针对焊接熔渣分子理论及离子理论存在的局限,基于冶金界近年来提出的熔渣共存理论,结合MgO-CaO-SiO2高温三元相图确定的结构单元,利用质量平衡原理建立了MgO-CaO-SiO2三元熔渣离子活度热力学计算模型,并借助于Matlab计算工具进行数值求解.计算结果表明,该模型可同时兼顾熔渣的分子理论和离子理论,离子活度随碱度的变化与碱度理论及直流焊接冶金电化学实验结果一致,在焊接化学冶金定量研究方面显示出良好的应用前景.
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