超极化129Xe核磁共振技术及其在多孔催化材料研究中的应用

催化学报 , 2006, 27(9): 827-836.

超极化129Xe核磁共振技术及其在多孔催化材料研究中的应用

刘勇 ^1, , 张维萍 ^2, , 韩秀文 ^3, , 包信和 ^4,

1.中国科学院大连化学物理研究所催化基础国家重点实验室,辽宁,大连,116023;中国科学院研究生院,北京,100049

2.中国科学院大连化学物理研究所催化基础国家重点实验室,辽宁,大连,116023

3.中国科学院大连化学物理研究所催化基础国家重点实验室,辽宁,大连,116023

4.中国科学院大连化学物理研究所催化基础国家重点实验室,辽宁,大连,116023

基金项目: 国家自然科学基金(20573106)

关键词：激光抽运 , 超极化氙 , 核磁共振 , 多孔材料 , 多相催化 , 表征

Hyperpolarized 129Xe NMR and Its Applications in Characterization of Porous Catalytic Materials

激光抽运和自旋交换的超极化129Xe核磁共振是近几年发展起来的一种新方法,它比普通129Xe核磁共振的检测灵敏度提高约104～105倍,是研究材料孔结构和孔内粒子分布的强有力工具.本文介绍了超极化129Xe核磁共振技术并综述了其在多孔催化材料研究中的应用,特别是对催化反应中广泛使用的无机微孔和介孔材料中的应用进行了详细的讨论.最后展望了此技术的应用前景.

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超极化129Xe核磁共振技术及其在多孔催化材料研究中的应用

Hyperpolarized 129Xe NMR and Its Applications in Characterization of Porous Catalytic Materials

参考文献