采用熔融玻璃净化和循环过热相结合的方法,研究了Fe-Co合金在深过冷快速凝固中的亚稳相.结果表明,当熔体的过冷度达到某一临界数值(△Tcrit)时,亚稳相(b.c.c)在竞争形核中优先形核生长,并在随后的冷却过程中保留在凝固组织中.在γ单相区内等温退火3 h后,亚稳相完全转变为稳定相;在过冷Fe-Co合金的凝同组织中亚稳相是"竞争形核-重熔-γ相外延生长-不完全固态相变"的产物.
参考文献
[1] | R.E.Cech.Evidence for solidification of a metastable phase in Fe Ni alloys,Trans.AIME,206,585(1956) |
[2] | J.Gao,T.Volkmann,J.Strohmenger,D.M.Herlach,Phase selection in undercooled Nd-Fe-Co-B alloy droplets.Mater.Sci.Eng.,A 375-377,498(2004) |
[3] | J.Strohmenger,T.Volkmann,J.Gao,D.M.Herlach,Phase selection in undercooled Fe-Nd alloy melts.Mater.Sci.Eng.A,375-377,561(2004) |
[4] | Chen YZ,Yang GC,Liu F,N.Liu.H.Xie,Y.H.Zhou,Microstructural transitions of metastable phase in undercooled Fe-7.5at% Ni alloy,J.of Cryst.Growth,289,1(2006) |
[5] | N.Liu,F.Liu,G.C.Yang,Y.Z.Chen,C.L.Yang,Y.H.Zhou,Nucleation and phase selection in undercooled Fe-Co melt.J.Alloys Compd.,467,L11(2009) |
[6] | Y.Z.Chen,G.C.Yang,F.Liu,N.Liu,H.Xie,Y.H.Zhou,Forming mechanism of metastable"dendrite core"in undercooled Fe-Ni alloy,Mater.Lett.,60,1888(2006) |
[7] | D.M.tlerlach,B.Feucrbacher,E.Schleip,Phase seeding in the solidification of an undercooled melt.Mater.Sci.Eng.A,133.795(1991) |
[8] | J.F.Li,W.Q.Jie,G.C.Yang,Y.H.Zhou,Solidification structure formation in undercooled Fe-Ni alloy,Acta Materialia,50(7),1797(2002) |
[9] | T.Koseki,M.C.Flemillgs,Solidification of undercooled Fe-Cr-Ni alloys,Metall.Mater.Trans.A,26A,2991(1995) |
[10] | R.Hermann,W.L(o)ser,H-G Lindenkreuz,A.Diefenbach,W.Zahnow,W.Dreier,T.Volkmann,D.M.Herlach,Metastable phase formation in undercooled Fe-Co melts under terrestrial and parabolic Hight conditions,Microgravity-Sciceuce and Technology,19,5(2007) |
[11] | R.Hermann,W.L(o)ser,G.Lindenkreuz,A.Diefenbach,W.Zahnow,W.Dreier,T.Volkmann,D.M.Herlach,Metastable phase formation in undercooled Fe-Co melts.Mater.Sci.Eng.A,375-377,507(2004) |
[12] | T.G.Woodcock,R.Hermann,W.L(o)ser,Development of a metastable phase diagram to describe solidification in undercooled Fe-Co melts,Comp.Coupling Phase Diagrams Thermochem,31,256(2007) |
[13] | Li Mingjun,Song Guangsheng,Yang Gencang and Zhou Yaohe,Microstructure evolution and metastable phase formation in Fe-30at.%Co melt,Mater.Sci.Eng.,A26,90(1998) |
[14] | GUO Xuefeng,YANG Gencang,Effect of glass composition on undercooling stability of Cu50Ni50 alloy melts,Chin.J.Nonferrous Met.,10,77(2000)(郭学锋,杨根仓,玻璃净化剂组分对Cu50Ni50合金熔体过冷度稳定性的影响,中国有色金属学报,10,77(2000)) |
[15] | LIU Ning,YANG Gencang,LIU Feng,CHEN Yuzeng,YANG Changlin,ZHOU Yaohe,Solidification disciptinarian of highly undercooled Fe-Co alloy,Acta Metal Sinica,43(5),449(2007)(刘宁,杨根仓,刘峰,陈豫增,杨长林,周尧和,深过冷Fe-Co合金的凝固规律,金属学报,43(5),449(2007)) |
[16] | D.Turnbull,J.C.Fisher,Rate of nucleation in condensed system,J.Chem.Phys.,17,71(1949) |
[17] | D.Turnbull,Formation of crystal nuclei in liquid metals,J.Appl.Phys.,21,1022(1950) |
[18] | C.V.Thompson.F.Spaepen.Homogeneous crystal nucleation in binary metallic melts,Acta Metal,31,3021(1983) |
[19] | J.F.Li,Y.C.Liu,Y.L.Lu,G.C.Yang,Y.H.Zhou,Structural evolution of undercooled Ni-Cu alloys.J.of Crystal Growth,192(3-4),462(1998) |
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