metal oxide gas sensors[J].Journal of Electroceramics,2001,7:143-167. |
| [13] | Massimiliano D'Arienzo;Davide Cristofori;Roberto Scotti .New Insights into the SnO2 Sensing Mechanism Based on the Properties of Shape Controlled Tin Oxide Nanoparticles[J].Chemistry of Materials: A Publication of the American Chemistry Society,2013(18):3675-3686. |
| [14] | BAI ShouLi,SHI BingJie,MA LiJing,YANG PengCheng,LIU ZhiYong,LI DianQing,CHEN AiFan.Synthesis of LaFeO_3 catalytic materials and their sensing properties[J].中国科学B辑（英文版）,2009(12):2106-2113. |
| [15] | Rebholz, J.;Bonanati, P.;Jaeschke, C.;Hübner, M.;M?dler, L.;Weimar, U.;Barsan, N..Conduction mechanism in undoped and antimony doped SnO_2 based FSP gas sensors[J].Sensors and Actuators, B. Chemical,2013:631-636. |
| [16] | Zeng, W;Liu, TM .Hydrogen sensing characteristics and mechanism of nanosize TiO2 dope with metallic ions[J].Physica, B. Condensed Matter,2010(2):564-568. |
| [17] | Xu JQ;Han JJ;Zhang Y;Sun Y;Xie B .Studies on alcohol sensing mechanism of ZnO based gas sensors[J].Sensors and Actuators, B. Chemical,2008(1):334-339. |
| [18] | Jaehyun Kim;Kijung Yong .Mechanism Study of ZnO Nanorod-Bundle Sensors for H2S Gas Sensing[J].The journal of physical chemistry, C. Nanomaterials and interfaces,2011(15):7218-7224. |
| [19] | BAI ShouLi,SHI BingJie,MA LiJing,YANG PengCheng,LIU ZhiYong,LI DianQing,CHEN AiFan.Synthesis of LaFeO_3 catalytic materials and their sensing properties[J].中国科学B辑（英文版）,2009(12):2106-2113. |
| [20] | Korotcenkov, G;Han, SD;Cho, BK;Brinzari, V .Grain Size Effects in Sensor Response of Nanostructured SnO2-and In2O3-Based Conductometric Thin Film Gas Sensor[J].Critical Reviews in Solid State and Materials Sciences,2009(1/2):1-17. |
| [21] | ZAI J T;ZHU J;QI R R et al.Nearly monodispersed In(OH)3 hierarchical nanospheres and nanocubes:tunable ligand-assisted synthesis and their conversion into hierarchical In2O3 for gas sensing[J].Journal of Materials Chemistry:A,2013,1:735-745. |
| [22] | MA J M;ZHANG J;WANG S R et al.Superior gas-sensing and lithium-storage performance SnO2 nanocrystals synthesized by hydrothermal method[J].Cryst Eng Comm,2011,13:6077-6081. |
| [23] | 位莉,苏慧兰,张荻.纳米结构金属氧化物气敏材料的研究进展[J].机械工程材料,2013(01):5-9,80. |
| [24] | KIM M Y;CHOI Y N;BAE J M et al.Carbon dioxide sensitivity of La-doped thick film tin oxide gas sensor[J].Ceramics International,2012,38(1):657-660. |
| [25] | ANDREA H;JU M .A novel thick film conductive type CO2 sensor[J].Sensors and Actuators:B,1996,34(2):388-395. |
| [26] | Herrán, J.;Fernández-González, O.;Castro-Hurtado, I.;Romero, T.;G Mandayo, G.;Casta?o, E. .Photoactivated solid-state gas sensor for carbon dioxide detection at room temperature[J].Sensors and Actuators, B. Chemical,2010(2):368-372. |
| [27] | HARIDAS D;CHOWDHURI A;SREENIVAS K et al.Enhanced response characteristics of SnO2 thin film loaded with nanoscale catalytic clusters for Methane gas[J].Materials Research Society Symposium Proceedings,2013,1303:169-176. |
| [28] | MEENAKSHI CHOUDHARY;V.N. MISHRA;R. DWIVEDI .Pd-Doped Tin-Oxide-Based Thick-Film Sensor Array for Detection of H_2, CH_4, and CO[J].Journal of Electronic Materials,2013(9):2793-2802. |
| [29] | Shao-Lin Zhang;Jeong-Ok Lim;Jeung-Soo Huh;Wooyoung Lee .Selective Growth of ZnO Nanorods and Its Gas Sensor Application[J].IEEE sensors journal,2012(11):3143-3148. |
| [30] | PATI S;MAITY A;BANERJI P et al.Qualitative and quantitative differentiation of gases using ZnO thin film gas sensors and pattern recognition analysis[J].ANALYST,2014,139:1796-1800. |
| [31] | Yuan Zhang;Jiaqiang Xu;Qun Xiang .Brush-Like Hierarchical ZnO Nanostructures: Synthesis, Photoluminescence and Gas Sensor Properties[J].The journal of physical chemistry, C. Nanomaterials and interfaces,2009(9):3430-3435. |
| [32] | Nguyen Van Hieu;Nguyen Due Khoang;Do Dang Trung;Le Due Toan;Nguyen Van Duy;Nguyen Due Hoa .Comparative study on CO_2 and CO sensing performance of LaOCl-coated ZnO nanowires[J].Journal of hazardous materials,2013(Jan.15):209-216. |
| [33] | Li, Y.-J.;Li, K.-M.;Wang, C.-Y.;Kuo, C.-I.;Chen, L.-J. .Low-temperature electrodeposited Co-doped ZnO nanorods with enhanced ethanol and CO sensing properties[J].Sensors and Actuators, B. Chemical,2012(1):734-739. |
| [34] | A. A. Zhukova;A. N. Shatokhin;F. N. Putilin;I. A. Petukhov;M. N. Rumyantseva;A. M. Gaskov .Effect of Surface Modification with Palladium on the CO Sensing Properties of Antimony-Doped SnO_2 Whiskers[J].Inorganic materials,2013(10):1005-1010. |
| [35] | SINGH A K;PATIL S B;NAKATE U T et al.Effect of Pd and Au sensitization of bath deposited flowerlike TiO2 thin films on CO sensing and photocatalytic properties[J].Journal of Chemistry,2013,2013:370578-370585. |
| [36] | HEIDARI E K;MARZBANRAD E;ZAMANI C et al.Nanocasting synthesis of ultrafine WO3 nanoparticles for gas sensing applications[J].Nanoscale Research Letter,2010,5:370-373. |
| [37] | Chao Zhang;Marc Debliquy;Abdelhamid Boudiba;Hanlin Liao;Christian Coddet .Sensing properties of atmospheric plasma-sprayed WO3 coating for sub-ppm NO2 detection[J].Sensors and Actuators, B. Chemical,2010(1):280-288. |
| [38] | Shi, L.;Naik, A.J.T.;Goodall, J.B.M.;Tighe, C.;Gruar, R.;Binions, R.;Parkin, I.;Darr, J. .Highly sensitive ZnO nanorod- and nanoprism-based NO_2 gas sensors: Size and shape control using a continuous hydrothermal pilot plant[J].Langmuir: The ACS Journal of Surfaces and Colloids,2013(33):10603-10609. |
| [39] | Mei Chen;Zhihua Wang;Dongmei Han .Porous ZnO Polygonal Nanoflakes: Synthesis, Use in High-Sensitivity NO2 Gas Sensor, and Proposed Mechanism of Gas Sensing[J].The journal of physical chemistry, C. Nanomaterials and interfaces,2011(26):12763-12773. |
| [40] | K. Vijayalakshmi;C. Ravidhas;V. Vasanthi Pillay;D. GopalaKrishna .Influence of deposition parameters and heat treatment on the NO_2 sensing properties of nanostructured indium tin oxide thin film[J].Thin Solid Films: An International Journal on the Science and Technology of Thin and Thick Films,2011(10):3378-3382. |
| [41] | Kwak, Y.;Wang, J.;Meang, S.;Kim, G.-H. .Hydrogen sensing properties of dielectrophoretically assembled SnO _2 nanoparticles on CMOS-compatible micro-hotplates[J].Nanotechnology,2011(44):445501-1-445501-5. |
| [42] | Huang, H;Lee, YC;Tan, OK;Zhou, W;Peng, N;Zhang, Q .High sensitivity SnO2 single-nanorod sensors for the detection of H-2 gas at low temperature[J].Nanotechnology,2009(11):115501-1-115501-5-0. |
| [43] | O. Lupan;V.V. Ursaki;G. Chai;L. Chow;G.A. Emelchenko;I.M. Tiginyanu;A.N. Gruzintsev;A.N. Redkin .Selective hydrogen gas nanosensor using individual ZnO nanowire with fast response at room temperature[J].Sensors and Actuators, B. Chemical,2010(1):56-66. |
| [44] | J.J. Hassan;MA Mahdi;C.W. Chin.Room temperature hydrogen gas sensor based on ZnO nanorod arrays grown on a SiO_2/Si substrate via a microwave-assisted chemical solution method[J].Journal of Alloys and Compounds: An Interdisciplinary Journal of Materials Science and Solid-state Chemistry and Physics,2013:107-111. |
| [45] | Zhaojie Wang;Zhenyu Li;Jinghui Sun .Improved Hydrogen Monitoring Properties Based on p-NiO/n-SnO2 Heterojunction Composite Nanofibers[J].The journal of physical chemistry, C. Nanomaterials and interfaces,2010(13):6100-6105. |
| [46] | Chia-Ming Chang;Min-Hsiung Hon;Ing-Chi Leu .Outstanding H2 Sensing Performance of Pd Nanoparticle-Decorated ZnO Nanorod Arrays and the Temperature-Dependent Sensing Mechanisms[J].ACS applied materials & interfaces,2013(1):135-143. |
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