考察热轧工艺及随后热处理对Mg-Y-Nd合金组织演变的影响。结果表明:低温(<500℃)轧制时,大量稠密析出相的出现致使轧制性能极大地降低且组织难以细化;在固溶温度下轧制(525℃)时,晶粒极易粗化;当轧制温度略低于固溶温度时,轧制过程中会析出弥散的第二相粒子。这些粒子的存在没有恶化轧制性能且有效地钉扎晶界并抑制高温下再结晶晶粒的粗化。该合金的较佳轧制工艺如下:轧制温度为500℃、每道次轧制变形量为10%且总轧制变形量70%。热轧后,材料获得平均晶粒尺寸为30μm左右的组织,并产生较强的基面织构。固溶处理1h可有效地消除位错并维持细晶和基面织构。进一步增加固溶时间,晶粒发生粗化且织构变得分散。相比于均匀化态,经T6处理的热轧态Mg-Y-Nd合金的屈服强度提高176 MPa。
The effects of hot-rolling and the following heat treatment on microstructure were investigated. The results show that, for rolling below 500 ℃, the dense precipitates are formed, which is bad for further rolling and grain refinement. However, rolling at the solution temperature (525℃), the recrystallization grains grow rapidly and coarsen. When rolling temperature is slightly lower than the solution temperature, dispersion particles are precipitated, which are not harmful for further rolling and are capable of pinning grain boundary to resist coarsening of recrystallization grains at high temperature. The better rolling processing parameters are that the rolling temperature is 500 ℃, the thickness reduction per pass is 10%and the total thickness reduction is 70%. After hot-rolling, the fine and uniform microstructure with an average size of approximately 30μm and a strong basal texture are obtained. The solution treatment for 1h can effectively eliminate dislocation and retain the same grain size and texture. As solution time further increases, the grain coarsens and texture becomes dispersive. Compared to the as-received alloy, the yield strength of the hot-rolled Mg-Y-Nd alloy with T6 treatment is increased by 176 MPa.
参考文献
[1] | J. F. Nie and B. C. Muddle .CHARACTERISATION OF STRENGTHENING PRECIPITATE PHASES IN A Mg-Y-Nd ALLOY[J].Acta materialia,2000(8):1691-1703. |
[2] | J.F.Nie;B.C.Muddle .PRECIPITATION IN MAGNESIUM ALLOY WE54 DURING ISOTHERMAL AGEING AT 250℃[J].Scripta materialia,1999(10):1089-1094. |
[3] | Renlong Xin;Ling Li;Ke Zeng .Structural examination of aging precipitation in a Mg-Y-Nd alloy at different temperatures[J].Materials Characterization,2011(5):535-539. |
[4] | 陈振华.变形镁合金[M].北京:化学工业出版社,2005 |
[5] | J. A. del Valle;M. T. Perez-Prado;O. A. Ruano .Texture evolution during large-strain hot rolling of the Mg AZ61 alloy[J].Materials Science & Engineering, A. Structural Materials: Properties, Misrostructure and Processing,2003(1/2):68-78. |
[6] | S. R. Agnew;J. A. Horton;T. M. Lillo;D. W. Brown .Enhanced ductility in strongly textured magnesium produced by equal channel angular processing[J].Scripta materialia,2004(3):377-381. |
[7] | D. Wu;R.S. Chen;E.H. Han .Excellent room-temperature ductility and formability of rolled Mg-Gd-Zn alloy sheets[J].Journal of Alloys and Compounds: An Interdisciplinary Journal of Materials Science and Solid-state Chemistry and Physics,2011(6):2856-2863. |
[8] | Renlong Xin;Bo Song;Ke Zeng;Guangjie Huang;Qing Liu .Effect of aging precipitation on mechanical anisotropy of an extruded Mg-Y-Nd alloy[J].Materials & design,2012(Feb.):384-388. |
[9] | 余琨,黎文献,王日初,王渤,李超.轧制及热处理对WE43镁合金组织和性能的影响[J].材料热处理学报,2008(02):95-98. |
[10] | Thirumurugan, M.;Kumaran, S.;Suwas, S.;Rao, T.S. .Effect of rolling temperature and reduction in thickness on microstructure and mechanical properties of ZM21 magnesium alloy and its subsequent annealing treatment[J].Materials Science & Engineering, A. Structural Materials: Properties, Misrostructure and Processing,2011(29/30):8460-8468. |
[11] | M. T. Perez-Pardo;J. A. del Valle;O. A. Ruano .Effect of sheet thickness on the microstructural evolution of an Mg AZ61 alloy during large strain hot rolling[J].Scripta materialia,2004(5):667-671. |
[12] | 张真,汪明朴,李树梅,蒋念,胡海龙,郝诗梦.热轧过程中AZ31镁合金的组织及织构演变[J].中国有色金属学报,2010(08):1447-1454. |
[13] | Yong Liu;Guangyin Yuan;Wenjiang Ding .Deformation behavior of Mg-Zn-Gd-based alloys reinforced with quasicrystal and Laves phases at elevated temperatures[J].Journal of Alloys and Compounds: An Interdisciplinary Journal of Materials Science and Solid-state Chemistry and Physics,2007(1/2):160-165. |
[14] | X.y. Song;G.q. Liu .Influence of the second-phase particle size on grain growth based on computer simulation[J].Materials Science & Engineering, A. Structural Materials: Properties, Misrostructure and Processing,1999(2):178-182. |
[15] | S. M. Hafez Haghighat;A. Karimi Taheri .Investigation of limiting grain size and microstructure homogeneity in the presence of second phase particles using the Monte Carlo method[J].Journal of Materials Processing Technology,2008(1-3):195-203. |
[16] | 宋波,辛仁龙,刘庆.析出相对镁合金变形机理影响的研究进展[J].中国有色金属学报,2011(11):2719-2731. |
[17] | H. Yan;R.S. Chen;E.H. Han .Room-temperature ductility and anisotropy of two rolled Mg–Zn–Gd alloys[J].Materials Science & Engineering, A. Structural Materials: Properties, Misrostructure and Processing,2010(15):3317-3322. |
[18] | 杨续跃,张雷,姜育培,朱亚坤.Mg-Y及AZ31镁合金高温变形过程中微观织构的演化[J].中国有色金属学报,2011(02):269-275. |
[19] | Wang, M.;Xin, R.;Wang, B.;Liu, Q. .Effect of initial texture on dynamic recrystallization of AZ31 Mg alloy during hot rolling[J].Materials Science & Engineering, A. Structural Materials: Properties, Misrostructure and Processing,2011(6):2941-2951. |
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