详细论述了在碱式氯化镁晶须的制备过程中,碱试剂、氯化镁浓度、碱与氯化镁的物质的量比、反应及陈化温度和时间等因素对晶须结构与形貌的影响,并指出在当前碱式氯化镁晶须的制备研究中存在产率低、缺乏理论研究等问题.作为一种简单易得的无机晶须,目前碱式氯化镁晶须的应用还比较有限,对其进行有机改性或将其作为模板剂制备一维中空材料可以明显拓宽其应用范围.
参考文献
[1] | Holmes J D;Johnston K P;Doty R C et al.Control of thickness and orientation of solution-grown silicon nanowires[J].Science,2000,287(5457):1471. |
[2] | Cui Y;Wei Q Q;Park H K et al.Nanowire nanosensors for highly sensitive and selective detection of biological and chemical species[J].Science,2001,293(5533):1289. |
[3] | Duan X F;Huang Y;Cui Y et al.Indium phosphide nanowires as building blocks for nanoscale electronic and optoelectronic devices[J].Nature,2001,409(6816):66. |
[4] | Xia Y N;Yang P D;Sun Y G et al.One-dimensional nanostructures:Synthesis,characterization,and applications[J].Advanced Materials,2003,15(05):353. |
[5] | 李武.无机晶须[M].北京:化学工业出版社,2005 |
[6] | Sugimoto K;Dinnebier RE;Schlecht T .Structure determination of Mg(3)(OH)(5)Cl.4H(2)O (F5 phase) from laboratory powder diffraction data and its impact on the analysis of problematic magnesia floors.[J].Acta Crystallographica. Section B, Section B. Structural Science,2007(6):805-811. |
[7] | 潘兆橹.结晶学与矿物学[M].北京:地质出版社,1993 |
[8] | 潘普林 B R.晶体生长[M].北京:中国建筑工业出版社,1981 |
[9] | 赵爱东,王红,翟学良.卤水-氨法制备碱式氯化镁纤维的SEM研究[J].电子显微学报,2005(04):371. |
[10] | 李春忠,古庆山,程起林,张玲.针状碱式氯化镁的合成及形态分析[J].华东理工大学学报(自然科学版),2005(03):314-318. |
[11] | 王世栋,褚敏雄,孙庆国.卤水-氨法碱式氯化镁晶须的制备及影响因素的研究[J].海湖盐与化工,2006(02):1-3. |
[12] | Weiliu Fan;Xinyu Song;Sixiu Sun;Xian Zhao .Hydrothermal formation and characterization of magnesium hydroxide chloride hydrate nanowires[J].Journal of Crystal Growth,2007(1):167-174. |
[13] | 任庆利,刘斌,陈维,陈寿田.制备工艺对纤维状碱式氯化镁晶体的影响[J].绝缘材料,2004(02):32-34,37. |
[14] | 王在华,冯刚,孙庆国,全宏毅.碱式氯化镁和氧化镁晶须的制备与表征[J].盐湖研究,2007(04):40-44. |
[15] | 薛冬峰,邹龙江,闫小星,王雷,王晓丽.氧化镁晶须制备及影响因素考查[J].大连理工大学学报,2007(04):488-493. |
[16] | Sears G W .A growth mechanism for mercury whiskers[J].Acta Metallurgica,1955,3:367. |
[17] | 田军.超声波在碱式氯化镁结晶中的应用[J].哈尔滨商业大学学报(自然科学版),2005(02):221-222. |
[18] | 王伟宁;王思嘉;胡金华.碱式氯化镁阻燃剂的应用研究[J].阻燃材料与技术,1991(01):21. |
[19] | 张林栋,卢亚哲,袁俊生.碱式氯化镁晶须在塑料中的应用研究[J].海湖盐与化工,2005(02):7-9. |
[20] | 张林栋,杨剑,袁俊生,李静.碱式氯化镁晶须用于热熔胶的研究[J].粘接,2004(02):10-12. |
[21] | 李静,高玉杰,任继春.碱式氯化镁晶须作纸张填料[J].中华纸业,2003(07):53-53. |
[22] | Takeshi Yanagida;Kazuki Nagashima;Hidekazu Tanaka;Tomoji Kawai .Mechanism of critical catalyst size effect on MgO nanowire growth by pulsed laser deposition[J].Journal of Applied Physics,2008(1):016101-1-016101-3-0. |
[23] | Hu L et al.MgO nanowire growth from Mg metal and SiO2[J].J Nanosci Nanotechn,2004,4(08):1071. |
[24] | Chen, L;Xu, C;Zhang, XF .DFT calculations of vibrational spectra and nonlinear optical properties for MgO nanotube clusters[J].Journal of Molecular Structure. Theochem: Applications of Theoretical Chemistry to Organic, Inorganic and Biological Problems,2008(1/3):55-59. |
[25] | Q YANG;J SHA;L WANG .Synthesis of MgO nanotube bundles[J].Nanotechnology,2004(8):1004-1008. |
[26] | G. Bilalbegovic .Structural and electronic properties of MgO nanotube clusters[J].Physical review, B. Condensed matter and materials physics,2004(4):045407.1-045407.6. |
[27] | 赵爱东,申玉双,翟学良.一种制备氧化镁纤维的方法[J].无机材料学报,2005(01):215-219. |
[28] | 赵爱东,翟学良,王红.液相法制备氧化镁晶须的SEM研究[J].电子显微学报,2004(04):455-455. |
[29] | 王洁,孙新华,欧秀芹,董广前,杨秀英,周启立.碱式氯化镁废渣生产氧化镁[J].无机盐工业,2003(05):45-46. |
[30] | 刘烨,景殿策,王宝和,吕晓明,云利娜.氢氧化镁纳米棒的制备及热分解动力学研究[J].河南化工,2008(01):25-27. |
[31] | Fan WL;Sun SX;Song XY;Zhang WM;Yu HY;Tan XJ;Cao GX .Controlled synthesis of single-crystalline Mg(OH)(2) nanotubes and nanorods via a solvothermal process[J].International Journal of Quantum Chemistry,2004(7):2329-2338. |
[32] | Weiliu Fan;Sixiu Sun;Liping You;Guangxiang Cao;Xinyu Song;Wimin Zhang;Haiyun Yu .Solvothermal synthesis of Mg(OH)-2 nanotubes using Mg_10(OH)_18Cl_2 centre dot 5H_2O nanowires as precursors[J].Journal of Materials Chemistry: An Interdisciplinary Journal dealing with Synthesis, Structures, Properties and Applications of Materials, Particulary Those Associated with Advanced Technology,2003(12):3062-3065. |
[33] | 范方荣 .镁系纳米棒的合成工艺研究[D].大连理工大学,2006. |
上一张
下一张
上一张
下一张
计量
- 下载量()
- 访问量()
文章评分
- 您的评分:
-
10%
-
20%
-
30%
-
40%
-
50%