研究了在二元二(三氟甲基磺酸酰)亚胺碱金属盐LiTFSI-CsTFSI的共晶熔体(共晶点组成:摩尔比为0.07:0.93;共晶点温度为112℃)中电化学沉积难熔金属钼.结果表明,选择MOCl3作为钼离子源,分别于200和150℃在镍基体上电沉积得到金属钼.循环伏安法结合SEM和XPS分析表明,在1.4V vs.Li+/Li处的恒电位电解所得到的沉积物为非晶态的金属钼.
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