用含不同取代数的硬脂酰基硅酸乙酯制备了有机-无机层状材料,利用粉末X射线衍射(XRD)和差示扫描量热法(DSC)进行表征,结果表明,含有3种取代数目的硬脂酰基硅酸乙酯的水解产物都具有典型的层状结构,同时随着长碳链酰基的数目增加,2θ向小角方向移动,层状材料的层间距变大,并对酰基链的排列方式进行了初步探讨.
参考文献
[1] | Xu A;W Highly.Ordered lamellar silica/surfactant composites templated from nonionic amphiphilic copolymer[J].CHEMISTRY OF MATERIALS,2002(14):3625. |
[2] | Xu A W.Novel surfactants for the synthesis of unusual highly ordered lamellar oxides[J].JOURNAL OF PHYSICAL CHEMISTRY B,2002(106):11713. |
[3] | Morizzi J;Hobday M;Rixl C.Synthesis and characterisation of some lamellar indium phosphonates[J].JOURNAL OF MATERIALS CHEMISTRY,1999(09):863. |
[4] | Gabashvili A;Seisenbaeva G A;Kessler V G.The sonochemical preparation of lamellar MoOx[J].JOURNAL OF MATERIALS CHEMISTRY,2003(13):2851. |
[5] | Haskouri J E;Cabrera S L;Roca M.Synthesis of a new mesostructured lamellar oxovanadium phosphate assembled through an S+X-Io mechanism[J].INORGANIC CHEMISTRY,1999(38):4243. |
[6] | Vanchura B A;He P;Antochshuk V.Direct synthesis of mesostructured lamellar molybdenum disulfides using a molten neutral n-alkylamine as the solvent and template[J].Journal of the American Chemical Society,2002(124):12090. |
[7] | Kruk M;Jaroniec M.Determination of the lamellar phase content in MCM-41 using X-ray diffraction,nitrogen adsorption,and thermogravimetry[J].JOURNAL OF PHYSICAL CHEMISTRY B,2000(104):1581. |
[8] | 吴芃,邓国军,徐赛龙,范青华,万立骏,王琛,白春礼.取代基数目对分子自组装结构的影响[J].科学通报,2002(11):841-844. |
上一张
下一张
上一张
下一张
计量
- 下载量()
- 访问量()
文章评分
- 您的评分:
-
10%
-
20%
-
30%
-
40%
-
50%