以聚乙烯吡咯烷酮(PVP)作为还原剂和稳定剂制备SiO2/Ag纳米复合材料,分析银氨络离子的浓度对银纳米粒子的影响,采用透射电镜(TEM)、扫描电镜(SEM)对SiO2/Ag复合材料进行表征,并研究以SiO2/Ag为基底的表面拉曼散射增强.结果表明,银纳米颗粒以多晶形式沉积在球形二氧化硅表面,通过调节银氨络离子的浓度可以改变Ag纳米颗粒的大小及其在SiO2上的沉积量;当银的沉积量增加时,表面拉曼散射也随之增强.
参考文献
[1] | Jackson J B;Halas N J .[J].Journal of Physical Chemistry B,2001,105:2743. |
[2] | Oldenburg S J;Averitt R D;Westcott S L et al.[J].Applied Physics Letters,1998,288:243. |
[3] | Oldenburg S J;Hale R D;Jackson J B et al.[J].Applied Physics Letters,1999,75:1063. |
[4] | 闫映辉;郭文利;梁彤祥 et al.[J].稀有金属材料与工程,2007,36(11):2045. |
[5] | 杨晓峰,董相廷,周艳慧,王进贤,刘桂霞.贵金属核壳纳米粒子最新研究进展[J].稀有金属材料与工程,2009(02):368-372. |
[6] | Cassagneau T;Caruso F .[J].Advanced Materials,2002,14:732. |
[7] | Zhang JH;Liu JB;Wang SZ;Zhan P;Wang ZL;Ming NB .Facile methods to coat polystyrene and silica colloids with metal[J].Advanced functional materials,2004(11):1089-1096. |
[8] | Wang, ZX;Chen, XB;Chen, M;Wu, LM .Facile Fabrication Method and Characterization of Hollow Ag/SiO2 Double-Shelled Spheres[J].Langmuir: The ACS Journal of Surfaces and Colloids,2009(13):7646-7651. |
[9] | Moskovits M .[J].Journal of Chemical Physics,1978,69:4159. |
[10] | Futamata M;Maruyama Y;Ishikawa M .[J].Journal of Physical Chemistry B,2003,107:7607. |
[11] | Otto A;Mrozek I;Grabhorn H .[J].Journal of Physics:Condensed Matter,1992,4:1143. |
[12] | Moskovits M .[J].Journal of Chemical Physics,1978,69:4159. |
[13] | Futamata M;Maruyama Y;Ishikawa M .[J].Journal of Physical Chemistry B,2003,107:7607. |
[14] | Drachev V P;Perminov S V;Rautian S G et al.[J].Topics in Applied Physics,2002,82:113. |
[15] | Xu HX.;Kall M.;Apell P.;Aizpurua J. .Electromagnetic contributions to single-molecule sensitivity in surface-enhanced Raman scattering[J].Physical review.E.Statistical physics, plasmas, fluids, and related interdisciplinary topics,2000(3 Pt.b):4318-4324. |
[16] | Talley CE;Jackson JB;Oubre C;Grady NK;Hollars CW;Lane SM;Huser TR;Nordlander P;Halas NJ .Surface-enhanced Raman scattering from individual Au nanoparticles and nanoparticle dimer substrates[J].Nano letters,2005(8):1569-1574. |
[17] | Michaels A M;Nirmal M;Brus L E .[J].Journal of the American Chemical Society,1999,121:9932. |
[18] | Xu HX.;Kall M.;Borjesson L.;Bjerneld EJ. .Spectroscopy of single hemoglobin molecules by surface enhanced Raman scattering[J].Physical review letters,1999(21):4357-4360. |
[19] | Svedberg F;Li ZP;Xu HX;Kall M .Creating hot nanoparticle pairs for surface-enhanced Raman spectroscopy through optical manipulation[J].Nano letters,2006(12):2639-2641. |
[20] | Green M;Liu F M .[J].Journal of Physical Chemistry B,2003,107:13015. |
[21] | Cai WB.;Li XQ.;She CX.;Liu FM.;Cai XW.;Tian ZQ.;Ren B. .Investigation of surface-enhanced Raman scattering from platinum electrodes using a confocal Raman microscope: dependence of surface roughening pretreatment[J].Surface Science: A Journal Devoted to the Physics and Chemistry of Interfaces,1998(1/3):9-22. |
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