在常压下研究了多种分子筛上NO和NO2的吸附和脱附情况. 结果表明,有O2存在时, O2与NO生成的NO2可与NO共吸附在分子筛上,显著促进了NO在分子筛特别是Na型分子筛上的吸附. 在所研究的ZSM-5, 13X, SAPO, Y, β和A分子筛中, Hβ分子筛在无氧条件下对NO的吸附能力最强;13X分子筛在有氧条件下对NOx的吸附能力最强,且对NOx的吸附性能具有很好的重复性.
参考文献
[1] | Arai H;Machida M .[J].Catalysis Today,1994,22(01):97. |
[2] | Despres J;Koebel M;Kr(o)cher O;Elsener M Wokaun A .[J].Microporous and Mesoporous Materials,2003,58(02):175. |
[3] | Zhang W X;Yahiro H;Mizuno N;Izumi J Iwamoto M .[J].Langmuir,1993,9(09):2337. |
[4] | Huuhtanen M;M(a) (a)tt(a) T;Rahkamaa-Tolonen K;Maunula T Keiski R L .[J].Topics in Catalysis,2004,30-31(1-4):359. |
[5] | Perdana I;Creaser D;Ohrman O;Hedlund J .NOx adsorption over a wide temperature range on Na-ZSM-5 films[J].Journal of Catalysis,2005(1):219-229. |
[6] | Fridell E;Skoglundh M;Westerberg B;Johansson S Smedler G .[J].Journal of Catalysis,1999,183(02):196. |
[7] | Gervasini A .[J].Applied Catalysis B:Environmental,1997,14(3-4):147. |
[8] | 徐如人;庞文琴;于吉红.分子筛与多孔材料化学[M].北京:科学出版社,2004:68. |
[9] | Szanyi J;Kwak J H;Moline R A;Peden C H F .[J].Physical Chemistry Chemical Physics,2003,5(18):4045. |
[10] | YU Shan-Shan,WANG Xin-Ping,WANG Chong,XU Yan.Using Acetylene for Selective Catalytic Reduction of NO in Excess Oxygen[J].中国化学(英文版),2006(05):598-602. |
[11] | Wang, XP;Xu, Y;Yu, SS;Wang, C .The first study of SCR of NOx by acetylene in excess oxygen[J].Catalysis Letters,2005(1/2):101-108. |
上一张
下一张
上一张
下一张
计量
- 下载量()
- 访问量()
文章评分
- 您的评分:
-
10%
-
20%
-
30%
-
40%
-
50%