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介绍了一种以新鲜蛋清蛋白为络合剂,用溶胶-凝胶法制备MnFe2O4尖晶石铁氧体的新方法,并探索最佳合成条件.研究发现此法反应条件温和且性能较好,最低可以在450℃C下制成单相MnFe2O4尖晶石铁氧体,最佳制备条件为500℃烧结 5h并淬火.最佳条件下制备的铁氧体结晶度好,粒度均匀且粒径大小在15nm左右,室温下具有较高的比饱和磁化强度和矫顽力,分别为54.07emu·g-1和3380e,剩磁比Mr/Ms=0.273.

参考文献

[1] Daliya S.Mathew;Ruey-Shin Juang .An overview of the structure and magnetism of spinel ferrite nanoparticles and their synthesis in microemulsions[J].Chemical engineering journal,2007(1/3):51-65.
[2] J. Douglas Adam;Lionel E. Davis;Gerald F. Dionne;Ernst F. Schloemann;Steven N. Stitzer .Ferrite Devices and Materials[J].IEEE Transactions on Microwave Theory and Techniques,2002(3):721-737.
[3] 颜旭刚,娄敏毅,王德平,黄文旵,陈晰.锰锌铁氧体材料的合成及其医学应用[J].材料导报,2005(z2):340-343.
[4] 郭秀盈,颜秀茹,霍明亮,王建萍,白天.纳米Mn-Zn铁氧体的制备和研究[J].无机化学学报,2004(05):608-612.
[5] Sun S H;Zeng H;Robinson D B .Monodisperse MFe2O4 (M=Mn,Fe,Co) nanoparticles[J].Journal of the American Chemical Society,2004,126(01):273.
[6] Liu Chao;Zou Bingsuo;Adam J Rondinone et al.Reverse micelle synthesis and characterization of superparamagnetic MnFe2O4 spinel ferrite nanoctrystallites[J].Journal of Physical Chemistry B,2000,104(06):1141.
[7] Karen S Martirosyan;Dan Luss .Carbon combustion synthesis of ferrites:synthesis and characterization[J].Industrial and Engineering Chemistry Research,2007,46:1492.
[8] Shannon A.Morrison;Christopher L.Cahill;Everett E.Carpenter;Vincent G.Harris .Production Scaleup of Reverse Micelle Synthesis[J].Industrial & Engineering Chemistry Research,2006(3):1217-1220.
[9] Caruntu D.;Remond Y.;Chou NH.;Jun MJ.;Caruntu G.;He JB.;Goloverda G. O'Connor C.;Kolesnichenko V. .Reactivity of 3d transition metal cations in diethylene glycol solutions. Synthesis of transition metal ferrites with the structure of discrete nanoparticles complexed with long-chain carboxylate anions[J].Inorganic Chemistry: A Research Journal that Includes Bioinorganic, Catalytic, Organometallic, Solid-State, and Synthetic Chemistry and Reaction Dynamics,2002(23):6137-6146.
[10] Sen D;Deb P;Mazumder S et al.Microstructural investigations of ferrite nanoparticles prepared by nonaqueous precipitation route[J].Materials Research Bulletin,2000,35:1243.
[11] Donald M Schleich;Zhang Yunchang .Preparation of some metal ferrite MFe2O4 thin films through a nonaqueous sol method[J].Materials Research Bulletin,1995,30(04):447.
[12] Xin-Hao Li;Dong-Hui Zhang;Jie-Sheng Chen .Synthesis of Amphiphilic Superparamagnetic Ferrite/Block Copolymer Hollow Submicrospheres[J].Journal of the American Chemical Society,2006(26):8382-8383.
[13] Santi Maensiri;Chivalrat Masingboon;Paveena Laokul .Egg white snythesis and photoluminescence of platelike clusters of CeO2 nanoparticles[J].Crystal Growth and Design,2007,7(05):950.
[14] Santi Maensiri;Chivalrat Masingboon;Banjong Boonchom .A simple route to synthesize nickel ferrite (NiFe_2O_4) nanoparticles using egg white[J].Scripta materialia,2007(9):797-800.
[15] Ola Lyckfeldt;Jesper Brandt .Protein forming - a novel shaping technique for ceramics[J].Journal of the European Ceramic Society,2000(14/15):2551-2559.
[16] QIANG-MIN WEI;JIAN-BIAO LI;YONG-JUN CHEN .Cation distribution and infrared properties of Ni_(x)Mn_(1-x)Fe_(2)O_(4) ferrites[J].Journal of Materials Science,2001(21):5115-5118.
[17] Gabal, MA;Ata-Allah, SS .Concerning the cation distribution in MnFe2O4 synthesized through the thermal decomposition of oxalates[J].The journal of physics and chemistry of solids,2004(5):995-1003.
[18] 周志刚.铁氧体磁性材料[M].北京:科学出版社,1981:381.
[19] Yu Hsuanfu;Yang Shangwei .Formation of crystalline MnFe2O4 powder by flame-combusting freeze-dried citrate precursors[J].Journal of Alloys and Compounds,2005,394(01):286.
[20] Nevenka Rajic;Miran Ceh;Roman Gabrovsek .Formation of Nanocrystalline Transition-Metal Ferrites inside a Silica Matrix[J].Journal of the American Ceramic Society,2002(7):1719-1724.
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