以多孔阳极氧化铝（AAO）膜制备纳米材料时降低AAO膜孔径至关重要，降低电压无法达到要求，而降低氧化温度可实现这一目标。在0．4mol／L H3PO4溶液中加入70％～80％（体积分数）1，3-丙三醇（PDO），于-10～10℃下恒压110V阳极氧化1h制备了多孔阳极氧化铝（AAO）膜，并在0．50mol／LH，B03和0．05mol／L Na2B4O7溶液中于20℃下以0.5mA／cm。进行填孔后处理。利用SEM，EDS，XRD分析了AAO膜的表面彤貌与组成。并对AAO膜填孔前后的极化曲线和交流阻抗谱进行了测试。结果表明，膜孔径随氧化温度降低而降低，80％PDO，10℃所得AAO膜的成分包括65．94％（质量分数，下同）Al，12．79％C，20．29％O和0．98％P；随氧化温度升高和PDO含量下降，AAO膜的稳定电流密度增大；随氧化温度升高，膜阻挡层厚度增大；填孔试验前AAO膜只存在一个阻挡层的相位角峰，填孔后出现两个峰，中高频段体现封闭的阻挡层特性，低频段体现的是多孔层封闭部分的特性。
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