欢迎登录材料期刊网

材料期刊网

高级检索

为制备具有功能性的聚乳酸复合材料,以聚L-乳酸(PLLA)和α-环糊精(α-CD)为原料,通过熔融共混技术制备PLLA/α-CD复合材料.研究结果显示α-CD促进了PLLA的结晶,提高了PLLA的结晶速率,但材料变脆;而PLLA/α-CD复合材料非等温结晶后的熔融行为则地受到降温速率的强烈影响,降温速率的增加使得PLLA/α-CD复合材料由单熔融峰转变为双熔融峰.热分解性能研究结果则表明添加α-CD能使PLLA的热分解温度升高.

参考文献

[1] Yu Q Z;Qin Y M .Fabrication and formation mechanism of poly(L-lactic acid) ultrafine multi-porous hollow fiber by electrospinning[J].express polymer Letters,2013,7(01):55.
[2] Chen, X.;Zhuo, J.;Jiao, C. .Thermal degradation characteristics of flame retardant polylactide using TG-IR[J].Polymer Degradation and Stability,2012(11):2143-2147.
[3] Suprakas Sinha Ray;Mosto Bousmina .Biodegradable polymers and their layered silicate nanocomposites: In greening the 21st century materials world[J].Progress in materials science,2005(8):962-1079.
[4] Vainionpaa S S;Rokkanen P;Tormala P .Surgical applications of biodegradable polymers in human tissues[J].Progress in Polymer Science,1989,14(05):679.
[5] Leenslag J W;Pennings A J;Bos R M et al.Resorbable materials of poly(L-lactide):Ⅶ.In vivo and in vitro degradation[J].Biomaterials,1987,8(04):311.
[6] Gu J D;Gada M;Kharas G et al.Degradability of cellulose acetate (1.7 and 2.5 D.S.) and poly(lactide) in simulated composting bioreactors[J].Polymeric Materials Science and Engineering,1992,67:351.
[7] Cai, Y.;Yan, S.;Yin, J.;Fan, Y.;Chen, X. .Crystallization behavior of biodegradable poly(L-lactic acid) filled with a powerful nucleating agent: N,N′-Bis(benzoyl) suberic acid dihydrazide[J].Journal of Applied Polymer Science,2011(3):1408-1416.
[8] Huang, SM;Hwang, JJ;Liu, HJ;Lin, LH .Crystallization Behavior of Poly(L-lactic acid)/Montmorillonite Nanocomposites[J].Journal of Applied Polymer Science,2010(1):434-442.
[9] Gopakumar T G;Lee J A et al.Influence of clay exfoliation on the physical properties of montrmorillonite/polyethylene composites[J].Polymer,2002,43(20):5483.
[10] Yasuniwa M.;Satou T. .Multiple melting behavior of poly(butylene succinate). I. Thermal analysis of melt-crystallized samples[J].Journal of Polymer Science, Part B. Polymer Physics,2002(21):2411-2420.
[11] Shun-Jiang Li;Yan-Hua Cai .Synthesis, Morphology and Thermal Decomposition of Schiff Base Derived from m-Hydroxybenzaldehyde and p-Aminobenzoic Acid[J].Asian Journal of Chemistry: An International Quarterly Research Journal of Chemistry,2011(6):2619-2621.
上一张 下一张
上一张 下一张
计量
  • 下载量()
  • 访问量()
文章评分
  • 您的评分:
  • 1
    0%
  • 2
    0%
  • 3
    0%
  • 4
    0%
  • 5
    0%