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采用固相反应法制备了相变温度接近室温的热致变色材料,研究了不同掺杂元素和掺杂浓度对热致变色材料辐射和光学特性的影响,并利用K—K分析模型导出了热致变色材料的光学常数。结果表明:热致变色材料LCSMO和LSMO(x=0.175)的发射率在相变温度附近出现剧烈变化,并且光常数在很大的频域范围内可自主调制。

The thermochromatic materials, of which phase transition temperature is near room temperature, are prepared by standard solid state reaction method. The influences of component fraction and doping element on the radiative and optical properties of the materials are studied. Based on the spectral reflectivity data of the materials, the optical constants are obtained through the Kramers-Kroning analysis. The result shows that the emissivity of the materials (La0.7Ca0.2Sr0.1MnO3 and La0.825Sr0.175MnO3) present a sudden transition around the phase transition temperature, and the optical constants can be also adjusted by the change of doping level.

参考文献

[1] Robert Osiander;Samara L. Firebaugh;John L. Champion;Dawnielle Farrar;M. Ann Garrison Darrin .Microelectromechanical Devices for Satellite Thermal Control[J].IEEE sensors journal,2004(4):525-531.
[2] Computational design of solar reflection and far-infrared transmission films for a variable emittance device[J].Applied optics,2003(7):1360-1366.
[3] 李强,匡柳,宣益民.热致变色可变发射率材料的制备与辐射特性研究[J].工程热物理学报,2009(06):1005-1008.
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