介孔稀土氧化物由于在催化、光、电、磁等领域具有巨大应用潜力,已逐渐成为一个研究的热点.介绍了介孔材料的合成机理,较全面地综述了近年来合成介孔稀土氧化物的几种方法及最新研究进展.通过各种物理表征结果考察了合成条件对介孔材料的性质和形貌的影响,指出了目前介孔稀土氧化物制备方面存在的一些问题,对其应用前景进行了展望.
参考文献
| [1] | Gregg S J;Sing K S W.Adsorption,surface and porosity[M].New York:Academic Press,Inc,1982:42. |
| [2] | Kresge C T;Leonowicz M E;Roth W J et al.Ordered mesoporous molecular sieves synthesized by a liquid crystal template mechanism[J].Nature,1992,359:710. |
| [3] | Liu Honglei;Sun Xiaofei;Yin Chengqing et al.Removal of phosphate by mesoporous ZrO2[J].Journal of Hazardous Materials,2008,151(2-3):616. |
| [4] | Feng RM;Yang XJ;Ji WJ;Au CT .Hydrothermal synthesis of stable mesoporous ZrO2-Y2O3 and CeO2-ZrO2-Y2O3 from simple inorganic salts and CTAB template in aqueous medium[J].Materials Chemistry and Physics,2008(1):132-136. |
| [5] | Sinha;Anil K;Suzuki et al.Crystallization of stable mesoporous zirconia and ceria-zirconia[J].Studies in Surface Science and Catalysis,2007,165:323. |
| [6] | 索也兵,杜玉成,张久兴,张余莉.液相法合成ZrO2介孔材料[J].硅酸盐学报,2005(09):1081-1084,1099. |
| [7] | Tidahy H L;Siffert S;Lamonier J F et al.Characterisation of new Pd/hierarchical macro-mesoporous ZrO2 TiO2 and ZrO2-TiO2 catalysts for toluene total oxidation[J].Studies Surf Sci Catal,2007,160:201. |
| [8] | 沈杭燕,郭冰,舒康颖.氯离子对介孔氧化铝质子导电性的影响[J].化学通报（印刷版）,2007(11):865-868. |
| [9] | 赵瑞红,郭奋,杨会龙,胡永其.有序介孔氧化铝的合成、结构表征及催化应用[J].现代化工,2005(09):65-67,73. |
| [10] | Zhao, J;Yue, YH;Hua, WM;Gao, Z .Catalytic activities and properties of mesoporous sulfated Al2O3-ZrO2[J].Catalysis Letters,2007(1/2):27-34. |
| [11] | Fajardo H V;Martins A O;de Almeida et al.Synthesis of mesoporous Al2O3 macrospheres using the biopolymer chitosan as a template:A novel active catalyst system for CO2 reforming of methane[J].Materials Letters,2005,59(29):3963. |
| [12] | Zima T M;Baklanova N I;Lyakhov N Z .Mesoporous structure of Al2O3 prepared from poly(N-vinylpyrrolidone)modified sols of hydrous metal oxides[J].Inorganic Materials,2008,44(02):146. |
| [13] | Septina W;Yuliarto B;Nugraha .Preparation of self-assembly mesoporous TiO2 using block copolymer pluronic PE6200 template[J].AIP Conference Proceedings,2008,989:255. |
| [14] | Li Xiaohong;Fryxell S;Glen E et al.The synthesis of Agdoped mesoporous TiO2[J].Microporous and Mesoporous Materials,2008,111(1-3):639. |
| [15] | Chen Wei;Gang Yi;Sun Xiaodan et al.Achievement of thick mesoporous TiO2 crystalline films by one-step dipcoating approach[J].Microporous and Mesoporous Materials,2008,111(1-3):219. |
| [16] | Khadamova M V;Kolesnik I V;Shaporev A S et al.Modification of mesoporous titanium oxide structure by solvent extraction of template[J].Al' ternativnaya Energetikai Ekologiya,2008,1:43. |
| [17] | Yuan Shuai;Sheng Qiaorong;Zhang Jinlong et al.Synthesis of thermally stable mesoporous TiO2 and investigation of its photocatalytic activity[J].Microporous and Mesoporous Materials,2008,110(2-3):501. |
| [18] | Huo Q S;Margolese D I;Ciesla U et al.Generalized synthesis of periodic surfactant inorganic composite materials[J].Nature,1994,368:317. |
| [19] | Yoshiaki Fukushima;Shinji Inagaki .Nano-scale structure control of mesoporous silica[J].Materials Science and Engineering A:Structural Materials Properties Microstructure and Processing,1996,A217-218:116. |
| [20] | Lin Wenyong;Pang Wenqin;Wei Changping et al.Synthesis and characterization of H-form aluminosnilicate MCM-41 in a novel alkalimetal Free media[J].Chemical Journal of Chinese Universities,1992,267:1138. |
| [21] | 曾垂省,陈晓明,闫玉华,高玉香.介孔材料及其应用进展[J].化工科技,2004(05):48-52. |
| [22] | Mitsunori Yada;Hirohumi Kitamura;Masato Machida et al.Yttrium-based porous materials templated by anionic surfactant assemblies[J].Inorganic Chemistry,1998,37:6470. |
| [23] | Mitsunori Yada;Hirohumi Kitamura;Akira Ichinose;Masato Machida;Tsuyoshi Kijima .Mesoporous Magnetic Materials Based on Rare Earth Oxides[J].Angewandte Chemie International Edition,1999(23):3506-3510. |
| [24] | Wang Yanqin;Yin Lunxiang;Arahon Gedanken .Sonochemical synthesis of mesoporous transition metal and rare earth oxides[J].Ultrasonics Sonochemistry,2002,9:285. |
| [25] | 杨儒;刘建红;李敏 .介孔稀土氧化物的制备方法[P].CN 1511787A,2004-07-14. |
| [26] | 杨儒,刘建红,李敏.非表面活性剂合成CeO2介孔材料[J].中国稀土学报,2004(06):739-745. |
| [27] | 陈慧华,周钰明,叶晓云.介孔La2O3的制备及性能研究[J].中国稀土学报,2007(05):573-577. |
| [28] | Daniel M L;Linda P H;Michael A .Morris Preparation of a series of mesoporous lanthanide oxides by aneutral supramolecular templating route[J].Materials Chemistry,2004,14:1976. |
| [29] | Hung I M .Preparation of mesoporous cerium oxide templated by tri-block copolymer for solid oxide fuel cell[J].Electrochimica Acta,2004,50:745. |
| [30] | Pavawupree S .Preparation and characterization of mesoporous MO2(M=Ti,Ce,Zr,and Hf) nanopowders by a modified sol-gel method[J].Ceramics International,2005,31:959. |
| [31] | Cao Jieming;Jia Hongmei;Liu Jinsong et al.Controllable syntheses of hexagonal and lamellar mesostructured lanthanum oxide[J].Materials Letters,2005,59:408. |
| [32] | Thammanoon S;Sumaeth C;Supachai N et al.A simple route utilizing surfactant-assisted templating sol-gel process for synthesis of mesoporous Dy2O3 nanocrystal[J].Journal of Colloid and Interface Science,2006,300:219. |
| [33] | Thammanoon Sreethawong;Sumaeth Chavadej;Supachai Ngamsinlapasathian .Sol-gel synthesis of mesoporous assembly of Nd_2O_3 nanocrystals with the aid of structure-directing surfactant[J].Solid state sciences,2008(1):20-25. |
| [34] | Zhang Guijun;Shen Zhurui;Liu Mi et al.Synthesis and characterization of mesoporous ceria with hierarchical nanoarchitecture controlled by amino acids[J].Journal of Physical Chemistry B,2006,110:25782. |
| [35] | Chunwen Sun;Guoliang Xiao;Hong Li .Mesoscale Organization of Flower-Like La_2O_2CO_3 and La_2O_3 Microspheres[J].Journal of the American Ceramic Society,2007(8):2576-2581. |
| [36] | Hosokawa S;Iwamoto S;Inoue M .Synthesis of mesoporous needle-shaped ytterbium oxide crystals by solvothermal treatment of ytterbium chloride[J].Journal of the American Ceramic Society,2007(4):1215-1221. |
| [37] | Zawadzki M .Microwave-assisted synthesis and characterization of uhrafine neodymium oxide particles[J].Journal of Alloys and Compounds,2008,451:297. |
| [38] | WANG Tong-Wen,王彤文,刘玲,刘伟平,马子鹤,杨智,段爱红,阮琼.Y2O3和Nd2O3介孔薄膜的制备与表征[J].高等学校化学学报,2006(11):2026-2029. |
| [39] | Yolanda Castro;Beatriz Julian;Cedric Boissiere .Synthesis, characterization and optical properties of Eu_2O_3 mesoporous thin films[J].Nanotechnology,2007(5):055705(1-7). |
| [40] | Yolanda Castro;Beatriz Julián-López;Cédric Boissière;Bruno Viana;David Grosso;Clément Sanchez .Preparation, structural and optical characterization of rare earth doped mesoporous Y2O3 thin films by EISA method[J].Microporous and Mesoporous Materials,2007(1/3):273-279. |
| [41] | Shen W H;Dong X P .Mesoporous CeO2 and CuO2 loaded mesoporous CeO2:Synthesis,characterization and CO catalytic oxidation property[J].Microporous and Mesoporous Materials,2005,85:157. |
| [42] | Jan R;Hanno S;Tanya T et al.Mesoporous CeO2:Synthesis by nanocasting characterisation and catalytic properties[J].Microporous and Mesoporous Materials,2007,101:335. |
| [43] | Wang SF;Gu F;Li CZ;Lu MK .Synthesis of mesoporous Eu2O3 microspindles[J].Crystal growth & design,2007(12):2670-2674. |
| [44] | Javier Guzman;Avelino Corma .Nanocrystalline and mesostructured Y_2O_3 as supports for gold catalysts[J].Chemical communications,2005(6):743-745. |
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