Crystallization and Corrosion Resistance of (Fe0.78Si0.09B0.13)100-xNix (x=0, 2 and 5) Glassy Alloys

材料科学技术（英文）, 2011, 27(12): 1169-1177.

^1, , ^2, , ^3, , ^4, , ^5, , ^6,

1.Key Laboratory for Liquid-Solid Structural Evolution and Processing of Materials Ministry of Education, Shandong University, Jinan 250061, China;School of Mechanical and Electrical Engineering, Weifang University, Weifang 261061, China

2.Key Laboratory for Liquid-Solid Structural Evolution and Processing of Materials Ministry of Education, Shandong University, Jinan 250061, China

3.Key Laboratory for Liquid-Solid Structural Evolution and Processing of Materials Ministry of Education, Shandong University, Jinan 250061, China

4.Shandong Institute of Metrology, Jinan 250014, China

5.Department of Applied Physics, Northwestern Polytechnical University, Xi'an 710072, China

6.Key Laboratory for Liquid-Solid Structural Evolution and Processing of Materials Ministry of Education, Shandong University, Jinan 250061, China

基金项目: the Excellent Youth Project of Natural Science Foundation of Shandong(JQ201012) the Open Project of Key Lab of Magnetism,Magnetic Materials in Lanzhou University(LZUMMM 2010008) the Shandong Excellent Youth Award Foundation(2008BS04020) The authors acknowledge the National Natural Science Foundation of China(50871061;51171091)

Crystallization and Corrosion Resistance of (Fe0.78Si0.09B0.13)100-xNix (x=0, 2 and 5) Glassy Alloys

Haijian Ma ^1, , Weimin Wang ^2, , Jie Zhang ^3, , Guihua Li ^4, , Chongde Cao ^5, , Hongdi Zhang ^6,

2.Key Laboratory for Liquid-Solid Structural Evolution and Processing of Materials Ministry of Education, Shandong University, Jinan 250061, China

3.Key Laboratory for Liquid-Solid Structural Evolution and Processing of Materials Ministry of Education, Shandong University, Jinan 250061, China

4.Shandong Institute of Metrology, Jinan 250014, China

5.Department of Applied Physics, Northwestern Polytechnical University, Xi'an 710072, China

6.Key Laboratory for Liquid-Solid Structural Evolution and Processing of Materials Ministry of Education, Shandong University, Jinan 250061, China

Keywords： Crystallization

The crystallization of the (Fe0.78Si0.09B0.13)100-xNix glassy alloys (x=0, 2 and 5) has been investigated by X-ray diffraction (XRD) and differential scanning calorimeter (DSC). Corrosion resistance analyses have been carried out using electrochemical measurements and corrosion products have been analyzed by scanning electron microscopy (SEM). The experimental results show that the addition of Ni can promote the nucleation of α-Fe, retard the decomposition of the metastable borides, and alter the crystallization mode of the present Fe-based glassy alloys. The lattice constant (aFe0) of α-Fe in the annealed samples shows a decreasing trend with increasing annealing time. The Ni addition can improve the corrosion resistance of the as-quenched Fe-based glassy alloys in H_2SO4, NaCl and NaOH solutions. The results indicate that Ni can promote the diffusion of Si atoms during quenching and annealing processes.

参考文献

[1]	A. R. Yavari;O. Drbohlav .Thermodynamics and Kinetics of Nanostructure Formation in Soft-Magnetic Nanocrystalline Alloys (Overview)[J].Materials Transactions, JIM,1995(7):896-902.
[2]	N. A. Mariano;C.A.C. Souza;J. E. May .Influence of Nb content on the corrosion resistance and saturation magnetic density of FeCuNbSiB alloys[J].Materials Science & Engineering, A. Structural Materials: Properties, Misrostructure and Processing,2003(1/2):1-5.
[3]	D. Szewieczek;A. Baron .Electrochemical corrosion properties of amorphous Fe_(78)Si_(13)B_9 alloy[J].Journal of Materials Processing Technology,2004(0):442-445.
[4]	R. Raicheff;V. Zaprianova;E. Gattef .Effect of structural relaxation on electrochemical corrosion behaviour of amorphous alloys[J].Journal of Materials Science Letters,1997(21):1701-1704.
[5]	X.L.Tian,C.W.Zhan,J.X.Hou,X.C.Chen,J.J.Sun.Nanocrystal Model for Liquid Metals and Amorphous Metals[J].材料科学技术学报（英文版）,2010(01):69-74.
[6]	M. Iqbal,J.I. Akhter,H.F. Zhang,Z.Q. Hu.Synthesis and Characterization of Fe50Cr14Mo14C14B6Gd2 Bulk Amorphous Steel[J].材料科学技术学报（英文版）,2010(09):783-786.
[7]	K. Chrissafis;M.I. Maragakis;K.G. Efthimiadis .Detailed study of the crystallization behaviour of the metallic glass Fe_(75)Si_9B_(16)[J].Journal of Alloys and Compounds: An Interdisciplinary Journal of Materials Science and Solid-state Chemistry and Physics,2005(1/2):165-173.
[8]	F.X. Qin;H.F. Zhang;P. Chen .Corrosion behavior of bulk amorphous Zr_(55)Al_(10)Cu_(30)Ni_(5-x)Pd_x alloys[J].Materials Letters,2004(7/8):1246-1250.
[9]	S.J. Pang;C.H. Shek;K. Asami .Formation and corrosion behavior of glassy Ni-Nb-Ti-Zr-Co(-Cu) alloys[J].Journal of Alloys and Compounds: An Interdisciplinary Journal of Materials Science and Solid-state Chemistry and Physics,2007(0):240-243.
[10]	T.Naohara .The role of Nb in the nanocrystallization of amorphous Fi-Si-Nb alloys[J].Acta materialia,1998(2):397-404.
[11]	T.-S. Chin;C.Y. Lin;M.C. Lee .Bulk nano-crystalline Fe-based alloys by annealing bulk glassy precursors[J].Intermetallics,2008(1):52-57.
[12]	H.J. Ma;W.M. Wang;J.T. Zhang .Effect of Ni on the mlcrostructure and precipitate phases of Fe_(78)Si_9B_(13) glassy alloy[J].Journal of Alloys and Compounds: An Interdisciplinary Journal of Materials Science and Solid-state Chemistry and Physics,2009(1/2):255-260.
[13]	K.L. Sahoo;M. Wollgarten;J. Haug .Effect of La on the crystallization behaviour of amorphous Al_(94-x)Ni_6La_x (x = 4-7) alloys[J].Acta materialia,2005(14):3861-3870.
[14]	L. Q. Xing;J. Eckert;W. Loeser .Atomic ordering and magnetic properties in Nd_(57)Fe_(20)B_(8)Co_(5)Al_(10) solids[J].Journal of Applied Physics,2000(6):3565-3569.
[15]	W.-M. WANG;W.X. ZHANG;A. GEBERT .Microstructure and Magnetic Properties in Fe_(61)Co_(9-x)Zr_8Mo_5W_xB_(17) (0 < = x< = 3) Glasses and Glass-Matrix Composites[J].Metallurgical and Materials Transactions, A. Physical Metallurgy and Materials Science,2009(3):511-521.
[16]	D.M. Minic;A. Gavrilovic;P. Angerer .Structural transformations of Fe_(75)Ni_2Si_8B_(13)C_2 amorphous alloy induced by thermal treatment[J].Journal of Alloys and Compounds: An Interdisciplinary Journal of Materials Science and Solid-state Chemistry and Physics,2009(1/2):705-709.
[17]	A. Baron;D. Szewieczek;G. Nawrat .Corrosion of amorphous and nanocrystalline Fe-based alloys and its influence on their magnetic behavior[J].Electrochimica Acta,2007(18):5690-5695.
[18]	C. A. C. Souza;S. E. Kuri;F. S. Politti;J. E. May;C. S. Kiminami .Corrosion resistance of amorphous and polycrystalline FeCuNbSiB alloys in sulphuric acid solution[J].Journal of Non-Crystalline Solids: A Journal Devoted to Oxide, Halide, Chalcogenide and Metallic Glasses, Amorphous Semiconductors, Non-Crystalline Films, Glass-Ceramics and Glassy Composites,1999(0):69-73.
[19]	M.G. Alvarez;S.M. Vazquez;J. Moya .ANODIC BEHAVIOUR OF Fe_(73.5)Si_(13.5-x)Al_xB_9Nb_3Cu_1 (x = 0 - 2) AMORPHOUS, NANOSTRUCTURED AND CRYSTALLINE ALLOYS[J].Scripta materialia,2001(3):507-512.

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Crystallization and Corrosion Resistance of (Fe0.78Si0.09B0.13)100-xNix (x=0, 2 and 5) Glassy Alloys

参考文献