镀锌钢板无铬钝化研究新进展

腐蚀学报（英文）, 2011, 23(6): 535-539.

镀锌钢板无铬钝化研究新进展

徐丽萍 ^1, , 胡丰 ^2, , 杨兴亮 ^3, , 赵云龙 ^4, , 陈均 ^5, , 裴立宅 ^6, , 张千峰 ^7,

1.安徽工业大学分子工程与应用化学研究所,马鞍山243002／马鞍山钢铁股份有限公司技术中心,马鞍山243000

2.安徽工业大学分子工程与应用化学研究所,马鞍山243002／马鞍山钢铁股份有限公司技术中心,马鞍山243000

3.马鞍山钢铁股份有限公司技术中心,马鞍山,243000

4.马鞍山钢铁股份有限公司技术中心,马鞍山,243000

5.安徽工业大学分子工程与应用化学研究所,马鞍山,243002

6.安徽工业大学分子工程与应用化学研究所,马鞍山,243002

7.安徽工业大学分子工程与应用化学研究所,马鞍山243002／马鞍山钢铁股份有限公司技术中心,马鞍山243000

基金项目: 国家重点基础研究发展计划项目(2009AA032529)

关键词：镀锌钢板 , 无铬钝化 , 表面钝化处理 , 电化学反应 , 国民生产总值 , 钝化工艺 , 耐腐蚀性 , 自修复能力

在我国由于金属材料与周围环境发生化学或电化学反应所带来的腐蚀损失每年大约5000亿元人民币，约占我国国民生产总值的6％镀锌处理是钢铁防腐的一种有效手段，但在一些潮湿或腐蚀性气体环境中，镀锌层也极易被腐蚀破坏，因此，镀锌钢板仍需要进行表面钝化处理．传统的钝化工艺采用铬酸盐钝化处理技术，具有处理工艺简单、膜结合力好、耐腐蚀性高以及自修复能力好的特点．

参考文献

[1]	杨新岐.工业化粉末渗锌技术研究现状及市场发展前景[A].第四届中国国际腐蚀控制大会技术推广文集,2009.
[2]	闫磊.电镀锌硅酸盐钝化工艺及机理研究[D].昆明理工大学硕士学位论文,2008.
[3]	范云鹰,陈冬华,刘晓晶等.一种清洁型镀锌件硅酸盐彩色钝化工艺[P].中国国家发明专利,ZL200910094646.X,2009.
[4]	李广超.镀锌层硅酸盐钝化工艺研究[J]. 电镀与精饰,2007,29(2):31.
[5]	Song Y K, Mansfeld F. Development of a molybdate- phosphate-silane-silicate (MPSS) coating process for elec- trogalvanized steel [J]. Corros. Sci., 2005, 48(1): 154.
[6]	Hamlaoui Y, Tifouti L, Pedraza F. Corrosion behaviour of molybdate-phosphate-silicate coatings on galvanized steel [J]. Corros. Sci, 2009, 51(10): 2455.
[7]	Hinton B R, Wilson L. The corrosion inhibition of zinc with cerous chloride [J]. Corros. Sci, 1989, 29(8): 967.
[8]	Motte C, Maury N, Olivier M G, et al. Cerium treat- ments for temporary protection of electroplated steel [J]. Surf. Coat. Teehnol., 2005, 200(7): 2366.
[9]	Mirghasem H, Habib A S, Heshmat A, et al. Corrosion protection of electro-galvanized steel by green conversion coatings [J]. Rare Earths, 2007, 25(5): 537.
[10]	Wilson L, Hiton B R W. A nlethod for forming a corrosion coating resistant [P]. Australian, WO/1988/006639, 1988.
[11]	张英杰,章江洪,董鹏等.一种清洁型稀土盐钝化液制备方法[P].中国国家发明专利,ZL200910094371.X,2009.
[12]	廖秀娟.镀锌板的稀土钝化工艺的研究[D].武汉理工大学硕上学位论文,2008.
[13]	Liu G M, Yu F, Yang L, et al. Cerium-tannic acid passi- vation treatment on galvanized steel [J]. Rare Met., 2009, 28(3): 284.
[14]	Kong G, Liu L Y, Lu J T, et al. Study on lanthanum salt conversion coating modified with citric acid on hot dip galvanized steel [J]. Rare Earths, 2010, 28(3): 461.
[15]	路长青.钼酸盐的缓蚀机理[J].材料保护,1996,29(10):22.
[16]	Twite R L, Bierwagen G P. Review of alternatives to chro- mate for corrosion protection of aluminum aerospace alloys [J]. Prog. Org. Coat., 1998, 33(2): 91.
[17]	Treacy G M, Wilcox G D, Richardson M O W. Behaviour of molybdate-passivated zinc coated steel exposed to cor- rosive chloride environments [J]. Appl Electrochem., 1999, 29(5): 647.
[18]	Magalhges A A O, Margarit I C P, Mattos O R. Molyb- date conversion coatings on zinc surfaces [J]. Electroanal. Chem., 2004, 572(2): 433.
[19]	Lin B L, Lu J T, Kong G, et al. Growth and corrosion re- sistance of molybdate modified zine phosphate conversion coatings on hot-dip galvanized steel [J]. Trans. Nonferrous Met. Soc. Chin., 2007, 17(4): 755.
[20]	Tsai C Y, Liu J S, Chen P L, et al. A tow-step roll coat- ing phosphate/molybdate passivation treatment for hot- dip galvanized steel sheet [J]. Corros. Sci., 2010, doi: 10.1016/j.corsci.2010.06.020.
[21]	赖奂汶,黄清安,贾建新.镀锌层无铬钼酸盐钝化液的研究进展及思考[J].材料保护,2010,43(4):46.
[22]	Subramanian V, Ooij W J V. Effect of the amine func- tional group on corrosion rate of iron coated with films of organofunctional silanes [J]. Corros. Sci, 1998, 54(3): 204.
[23]	Brown K, Hamshire B, Bines E B, et al. Method of treat- ing metals using amino silanes and multi-silyl-functional silanes in admixture [P]. United States, US6596835B1, 2003.
[24]	Zhu D G, Ooij W J V. Corrosion protection of metals by water-based silane mixtures of bis- [trimethoxysilylpropyl]amine and vinyltriacetoxysilane [J]. Prog. Org. Coat., 2004, 49(1): 42.
[25]	Ooij W J V, Zhu D, Stacy M, et al. Corrosion protection properties of organofunctional silanes-an overview [J]. Ts- inghua Sci.Technol., 2005, 10(6): 639.
[26]	曾恩.热镀锌板表面无铬钝化研究[D].武汉材料保护研究所硕士毕业论文,2009.
[27]	姜瑞.热浸镀锌层钛盐转化膜的研究[D].华南理工大学硕士毕业论文,2010.
[28]	卢琳,李晓刚,宫丽等.镀锌层无铬钝化的现状与发展趋向[J],轧钢,2007,24(5):41.
[29]	吴双成.单宁酸在表面处理中的应用[J]. 表面技术,2000,29(2):36.
[30]	贝恩德,申策尔,阿林娜·莫妮卡,科赫.抗腐蚀剂和用于金属表面的防腐蚀工艺[P].中国发明专利,ZL01804595.2,2003.
[31]	Camalet J L, Lacroix J C, Aeiyach S. Characterization of polyaniline films electrodeposited on mild steel in aqueous p-toluenesulfonic acid solution [J]. J Electr. Chem., 1998, 445: 117.
[32]	Chen Z W, Kennon N F, See J B. Technigalva and other developments in batch hot-dip galvanizing [J]. JOM, 1992, 44(1): 22.
[33]	Wippermann K, Schuitze J W, Kessel R. The inhibition of zinc corrosion by bisaminotriazole and other triazole derivatives [J]. Corro Sci, 1991, 32(2): 205.
[34]	Peng T L, Man R L. Rare earth and silane as chromate replaces for corrosion protection on galvanized steel [J]. Rare Earths, 2009, 27(1): 159.
[35]	Kong G, Lu J T, Wu N J. Post treatment of silane and cerium salt as chromare replaces on galvanized steel [J]. Rare Earths, 2009, 27(1): 164.
[36]	徐斌,满瑞林,倪网东等.镀锌钢板表面硅烷、铈盐复合膜的制备及耐腐蚀性能研究[J].涂料工业,2007,37(12):46.
[37]	孙宁峰,李宁,吴志良等.用于电镀锌钢板表面处理的无铬钝化液及其使用法[P].中国发明专利,ZL200710039599.X,2008.
[38]	刘万青,饶丹.用于金属表面预处理的以硅烷偶联剂为主要成分的金属表面处理剂[P].中国专利,ZL200810020748.2,2008.
[39]	Shan F J, Liu C S, Wang S H, et al. Corrosion resistance of hot dip galvanized steel pretreated with bis-functional silanes modified with nanoalumina [J]. Acta Metall.Sin. (Eng.lett.) ,2008, 21(4): 245.
[40]	Suegama P H, Melo H G, Recco A A C, et al. Corro- sion behavior of carbon steel protected with single and bilayer of silane films filled with silica nanoparticles [J]. Surf. Coat. Technol., 2008, 202(13): 2850.
[41]	Montemor M F, Pinto R, Ferreira M O S. Chemical com- position and corrosion protection of silane films modified with CeO2 nanoparicles [J]. Electrochim. Acta, 2009, 54(22): 5179.
[42]	Deflorian F, Rossi S, Fedel M, et al. Electrochemical inves- tigation of high-performance silane sol-gel films containing clay nanoparticles [J]. Prog. Org .Coat., 2010, 69(2): 158.
[43]	Saravanan K, Sathiyanarayanan S, Muralidharan S, et al. Performance evaluation of polyaniline pigmented epoxy coating for corrosion protection of steel in concrete en- vironment [J]. Prog. Org. Coat., 2007, 59(2): 160.
[44]	Shi X M, Ngayen T A, Suo Z Y, et al. Effect of nanopar- tieles on the auticorrosion and mechanical properties of epoxy coating [J]. Surf. Coat. Technol., 2009, 204(3): 237.
[45]	Cieslik M, Engvall K, Pan J S, et al. Silane-parylene coating for improving corrosion resistance of stainless steel 316L implant material [J]. Corros. Sci., 2011, 53(1): 296.
[46]	Fedel M, Olivier M, Poelman M, et al. Corrosion protec- tion properties of silane pre-teated powder coated galva- nized steel [J]. Org. Coat., 2009, 66(2): 118.
[47]	Behzadnasab M, Mirabedini M, Kabiri K, et al. Corrosion performance of epoxy coatings containing silane treated ZrO2 nanoparticles on mild steel in 3.5% NaC1 solution [J]. Corros. Sci., 2011, 53(1): 89.
[48]	王静,伍林,宋世红等.镀锌板无铬钝化膜耐蚀性能的研究[J].材料保护,2008,41(11):28.
[49]	李智,陈抒,毕秋芳等.热镀锌板纳米二氧化硅改性有机-无机复合膜[J].电镀与环化,2008,28(1):27.
[50]	宫丽,卢琳,卢燕平.薄型无铬有机复合涂层钢板而耐蚀性的研究[J].材料保护,2008,41(2):68.
[51]	赵丽虹,李岩,吴建文.镀锌板无铬钝化液[P].中国发明专利,ZL200710010022.6,2008.
[52]	Yang H, Kong X H, Lu W H, et al. High anti-corrosion chromate-free passive films made by Titanate and water- borne polyethane on galvanized steel sheet [J]. Prog. Org. Coat., 2010, 67(4): 375.
[53]	孔祥华,杨辉,卢万恒等.一种有机无机复合金属表面钝化处理液[P].中国发明专利,ZL200810115662.8,2008.
[54]	大下贤一郎,田中宗德.金属表面处理剂、金属材料的表面处理方法以及表面处理金属材料[P].中国发明专利,ZL200580036339.6.2007.

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镀锌钢板无铬钝化研究新进展

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