贵金属因其独特的催化性能，在车用尾气净化催化剂行业倍受关注。简述了当前贵金属催化剂的研究现状及存在的不足，并从三维有序大孔材料(3DOM)的特殊结构特征着手，阐述了3DOM催化净化作用的特点和优势。为高催化活性和低制造成本的新型贵金属三维有序大孔材料的研制和应用提供可行性分析。
Noble metals have become the focus in auto-exhaust catalysts owing to their unique catalytic properties. The current research status and problems of noble metal catalysts are sketched in the present, and the advantages of three dimensional ordered macroporous material (3DOM) catalyst, based on its characteristic of special structure, are also summarized. The feasibility analysis is provided for the development and application of the novel noble metal 3DOM catalysts with high catalytic activities and low manufacturing cost.
参考文献
| [1] | 张爱敏,宁平,黄荣光,贺小昆,赵云昆,顾永万,桓源峰,杨冬霞.汽车尾气净化用贵金属催化材料研究进展[J].贵金属,2005(03):66-70,50. |
| [2] | Ralph T R;Hogarth M P .Catalyst for low temperature fuel cells[J].Platinum Met Rev,2002,46(03):117-135. |
| [3] | Yuyan Shao;Jun Liu;Yong Wang .Novel catalyst support materials for PEM fuel cells: current status and future prospects[J].Journal of Materials Chemistry: An Interdisciplinary Journal dealing with Synthesis, Structures, Properties and Applications of Materials, Particulary Those Associated with Advanced Technology,2009(1):46-59. |
| [4] | 杨苏东,梁彦瑜,温祝亮,宋启军,张校刚.不同载体负载Pd催化剂对甲酸的电催化氧化活性比较[J].电化学,2011(02):175-179. |
| [5] | 卢雯婷,陈敬超,冯晶,于杰.贵金属催化剂的应用研究进展[J].稀有金属材料与工程,2012(01):184-188. |
| [6] | 查进 .汽车尾气净化用三效催化剂中储氧材料的研究[D].大连理工大学,2009. |
| [7] | 张爱敏,宁平,赵云昆,贺小昆,黄荣光.贵金属在载体上的分布对催化剂性能的影响[J].稀有金属材料与工程,2007(03):394-397. |
| [8] | 赵秋伶,徐小健,蔡秀琴.汽车尾气净化催化剂及载体的研究进展[J].广州化工,2009(08):15-18. |
| [9] | 杨建新,熊祥辉,蔡兴旺.纳米材料在汽车尾气净化中的应用[J].韶关学院学报,2005(03):58-60. |
| [10] | 旷成秀,刘康强,李凤仪.Pt-Rh-Pd/Al2O3三元催化剂的制备及其表征[J].贵金属,2013(01):17-20,24. |
| [11] | 黎鼎鑫;张永俐;袁弘鸣.贵金属材料学[M].长沙：中南工业大学出版社,1991:251-547. |
| [12] | Wang D;Caruso R A;Caruso F .Synthesis of macro-porous titania and inorganic composite materials from coated colloidal spheres - a novel route to tune pore morphology[J].Chem Mater,2001,13(02):364-371. |
| [13] | Miguez H.;Lopez C.;Mifsud A.;Moya JS.;Vazquez L.;Meseguer F. .EVIDENCE OF FCC CRYSTALLIZATION OF SIO2 NANOSPHERES[J].Langmuir: The ACS Journal of Surfaces and Colloids,1997(23):6009-6011. |
| [14] | Bollhuis P G;Frenkel D;Mau S et al.Entropy difference between crystal phases[J].Nature,1997,388(11):235-237. |
| [15] | 周公度;段连云.结构化学基础[M].北京：北京大学出版社,2002:308-310. |
| [16] | Guan G Q;Zapf R;Kolb G et al.Preferentical CO oxidation over catalysts with well defined inverse opal structure in microchannels[J].International Journal of Hydrogen Energy,2008,33(02):797-801. |
| [17] | D. Dong;X.H. Chen;W.T. Xiao;G.B. Yang;P.Y. Zhang .Preparation and properties of electroless Ni-P-SiO_2 composite coatings[J].Applied Surface Science,2009(15):7051-7055. |
| [18] | Sadakane M;Sasaki K;Kunioku H et al.Preparation of 3-D ordered macroporous tungsten oxides and nano-crystalline particulate tungsten oxides using a colloidal crystal template methold,and their structural characteri-zation and application as photocatalysts under wisible light irradiation[J].Journal of Materials Chemistry,2010,20(09):1811-1818. |
| [19] | Sadakane, M;Asanuma, T;Kubo, J;Ueda, W .Facile procedure to prepare three-dimensionally ordered macroporous (3DOM) perovskite-type mixed metal oxides by colloidal crystal templating method[J].Chemistry of Materials,2005(13):3546-3551. |
| [20] | Stein A;Schroden R C .Colloidal crystal templating of three-dimensionally ordered macroporous solids materials for photonics and beyond, current opinion solid state[J].Materials Science,2001,5(06):553-564. |
| [21] | Yu J;Yoon S;Chai G .Odered uniform porous carbon by carbonization of suguars[J].Carbon,2001,39(09):1442-1446. |
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