欢迎登录材料期刊网

材料期刊网

高级检索

首次研究了Ho3+掺杂对SrAl2O4:Eu2+,Dy3+发光性能的影响.采用燃烧合成方法,在600℃条件下,合成Ho3+掺杂的SrAl2O4:Eu2+,Dy3+新型长余辉光致发光材料.X射线衍射分析结果表明,合成的样品为单相SrAl2O4单斜晶系磷石英结构.光致发光光谱测量显示,合成样品的发射光谱是连续宽带谱,峰值位于510nm左右,激发光谱是单峰且峰值位于356nm的连续宽带谱.利用单光子计数系统测量了材料的余辉衰减曲线,结果显示Ho3+的适量掺杂可以明显提高铝酸锶的初始发光亮度.当Ho3+的掺入摩尔比例为0.005时,初始亮度是不掺杂Ho3+时的两倍多.对初始亮度增强的机理做了初步的探讨.

参考文献

[1] 罗昔贤,于晶杰,林广旭,肖志强,段锦霞,肖志国.长余辉发光材料研究进展[J].发光学报,2002(05):497-502.
[2] 唐道明.[J].光机电信息,2003(02):8.
[3] Luo Xixian;Cao Wanghe;Xiao Zhiguo .[J].Journal of Alloys and Compounds,2006,416:250.
[4] 周传仓,卢忠远,戴亚堂,王兵.共沉淀法制备超细长余辉发光材料铝酸锶铕镝的研究[J].稀有金属,2005(01):20-24.
[5] 李峻峰,邱克辉,赖雪飞,李群.燃烧法快速合成铝酸锶基质长余辉发光材料[J].硅酸盐学报,2004(12):1560-1562,1559.
[6] 张希艳,卢利平,王晓春.溶胶-凝胶法制备SrAl2O4:Eu2+,Dy3+纳米发光材料[J].硅酸盐学报,2003(03):268-271.
[7] Peng Tianyou;Yang Huanping;Pu Xuli et al.[J].Materials Letters,2004,58:352.
[8] Chander H;Haranath D;Shanker V;Sharma P .Synthesis of nanocrystals of long persisting phosphor by modified combustion technique[J].Journal of Crystal Growth,2004(1/2):307-312.
[9] Aizawa H.;Katsumata T.;Takahashi J.;Matsunaga K.;Komuro S.;Morikawa T.;Toba E. .Long afterglow phosphorescent sensor materials for fiber-optic thermometer[J].Review of Scientific Instruments,2003(3 Pt.1):1344-1349.
[10] Katsumata T;Toyomane S;Tonegawa A et al.[J].Journal of Crystal Growth,2002,237-239:316.
[11] 陈一诚,陈登铭,詹益松.杂质的添加对SrAl2O4∶Eu2+,Dy3+余辉发光特性的改善[J].中国稀土学报,2001(06):502-506.
[12] Matsuzawa T.;Takeuchi N.;Murayama Y.;Aoki Y. .NEW LONG PHOSPHORESCENT PHOSPHOR WITH HIGH BRIGHTNESS, SRAL2O4-EU2+,DY3+[J].Journal of the Electrochemical Society,1996(8):2670-2673.
[13] 孙家跃;杜海燕.固体发光材料[M].北京:化学工业出版社,2003:545.
[14] R. Sakai;T. Katsumata;S. Komouro;T. Morikawa .Effect of composition on the phosphorescence from BaAl_2O_4: Eu~(2+), Dy~(3+) crystals[J].Journal of Luminescence: An Interdisciplinary Journal of Research on Excited State Processes in Condensed Matter,1999(1/3):149-154.
[15] Aitasalo T;Deren P;Holsa J et al.[J].Journal of Solid State Chemistry,2003,171:114.
[16] Yamamoto H;Matsuzawa T .Mechanism of long phosphorescence of SrAl2O4:Eu2+, Dy3+ and CaAl2O4:Eu2+, Nd3+[J].Journal of Luminescence: An Interdisciplinary Journal of Research on Excited State Processes in Condensed Matter,1997(0):287-289.
[17] Kuang Jinyong;Liu Yingliang;Zhang Jingxian et al.[J].Solid State Communications,2005,136:6.
上一张 下一张
上一张 下一张
计量
  • 下载量()
  • 访问量()
文章评分
  • 您的评分:
  • 1
    0%
  • 2
    0%
  • 3
    0%
  • 4
    0%
  • 5
    0%