以天然鳞状石墨为原料,采用化学氧化法合成氧化石墨,再经低温热解膨胀得到膨胀石墨；采用微波加热乙二醇法同时还原膨胀石墨和PtClO2-6离子得到铂/石墨烯(Pt/Gr)复合材料.分析了反应前溶液的pH值、微波加热时间以及乙二醇中水含量对Pt/Gr结构及催化性能的影响.通过循环伏安法对Pt/Gr的电化学性能进行了表征.采用透射电镜和扫描电镜观察了Gr和Pt/Gr的表面结构.研究结果表明,在优化的实验条件下可以得到高负载量高分散性的Pt/Gr纳米复合材料.实验得到的40％(质量分数)Pt/Gr的Pt粒子粒径分布在3.0～3.3nm范围内,对氢电极和氧电极反应有高催化活性,可作为质子交换膜燃料电池的电催化剂.
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