为获得铝液腐蚀工况下金属材料的选用原则,运用静态铝液浸没腐蚀试验,研究了QT350、HT300、H13、Cr13、Ta、Mo在铝液中的腐蚀行为。结果表明:所选金属材料在试验条件下均与铝液反应生成金属间化合物层;所选金属材料在铝液中的平均腐蚀深度由高到低依次为QT350、H13、Cr13、HT300、Ta、Mo,难熔金属Ta、Mo具有优异的耐铝液腐蚀性能;QT350、HT300、H13、Cr13腐蚀后表面形成大量点状蚀坑,其在铝液中的腐蚀为非均匀腐蚀;Ta、Mo腐蚀后表面平整,其在铝液中的腐蚀为均匀腐蚀。
To obtain the selection principle of metals under molten aluminum corrosion condition, corrosion behavior of QT350,HT300,H13,Cr13,Ta,Mo in molten aluminum was investigated by static immersion tests. In all cases, intermetallic compound layer is formed due to reaction of chosen metals and molten aluminum under the experiment condition. Experiment result shows that the average corrosion depths of the chosen metals from large to small in proper order is QT350, H13, Cr13, HT300, Ta, Mo, and the refractory metals Mo, Ta exhibit excellent corrosion resistance in molten aluminum. Some etch pits appeared on local areas of QT350,HT300,H13,Cr13, and the corrosion is non-uniform. However, smooth surface of Ta, Mo shows that the corrosion is uniform.
参考文献
[1] | 李亚江,S. A. Gerasimov,王娟,马海军,任江伟.Ti/Al异种材料真空扩散焊及界面结构研究[J].材料科学与工艺,2007(02):206-210. |
[2] | 余岩,谢海东.不锈钢在熔融铝液中的高温腐蚀[J].腐蚀与防护,2012(03):216-217,221. |
[3] | K.A. Nazari;S.G. Shabestari .Effect of micro alloying elements on the interfacial reactions between molten aluminum alloy and tool steel[J].Journal of Alloys and Compounds,2009(1/2):523-530. |
[4] | 程晓敏,谭永刚,吴兴文.Cr20 Ni80合金在液态Al-Si合金及Al-Si-Cu-Mg-Zn合金中界面腐蚀研究[J].材料热处理学报,2010(11):134-138. |
[5] | 孙向雷 .热电偶保护套管耐铝液腐蚀性研究[D].太原理工大学,2012. |
[6] | HOU Hua;YANG Ruifeng .Study on stainless steel electrode based on dynamic aluminum liquid corrosion mechanism[J].Journal of Environmental Sciences Supplement,2009,21(Sup 1):S170-S173. |
[7] | 吴晓春,邬天荣,杨浩鹏,王庆芳.H13钢低温等离子体渗硼层的热熔损性能[J].材料热处理学报,2011(01):97-102. |
[8] | Yulong Zhu;David Schwam;John F. Wallace;Sebastian Birceanu .Evaluation of soldering, washout and thermal fatigue resistance of advanced metal materials for aluminum die-casting dies[J].Materials Science & Engineering, A. Structural Materials: Properties, Misrostructure and Processing,2004(1/2):420-431. |
[9] | 冼焯斌 .太阳能相变储能合金容器材料的选择及性能研究[D].广东工业大学,2011. |
[10] | Z. Zakhariev;M. Marinov;T. Penyashki .Simultaneous powdery boronaluminizing of steel stable in aluminum melts[J].Journal of Alloys and Compounds: An Interdisciplinary Journal of Materials Science and Solid-state Chemistry and Physics,2008(1/2):501-503. |
[11] | 陈维平,付志强,方思聪,肖华强,朱德智.Al0.5FeNiCr和Al0.5FeNiCrCoTi0.25合金高温铝液熔蚀行为[J].中国科技论文,2013(02):166-168,174. |
[12] | 娄本浊.从耐腐蚀性能看高温熔铝坩埚的选材[J].材料保护,2009(03):71-72. |
[13] | DAVID BALLOY;JEAN-CHARLES TISSIER;MARIE-LAURENCE GIORGI;MARC BRIANT .Corrosion Mechanisms of Steel and Cast Iron by Molten Aluminum[J].Metallurgical and Materials Transactions, A. Physical Metallurgy and Materials Science,2010(9):2366-2376. |
[14] | 长崎诚三;平林真;刘安生.二元合金状态图集[M].北京:冶金工业出版社,2004 |
[15] | 王晓亮.含Cr钢在Al液中腐蚀行为研究[J].热加工工艺,2011(08):38-40. |
- 下载量()
- 访问量()
- 您的评分:
-
10%
-
20%
-
30%
-
40%
-
50%