石墨烯独特的结构使其具有优异的电、光、热、强度等物理性质,是“后硅时代”的新潜力材料,因具有巨大的应用前景而成为研究的热点.首先对近10多年来国内外石墨烯的研究现状进行了简要分析,然后详细介绍了石墨烯的主要制备方法、原理、各自的特征及其应用前景,重点综述了石墨烯在超级电容器电极材料中的应用研究,最后就目前石墨烯及其在超级电容器中的应用研究的关键问题提出了个人看法和一些建议.
参考文献
| [1] | Mermin N D .Crystalline order in two dimensions[J].Physical Review,1968,176:250. |
| [2] | Novoselov K S;Geim A K;Morozov S V et al.Electric field effect in atomically thin carbon films[J].Science,2004,306(5296):666. |
| [3] | Lee C G;Wei X D;Kysar J W et al.Measurement of the elastic properties and intrinsic strength of monolayer graphene[J].Science,2008,321:385. |
| [4] | Balandin AA;Ghosh S;Bao WZ;Calizo I;Teweldebrhan D;Miao F;Lau CN .Superior thermal conductivity of single-layer graphene[J].Nano letters,2008(3):902-907. |
| [5] | Chen JH;Jang C;Xiao SD;Ishigami M;Fuhrer MS .Intrinsic and extrinsic performance limits of graphene devices on SiO2[J].Nature nanotechnology,2008(4):206-209. |
| [6] | Chae HK;Siberio-Perez DY;Kim J;Go Y;Eddaoudi M;Matzger AJ .A route to high surface area, porosity and inclusion of large molecules in crystals[J].Nature,2004(6974):523-527. |
| [7] | Novoselov KS;Jiang Z;Zhang Y;Morozov SV;Stormer HL;Zeitler U;Maan JC;Boebinger GS;Kim P;Geim AK .Room-temperature quantum Hall effect in graphene.[J].Science,2007(5817):1379-0. |
| [8] | Wang Y;Huang Y;Song Y;Zhang XY;Ma YF;Liang JJ;Chen YS .Room-Temperature Ferromagnetism of Graphene[J].Nano letters,2009(1):220-224. |
| [9] | Mark H. Rummeli;Claudia C. Rocha;Frank Ortmann;Imad Ibrahim;Haldun Sevindi;Felix Borrnert;Jens Kunstmann;Alicja Bachmatiuk;Markus Potschke;Masashi Shiraishi;M. Meyyappan;Bernd Buchner;Stephan Roche;Cianaurelio Cuniberti .Graphene: Piecing it Together[J].Advanced Materials,2011(39):4471-4490. |
| [10] | 黄毅,陈永胜.石墨烯的功能化及其相关应用[J].中国科学B辑,2009(09):887-896. |
| [11] | 万勇;马廷灿;冯瑞华.石墨烯国际发展态势分析[J].科学观察,2010(03):25. |
| [12] | 王丽,潘云涛.石墨烯的研究前沿及中国发展态势分析[J].新型炭材料,2010(06):401-408. |
| [13] | Sutter PW;Flege JI;Sutter EA .Epitaxial graphene on ruthenium[J].Nature materials,2008(5):406-411. |
| [14] | Berger, C;Song, ZM;Li, XB;Wu, XS;Brown, N;Naud, C;Mayo, D;Li, TB;Hass, J;Marchenkov, AN .Electronic confinement and coherence in patterned epitaxial graphene[J].Science,2006(5777):1191-1196. |
| [15] | Chong-an Di;Dacheng Wei;Gui Yu;Yunqi Liu;Yunlong Guo;Daoben Zhu .Patterned Graphene as Source/Drain Electrodes for Bottom-Contact Organic Field-Effect Transistors[J].Advanced Materials,2008(17):3289-3293. |
| [16] | Dalton AB;Collins S;Munoz E;Razal JM;Ebron VH;Ferraris JP .Super-tough carbon-nanotube fibres - These extraordinary composite fibres can be woven into electronic textiles.[J].Nature,2003(6941):703-0. |
| [17] | De, S.;Lyons, P.E.;Sorel, S.;Doherty, E.M.;King, P.J.;Blau, W.J.;Nirmalraj, P.N.;Boland, J.J.;Scardaci, V.;Joimel, J.;Coleman, J.N. .Transparent, flexible, and highly conductive thin films based on Polymer-nanotube composites[J].ACS nano,2009(3):714-720. |
| [18] | Lotya, M;Hernandez, Y;King, PJ;Smith, RJ;Nicolosi, V;Karlsson, LS;Blighe, FM;De, S;Wang, ZM;McGovern, IT;Duesberg, GS;Coleman, JN .Liquid Phase Production of Graphene by Exfoliation of Graphite in Surfactant/Water Solutions[J].Journal of the American Chemical Society,2009(10):3611-3620. |
| [19] | Li D;Muller MB;Gilje S;Kaner RB;Wallace GG .Processable aqueous dispersions of graphene nanosheets[J].Nature nanotechnology,2008(2):101-105. |
| [20] | Kostya S. Novoselov .Graphene: Materials in the Flatland (Nobel Lecture)[J].Angewandte Chemie,2011(31):6986-7002. |
| [21] | Bunch JS;Yaish Y;Brink M;Bolotin K;McEuen PL .Coulomb oscillations and Hall effect in quasi-2D graphite quantum dots[J].Nano letters,2005(2):287-290. |
| [22] | Meyer C J;Geim K A;Katsnelson I M et al.The structure of suspended graphene sheets[J].Nature,2007,446:60. |
| [23] | S Akc_ltekin;M El Kharrazi;B K_hler;A Lorke;M Schleberger .Graphene on insulating crystalline substrates[J].Nanotechnology,2009(15):155601-6. |
| [24] | Catharina Knieke;Angela Berger;Michael Voigt .Scalable production of graphene sheets by mechanical delamination[J].Carbon: An International Journal Sponsored by the American Carbon Society,2010(11):3196-3204. |
| [25] | Hernandez Y;Nicolosi V;Lotya M;Blighe FM;Sun ZY;De S;McGovern IT;Holland B;Byrne M;Gun'ko YK .High-yield production of graphene by liquid-phase exfoliation of graphite[J].Nature nanotechnology,2008(9):563-568. |
| [26] | Hamilton, CE;Lomeda, JR;Sun, ZZ;Tour, JM;Barron, AR .High-Yield Organic Dispersions of Unfunctionalized Graphene[J].Nano letters,2009(10):3460-3462. |
| [27] | Biswas S;Drzal LT .A Novel Approach to Create a Highly Ordered Monolayer Film of Graphene Nanosheets at the Liquid-Liquid Interface[J].Nano letters,2009(1):167-172. |
| [28] | Janowska I;Chizari K;Ersen O et al.Microwave synthesis of large few-layer graphene sheets in aqueous solution of ammonia[J].Nano Res,2010,3(02):126. |
| [29] | De, S;King, PJ;Lotya, M;O'Neill, A;Doherty, EM;Hernandez, Y;Duesberg, GS;Coleman, JN .Flexible, Transparent, Conducting Films of Randomly Stacked Graphene from Surfactant-Stabilized, Oxide-Free Graphene Dispersions[J].Small,2010(3):458-464. |
| [30] | Khan, U.;O'Neill, A.;Lotya, M.;De, S.;Coleman, J.N. .High-concentration solvent exfoliation of graphene[J].Small,2010(7):864-871. |
| [31] | Li XL;Zhang GY;Bai XD;Sun XM;Wang XR;Wang E;Dai HJ .Highly conducting graphene sheets and Langmuir-Blodgett films[J].Nature nanotechnology,2008(9):538-542. |
| [32] | Antisari V M;Montone A;Jovic N et al.Low energy pure shear milling:A method for the preparation of graphite nano-sheets[J].Scripta Materialia,2006,55:1047. |
| [33] | Sun L;Li X J;Qu Y D et al.Preparation and characterization of graphite nanosheets from detonation technique[J].Materials Letters,2008,62:703. |
| [34] | Darancet P;Wipf N;Mayou D et al.Quenching of quantum hall effect and the role of undoped planes in epitaxial graphene[J].Physical Review Letters,2008,101:116806. |
| [35] | Plochocka P;Faugeras C;Orlita M et al.Probing the high energy limit of massless dirac fermions in multi-layer graphene[J].Physical Review Letters,2008,100:087401. |
| [36] | 36 Kedzierski J;Hsu L P;Healey P et al.Epitaxial graphene electron devices on SiC substrates[J].IEEE/Trans Electron Devices,2008,55:2078. |
| [37] | Sutter PW;Flege JI;Sutter EA .Epitaxial graphene on ruthenium[J].Nature materials,2008(5):406-411. |
| [38] | Marchini S;Gunther S;Wintterlin J .Scanning tunneling microscopy of graphene on Ru(0001)[J].Physical review, B. Condensed matter and materials physics,2007(7):5429-1-5429-9-0. |
| [39] | CAI Jin-Ming,BAO Li-Hong,GUO Wei,CAI Li,HUAN Qing,LIAN Ji-Chun,GUO Hai-Ming,WANG Ke-Zhi,SHI Dong-Xia,PANG Shi-Jin,GAO Hong-Jun.Low-Dimensional Forest-Like and Desert-Like Fractal Patterns Formed in a DDAN Molecular System[J].中国物理快报（英文版）,2007(10):2918-2921. |
| [40] | Lerf A;He H;Forster M et al.Structure of graphite oxide revisited[J].Journal of Physical Chemistry B,1998,102(23):4477. |
| [41] | Staudenmaier L .Verfahren zur darstellung der graphits ure[J].Ber Dt Sch Chem Ges,1898,31(02):1481. |
| [42] | Brodie B C .Sur le poids atomique du graphite[J].Annales De Chimie Et De Physique,1860,59:466. |
| [43] | Hummers W;Offeman R .Preparation of graphitic oxide[J].Journal of the American Chemical Society,1958,80(06):1339. |
| [44] | Chattopadhyay J;Mukherjee A;Hamilton CE;Kang J;Chakraborty S;Guo WH;Kelly KF;Barron AR;Billups WE .Graphite epoxide[J].Journal of the American Chemical Society,2008(16):5414-5415. |
| [45] | Daniel R. Dreyer;Sungjin Park;Christopher W. Bielawski .The chemistry of graphene oxide[J].Chemical Society Reviews,2010(1):228-240. |
| [46] | Sasha Stankovich;Dmitriy A. Dikin;Richard D. Piner .Synthesis of graphene-based nanosheets via chemical reduction of exfoliated graphite oxide[J].Carbon: An International Journal Sponsored by the American Carbon Society,2007(7):1558-1565. |
| [47] | Xu Liqun;Liu Yiliang;Neoh Koon-Gee et al.Reduction of graphene oxide by aniline with its concomitant oxidative polymerization[J].Macromolecular Rapid Communications,2011,32:684. |
| [48] | 张天友,张东.还原氧化石墨烯横向尺寸分布影响因素初探[J].功能材料,2009(10):1695-1698. |
| [49] | Structures of thermally and chemically reduced graphene[J].Materials Letters,2010(3):357. |
| [50] | Photoluminescence and Raman studies of graphene thin films prepared by reduction of graphene oxide[J].Materials Letters,2010(3):399. |
| [51] | Liu N;Luo F;Wu H X .One-step ionic-liquid-assisted electrochemical synthesis of ionic-liquid-functionalized graphene sheets directly from graphite[J].Advanced Functional Materials,2008,18:1518. |
| [52] | Cristina Gomez-Navarro;R.Thomas Weitz;Alexander M.Bittner .Electronic Transport Properties of Individual Chemically Reduced Graphene Oxide Sheets[J].Nano letters,2007(11):3499-3503. |
| [53] | Wu, Z.-S.;Ren, W.;Gao, L.;Zhao, J.;Chen, Z.;Liu, B.;Tang, D.;Yu, B.;Jiang, C.;Cheng, H.-M. .Synthesis of graphene sheets with high electrical conductivity and good thermal stability by hydrogen arc discharge exfoliation[J].ACS nano,2009(2):411-417. |
| [54] | Cote, LJ;Cruz-Silva, R;Huang, JX .Flash Reduction and Patterning of Graphite Oxide and Its Polymer Composite[J].Journal of the American Chemical Society,2009(31):11027-11032. |
| [55] | Choucair, M;Thordarson, P;Stride, JA .Gram-scale production of graphene based on solvothermal synthesis and sonication[J].Nature nanotechnology,2009(1):30-33. |
| [56] | Wang, HL;Robinson, JT;Li, XL;Dai, HJ .Solvothermal Reduction of Chemically Exfoliated Graphene Sheets[J].Journal of the American Chemical Society,2009(29):9910-9911. |
| [57] | Yanwu Zhu;Shanthi Murali;Meryl D. Stoller .Microwave assisted exfoliation and reduction of graphite oxide for ultracapacitors[J].Carbon: An International Journal Sponsored by the American Carbon Society,2010(7):2118-2122. |
| [58] | Tong Wei;Zhuangjun Fan;Guilian Luo .A rapid and efficient method to prepare exfoliated graphite by microwave irradiation[J].Carbon: An International Journal Sponsored by the American Carbon Society,2009(1):337-339. |
| [59] | Park, S;An, JH;Jung, IW;Piner, RD;An, SJ;Li, XS;Velamakanni, A;Ruoff, RS .Colloidal Suspensions of Highly Reduced Graphene Oxide in a Wide Variety of Organic Solvents[J].Nano letters,2009(4):1593-1597. |
| [60] | Obraztsov, AN .CHEMICAL VAPOUR DEPOSITION Making graphene on a large scale[J].Nature nanotechnology,2009(4):212-213. |
| [61] | de Parga ALV;Calleja F;Borca B;Passeggi MCG;Hinarejos JJ;Guinea F;Miranda R .Periodically rippled graphene: Growth and spatially resolved electronic structure[J].Physical review letters,2008(5):056807-1-056807-4-0. |
| [62] | Land T A;Michely T;Behm R J et al.STM investigation of single layer graphite structures produced on Pt(111) by hydrocarbon decomposition[J].Surface Science,1992,264(03):261. |
| [63] | Coraux J;N'Diaye AT;Busse C;Michely T .Structural coherency of graphene on Ir(111)[J].Nano letters,2008(2):565-570. |
| [64] | Reina A;Jia XT;Ho J;Nezich D;Son HB;Bulovic V;Dresselhaus MS;Kong J .Large Area, Few-Layer Graphene Films on Arbitrary Substrates by Chemical Vapor Deposition[J].Nano letters,2009(1):30-35. |
| [65] | Kim K S;Zhao Y;Jang H et al.Large-scale pattern growth of graphene films for stretchable transparent electrodes[J].Nature,2009,457:706. |
| [66] | Li X S;Cai W W;An J H .Large-area synthesis of high-quality and uniform graphene films on copper foils[J].Science,2009,324(5932):1312. |
| [67] | Cote, LJ;Cruz-Silva, R;Huang, JX .Flash Reduction and Patterning of Graphite Oxide and Its Polymer Composite[J].Journal of the American Chemical Society,2009(31):11027-11032. |
| [68] | Jiao L Y;Zhang L;Wang X R et al.Narrow graphene nanoribbons from carbon nanotubes[J].Nature,2009,458:877. |
| [69] | Dato A;Radmilovic V;Lee ZH;Phillips J;Frenklach M .Substrate-free gas-phase synthesis of graphene sheets[J].Nano letters,2008(7):2012-2016. |
| [70] | Sidorov AN;Yazdanpanah MM;Jalilian R;Ouseph PJ;Cohn RW;Sumanasekera GU .Electrostatic deposition of graphene[J].Nanotechnology,2007(13):35301-1-35301-4-0. |
| [71] | Lei Wang;Chungui Tian;Huan Wang .Mass Production of Graphene via an in Situ Self-Generating Template Route and Its Promoted Activity as Electrocatalytic Support for Methanol Electroxidization[J].The journal of physical chemistry, C. Nanomaterials and interfaces,2010(19):8727-8733. |
| [72] | Zhang L L;Zhou R;Zhao X S .Graphene-based materials as supercapacitor electrodes[J].Journal of Materials Chemistry,2010,20:5983. |
| [73] | Stoller MD;Park SJ;Zhu YW;An JH;Ruoff RS .Graphene-Based Ultracapacitors[J].Nano letters,2008(10):3498-3502. |
| [74] | S R C VIVEKCHAND;CHANDRA SEKHAR ROUT;K S SUBRAHMANYAM .Graphene-based electrochemical supercapacitors[J].Journal of Chemical Sciences,2008(1):9-13. |
| [75] | Electrophoretic deposition of graphene nanosheets on nickel foams for electrochemical capacitors[J].Journal of Power Sources,2010(9):3031. |
| [76] | Chen S;Zhu J W;Wang X .One-step synthesis of graphenecohalt hydroxide nanocomposites and their electrochemical properties[J].Journal of Physical Chemistry C,2010,114(27):11829. |
| [77] | 郝亮,张校刚.石墨烯/氢氧化镍复合材料的制备[C].2009年第十五次全国电化学学术会议论文集,2009:1-2. |
| [78] | 吕维强 .石墨烯的电化学储氢性能及其理论计算[D].哈尔滨工业大学,2009. |
| [79] | 沈辰飞,郑明波,薛露平,李念武,吕洪岭,张松涛,曹洁明.石墨烯-氧化钌纳米复合材料的水热法合成及电化学电容性能[J].无机化学学报,2011(03):585-589. |
| [80] | 李津,刘晓来,赵东林.二氧化锰改性石墨烯电极材料的电化学性能[J].电池工业,2011(03):164-167. |
| [81] | Wu Zhongshuai;Wang Dawei;Ren Wencai .Anchoring hydrous RuO2 on graphene sheets for high-performance electrochemical capacitors[J].Advanced Functional Materials,2010,20:3595. |
| [82] | Ting Lu;Yanping Zhang;Haibo Li;Likun Pan;Yinlun Li;Zhuo Sun .Electrochemical behaviors of graphene-ZnO and graphene-SnO_2 composite films for supercapacitors[J].Electrochimica Acta,2010(13):4170-4173. |
| [83] | Xia, X.;Tu, J.;Mai, Y.;Chen, R.;Wang, X.;Gu, C.;Zhao, X. .Graphene sheet/porous NiO hybrid film for supercapacitor applications[J].Chemistry: A European journal,2011(39):10898-10905. |
| [84] | 吕伟;韩晓鹏;杨全红.石墨烯/金属氧化物复合材料的制备及电化学性能研究[A].重庆,2010:242. |
| [85] | 韩啸,王铀,刘淑娟,胡立江.聚苯胺/石墨烯/金复合材料的制备及超电容性能研究[J].功能材料,2011(z4):744-747. |
| [86] | Humberto Gómez;Manoj K. Ram;Farah. Alvi;P. Villalba;Elias (Lee) Stefanakos;Ashok Kumar .Graphene-conducting polymer nanocomposite as novel electrode for supercapacitors[J].Journal of Power Sources,2011(8):4102-4108. |
| [87] | 戴晓军,王凯,周小沫,吴海平,魏志祥.基于石墨烯/聚苯胺纳米线阵列复合薄膜的柔性超级电容器[J].中国科学（物理学 力学 天文学）,2011(09):1046-1051. |
| [88] | Zhang K;Zhang L L;Zhao X S et al.Graphene/polyaniline nanofiber composites as supercapacitor electrodes[J].Chemistry of Materials,2010,22:1392. |
| [89] | Wang, D.-W.;Li, F.;Zhao, J.;Ren, W.;Chen, Z.-G.;Tan, J.;Wu, Z.-S.;Gentle, I.;Lu, G.Q.;Cheng, H.-M. .Fabrication of graphene/polyaniline composite paper via in situ anodic electropolymerization for high-performance flexible electrode[J].ACS nano,2009(7):1745-1752. |
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