以负载醋酸锌的废活性炭为原料,采用微波法得到再生活性炭产品吸附甲苯.测定了20、30和40℃时活性炭吸附甲苯的吸附等温线和穿透曲线,并用Langmuir和Freundlich方程处理实验数据,Lang-muir方程能很好地拟合实验数据,计算了甲苯在活性炭上的最大饱和吸附量(qm)为273.23mg/g、平均吸附热(△H)为-1.92kJ/mol,吸附自由能(△G)为负数,吸附熵(△S)随吸附量增加而降低,表明该吸附过程是一个自发的放热过程.在相同入口气体浓度和吸附温度下,比较了3种活性炭的饱和吸附量,对比结果表明微波活性炭具有较大的饱和吸附量.
参考文献
[1] | Aguado S;Polo AC;Bernal MP;Coronas J;Santamaria J .Removal of pollutants from indoor air using zeolite membranes[J].Journal of Membrane Science,2004(1/2):159-166. |
[2] | Mo J;Zhang Y;Yang R .[J].INDOOR AIR-INTERNATIONAL JOURNAL OF INDOOR AIR QUALITY AND CLIMATE,2005,15:291-300. |
[3] | Jones AP .Indoor air quality and health[J].Atmospheric environment,1999(28):4535-4564. |
[4] | Khan F I;Ghoshal A K .[J].Journal of Loss Prevention in the Process Industries,2000,13:527-545. |
[5] | Chuang C L;Chiang P C;Chang E E et al.[J].Chemosphere,2003,53:17-27. |
[6] | Sorial G A;Smith F L;Suidan M T et al.[J].Journal of the Air & Waste Management Association,2001,51:756-765. |
[7] | Khan F I;Ghoshal A K .[J].Journal of Loss Prevention in the Process Industries,2000,13:527-545. |
[8] | Das D;Gaur V;Verma N .Removal of volatile organic compound by activated carbon fiber[J].Carbon: An International Journal Sponsored by the American Carbon Society,2004(14):2949-2962. |
[9] | 蔡超,薛屏.CU2+掺杂对Ce-Zr-O固溶体结构及苯催化燃烧性能的影响[J].宁夏大学学报(自然科学版),2005(04):345-348. |
[10] | 王军,沈美庆,王晓玲,杨项军,廖巧丽,刘廷斌.燃烧法控制有机废气污染的催化剂性能研究[J].燃烧科学与技术,2001(03):242-244. |
[11] | 李湘凌,林岗,周元祥,王资荣.复方液吸收法处理低浓度苯类废气[J].合肥工业大学学报(自然科学版),2002(05):794-796. |
[12] | 衣新宇,赵修华,朱登磊.表面活性剂吸收法治理含苯废气的中试实验[J].能源环境保护,2004(03):24-27,39. |
[13] | Alvim Ferraz M C .[J].Fuel,1988,67:1237-1241. |
[14] | Bagreev A;Bandosz T J .[J].Industrial and Engineering Chemistry Research,2002,41:672-679. |
[15] | Zhang Zhengyong;Qu Wenwen;Peng Jinhui .[J].Desalination,2009,249:247-252. |
[16] | Li Wei;Peng Jinghui;Zhang Libo .[J].Hydrometallurgy,2008,92:79-85. |
[17] | 彭金辉;周烈兴;钱天才 等.[P].ZL:200710066278.9,2008-07. |
[18] | 彭金辉;周烈兴;张利波 等.[P].ZL:200710066279.3,2008-07. |
[19] | 古可隆 .[J].林产化工通讯,1999,33:37-40. |
[20] | 周烈兴,钱天才,王绍华.活性炭掺杂氧化锌对苯的吸附等温线测定及甲苯的吸附等温线预测[J].功能材料,2010(08):1473-1476. |
[21] | Balathanigaimani MS;Shim WG;Lee MJ;Lee JW;Moon H .Adsorption isotherms of benzene and toluene on corn grain-based carbon monolith at (303.15, 313.15, and 323.15) K[J].Journal of Chemical and Engineering Data: the ACS Journal for Data,2008(3):732-736. |
[22] | Riccardo JL.;Ramirez-Pastor AJ.;Roma F. .Multilayer adsorption with multisite occupancy: an improved isotherm for surface characterization[J].Langmuir: The ACS Journal of Surfaces and Colloids,2002(6):2130-2134. |
[23] | Hu X;King B;Do D D .[J].Gas Separat Purif,1994,8:187-190. |
[24] | Mohan N;Kannan G K;Upendra S et al.[J].Journal of Hazardous Materials B:Environmental Technologies,2009,168:777-781. |
[25] | Carratala-Abril J;Lillo-Rodenas M A;Linares-Solano A et al.[J].Chemical Engineering Science,2010,65:2190-2198. |
[26] | Lillo-Rodenas M A;Fletcher A J;Thomas K M et al.[J].CARBO,2006,44:1455-1463. |
[27] | Lillo-Rodenas MA;Cazorla-Amoros D;Linares-Solano A .Behaviour of activated carbons with different pore size distributions and surface oxygen groups for benzene and toluene adsorption at low concentrations[J].Carbon: An International Journal Sponsored by the American Carbon Society,2005(8):1758-1767. |
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