综述了介孔材料的合成方法、分类、形成机理、形貌控制和应用.目前各种形状如球形、棒状、片状、螺旋形和绳形等形状的介孔材料已经采用溶胶-凝胶、自组装、微乳、反胶束和超声等方法合成出来.按化学组成介孔材料分为硅基和非硅介孔材料,硅基介孔材料已被很好地研究,相反,非硅介孔材料虽然有着广泛的应用前景但研究不多.介孔材料的几种形成机理已经被提出, 主要包括液晶模板和协同组装机理.作者也采用化学超声和反胶束方法制备出新奇的介孔二氧化钛粉末和薄膜材料, 其光催化活性明显高于普通二氧化钛粉末和薄膜材料.
参考文献
[1] | 吴庆生;郑能武 .The Synthesis of Molecule and Preparation of Nonomaterials[J].化学世界,1999,5(05):233-235. |
[2] | 张立德 .The Research Actuality and Develepment of Nonomaterials[J].现代科学仪器,1998,1(01):27-29. |
[3] | 陈艾 .Nono Science and Technology and Nonomaterials:New-century Important Problems of Cross- Disciplinary Research[J].电子科技导报,1998(12):19-25. |
[4] | Beck S J;Vartuli J C;Roth W J et al.[J].American Chemical Society,1992,114:10834-10843. |
[5] | Kresge C T;Leonowicz M E;Roth W J et al.[J].Nature,1992,359:710-712. |
[6] | Antonelli D M;Ying J Y .[J].Angewandte Chemie International Edition,1995,34:2014-2017. |
[7] | 张兆荣,索继栓,张小明,李树本.介孔硅基分子筛研究新进展[J].化学进展,1999(01):11-20. |
[8] | 陈航榕,施剑林,禹剑,严东生.非硅组成有序介孔材料合成及应用[J].硅酸盐学报,2000(03):259-263. |
[9] | 陈航榕,施剑林,张文华,严东生.高比表面积有序多孔氧化锆的合成与表征[J].无机材料学报,2000(06):1123-1126. |
[10] | 戴清;沈迅伟;荷农跃 et al.Synthesis and Characterization of Pure TiO2 Mesoporous Molecular Sleeves[J].无机化学学报,1998,14(04):460-466. |
[11] | 朱水平,金庆华,李宝会,王利军,王敬中,丁大同.模板剂在分子筛合成过程中的作用机理[J].无机化学学报,1999(03):331-335. |
[12] | Yang P;Zhao D;Margolese D L et al.[J].Nature,1998,396(6707):152-155. |
[13] | 朱培旭,吴明媚,黄爱红.表面活性剂模板法制备中孔材料的探索[J].功能材料,2001(06):590-594. |
[14] | 陈庆春.工业表面活性剂在纳米材料/纳米结构材料制备中的应用及展望[J].日用化学工业,2001(02):32-34. |
[15] | 蔡伟平,张立德.介孔固体及介孔复合体[J].物理,1997(04):213. |
[16] | Avelino Corma .From Microporous to Mesoporous Molecular Sicve Materials and Their Use in Catalysis[J].Chemical Reviews,1997,97:2373-2419. |
[17] | 李彦,张庆敏,黄福志,顾镇南.表面活性剂溶致液晶体系研究进展[J].大学化学,2000(01):5-9. |
[18] | 陈逢喜,黄茜丹,李全芝.中孔分子筛研究进展[J].科学通报,1999(18):1905-1919. |
[19] | 赵东元;余承忠.Sythetical Design and Life Science of the Functional Molecular Sieve[J].化学世界,2000(ZK):10-14. |
[20] | 孙锦玉,赵东元."面包圈"状高有序度大孔径介孔分子筛SBA-15的合成[J].高等学校化学学报,2000(01):21-23. |
[21] | Jimmy C.Yu;Jiaguo Yu;Jincai Zhao .Enhanced photocatalytic activity of mesoporous and ordinary TiO_2 thin films by sulfuric acid treatment[J].Applied Catalysis, B. Environmental: An International Journal Devoted to Catalytic Science and Its Applications,2002(1):31-43. |
[22] | Jiaguo Yu;Jimmy C.Yu;Wingkei Ho;Zitao Jiang .Effects of calcination temperature on the photocatalytic activity and photo-induced super-hydrophilicity of mesoporous TiO_2 thin films[J].New Journal of Chemistry,2002(5):607-613. |
[23] | Jimmy C.Yu;Lizhi Zhang;Jiaguo Yu .Rapid synthesis of mesoporous TiO_2 with high photocatalytic activity by ultrasound-induced agglomeration[J].New Journal of Chemistry,2002(4):416-420. |
[24] | Jimmy C. Yu;Jiaguo Yu;Wingkei Ho;Lizhi Zhang .Preparation of highly photocatalytic active nano-sized TiO_2 particles via ultrasonic irradiation[J].Chemical communications,2001(19):1942-1943. |
上一张
下一张
上一张
下一张
计量
- 下载量()
- 访问量()
文章评分
- 您的评分:
-
10%
-
20%
-
30%
-
40%
-
50%