在聚乙二醇(PEG-400)存在的条件下, 在溶液中FeCl3与NaOH反应所得的沉淀物经抽滤后, 在空气中60℃干燥6h后再在不同温度下热处理. 所得的各样品用XRD、Mossbauer谱、TEM及FTIR等手段进行了表征. 结果表明, 沉淀经60℃干燥6h后?得到结晶较差的γ-Fe2O3
粉体(含少量结晶较好的α-FeOOH). 经300℃热处理1h后得长径比约为5的棒形γ-Fe2O3纳米粒子.
This paper presented a new method to prepare γ-Fe2O3 nanoparticles. After the reaction of FeCl3 with NaOH in the presence of polyethylene glycol(PEG-400), the precipitate was dried at
60℃ in air and then calcined at different temperatures for 1h. XRD, Mossbauer spectroscope, TEM, FTIR and TG-DTA were used to characterize the obtained samples. The results
show that after the precipitate dried at 60℃ for 6h, a poor-crystalline γ-Fe2O3 powder forms, and calcined at 300℃ for 1h, the poor-crystalline powder turns to rod-like
γ-Fe2O3 nanoparticles with aspect ratio about 5.
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