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以正硅酸乙酯(TEOS)和乙烯基三乙氧基硅烷(VTES)为前驱物,通过溶胶-凝胶反应在铝颜料表面形成了一层致密的包覆层,再通过甲基丙烯酸甲酯(MMA)和丙烯酸(AA)的自由基聚合反应对铝颜料进行第二层包覆,制备了含亲水基团的包覆型铝粉颜料,以此包覆的铝颜料配制了水性铝粉涂料.研究了铝粉及交联剂的用量、涂料黏度和烘烤温度对漆膜外观和性能的影响,获得了较佳的工艺条件如下:铝粉用量为3%,交联剂的用量为树脂用量的30%,涂料黏度为13 s,烘烤温度为150℃.以此工艺获得的水性铝粉涂料涂膜具有较佳的综合性能,光泽度达到73.4°.

参考文献

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